Photometry of the minima of TX Herculis

Three epochs of primary and four epochs of secondary minima of TX Her were determined from photoelectric observations made between 1968 and 1973. The individual observations in three colours are given in Tables I-III.     

A Generalized Structure-Activity Relationship for the Decomposition of (Substituted) Alkoxy Radicals

A novel and readily applicable Structure-Activity Relationship (SAR) for predicting the barrier height E_b to decomposition by C-C scission of (substituted) alkoxy radicals is presented. Alkoxy radicals are pivotal intermediates in the atmospheric oxidation of (biogenic) volatile organic compounds, and their fate is therefore of crucial importance to the understanding of atmospheric VOC degradation mechanisms. The SAR is based on available theoretical energy barriers and validated against barriers derived from experimental data. The SAR is expressed solely in terms of the number(s) N_i of alkyl-, hydroxy- and/or oxo-substituents on the - and -carbons of the breaking bond: E_b(kcal/mol) =17.5 – 2.1 × N(alk) – 3.1 ×N(alk) – 8.0 × N_,(OH) – 8.0 × N(O=) – 12 × N(O=). For barriers below 7 kcal/mol, an additional, second-order term accounts for the curvature. The SAR reproduces the available experimental and theoretical data within 0.5 to 1 kcal/mol. The SAR generally allows conclusive predictions as to the fate of alkoxy radicals; several examples concerning oxy radicals from prominent atmospheric VOC are presented. Specific limitations of the SAR are also discussed. Using the predicted barrier height E_b, the high-pressure rate coefficient for alkoxy decomposition k _diss (298 K) can be obtained from k _diss (298 K) = L ×1.8 × 10¹³ exp(–E_b/RT) s^–1, with L the reaction path degeneracy.     

SfM-MVS Photogrammetry for Splash Erosion Monitoring under Natural Rainfall

An understanding of splash erosion is the basis to describe the impact of rain characteristics on soil disturbance. In typical splash cup experiments, splashed soil is collected, filtered, and weighed. As a way to collect additional data, our experiments have been supplemented by a photogrammetric approach. A total of three soils were tested across three sites, one in the Czech Republic and two in Austria, all equipped with rain gauges and disdrometers to measure rainfall parameters. The structure from motion multiview stereo (SfM-MVS) photogrammetric method was used to measure the raindrops impact on the soil surface. The images were processed using Agisoft PhotoScan, resulting in orthophotos and digital elevation models (DEMs) with a resolution of 0.1 mm/pix. The surface statistics included the mean surface height (whose standard deviation was used as a measure of surface roughness), slope, and other parameters. These parameters were evaluated depending on soil texture and rainfall parameters. The results show a linear correlation between consolidation and splash erosion with a coefficient of determination (R²) of approximately 0.65 for all three soils. When comparing the change in soil volume with rainfall parameters, the best correlation was found with the maximum 30-minintensity (I₃₀), resulting in R² values of 0.48 (soil A, silt loam, 26% clay), 0.59 (soil B, silt loam, 18% clay), and 0.68 (soil C, loamy sand, 12% clay). The initial increase in the sample volume for the lowest splashed mass corresponds with the increase in the clay content of each of the soils. Soil A swells the most. Soil B swells less. Soil C does not swell at all and consolidates the most. We derived the relationship between the photogrammetrically measured change in surface height and the splash erosion (measured by weight) by accounting for the effect of the clay content.     

Automated calibration of advanced soil constitutive models. Part II: hypoplastic clay and modified Cam-Clay

This paper introduces an automated deterministic method for the calibration of the Modified Cam-Clay and hypoplastic clay model. The calibration is structured in a hierarchical order established based on the apriori sensitivity study performed. The proposed method favours the clear physical meaning of the model parameters to a complete optimization of the objective error function. The method requires only basic laboratory experiments and it is currently implemented in the free-to-use online application called ExCalibre.

     

Total water content thresholds for shallow landslides,Outer Western Carpathians

Shallow landslides are fairly frequent natural processes which emerge as a result of both rainfall and rapid snowmelt in the Flysch Belt of the Outer Western Carpathians. We estimated the total water content thresholds for the previously defined seven phases of increased landsliding which took place between 1939 and 2010 around the Napajedla meteorological station. The time series were reconstructed on the basis of data from surrounding stations. Rainfalls with the highest intensities (>1 mm/min) were removed from the set. Rainfall of such an intensity primarily causes overland flow and soil erosion and does not contribute to landslide threshold. The snow water equivalent was computed on the basis of the snow height, and possible errors were evaluated as interval estimations. An interval of 10 days before a landslide phase was selected for the total water content threshold. The resulting lower boundary (67.0 mm/10 days) and upper boundary (163.3 mm/10 days) thresholds of water infiltrated into soil during an event shall be part of the prepared online warning system in this area.     

Diurnal variations of winds over an upwelling region off Oregon

The diurnal variation of surface winds off the coast of Oregon is described and compared with a recent analysis of winds off the coast of Peru. The Oregon wind speeds have a distinct 24-h periodicity, while the Peru wind speeds were reported to have an irregular 12-h variation. The long-and trans-shore components of both winds exhibit 24-h periodicities; the ratio of the long-shore to trans-shore diurnal amplitudes off Oregon is 2.8, twice the ratio found off Peru. Although meteorological conditions off Oregon were quasi-stationary during the period investigated, there were considerable day-to-day variations in diurnal amplitudes and phases. Diurnal amplitudes were found to be correlated with the daily mean long-shore winds.     

Snow and climate trends and their impact on seasonal runoff and hydrological drought types in selected mountain catchments in Central Europe

ABSTRACT

This study investigates changes in seasonal runoff and low flows related to changes in snow and climate variables in mountainous catchments in Central Europe. The period 1966–2012 was used to assess trends in climate and streamflow characteristics using a modified Mann–Kendall test. Droughts were classified into nine classes according to key snow and climate drivers. The results showed an increase in air temperature, decrease in snowfall fraction and snow depth, and changes in precipitation. This resulted in increased winter runoff and decreased late spring runoff due to earlier snowmelt, especially at elevations from 1000 to 1500 m a.s.l. Most of the hydrological droughts were connected to either low air temperatures and precipitation during winter or high winter air temperatures which caused below-average snow storages. Our findings show that, besides precipitation and air temperature, snow plays an important role in summer streamflow and drought occurrence in selected mountainous catchments.     

Seasonal and diurnal variability of pressure fluctuation in the infrasound frequency range observed in the Czech microbarograph network

Infrasound environments in the Czech microbarograph network were studied. Reference Fourier amplitude spectra were calculated from data measured at three microbarograph sites of the network in May 2011-April 2012; directional analysis of infrasound arrivals in the frequency band 0.15-0.4 Hz was performed for the microbarograph array at Panská Ves in May 2014-April 2015. Diurnal, seasonal and site-to-site variability of the reference spectra was evaluated. Site-to-site variability is influenced by the location of the respective sensors in the open air and inside the observatory buildings and by local noise phenomena like wind turbines. Diurnal variability is well developed in summer with maximum ambient noise levels during the daytime and minima at night. Seasonal variability is observed at night with maxima in winter and minima in summer. Wind and wind eddies seem to be an important source of ambient noise in measurements in the Czech microbarograph network. A distinct spectral peak occurs near 0.2 Hz with amplitudes by about one order of magnitude higher in winter than in summer. Its seasonal variability is related to seasonal propagation of microbaroms from the source region in the Northern Atlantic.