The stratigraphic and paleoenvironmental setting of Aptian OAE black shale deposits in the Pieniny Klippen Belt, Slovak Western Carpathians

During the Jurassic and Cretaceous, the Pieniny Klippen Belt units of the Outer Western Carpathians were situated on the edge of the Paleoeuropean shelf rimming the northermost margin of the Mediterranean Tethys. During the late early Aptian humid event, Lower Cretaceous pelagic carbonate (Maiolica) sedimentation was interrupted by terrigenous input as a consequence of the first major mid-Cretaceous climate perturbations. The fluctuation of radiolarian abundance indicated an expansion of the oxygen-minimum zone due to upwelling conditions and salinity changes. Foraminifera, radiolarians, non-calcareous dinocysts, and calcareous nannofossils encountered in the West Carpathian Rochovica section enable a comparison of the black shales of the upper lower Aptian Koňhora Formation with the well-known Selli Event. Subsequent anoxia patterns (depositional, productive, and stagnant) have taken part in the depositional regime. Early Aptian climate perturbations both in the Outer Western Carpathians, Swiss Prealps (situated in a similar position on the distal southern edge of the former Paleoeuropean shelf) and/or in other parts of the world are traceable with sedimentological, biological, and chemical proxies.     

New model calculations for the production rates of cosmogenic nuclides in iron meteorites

Abstract— Here we present the first purely physical model for cosmogenic production rates in iron meteorites with radii from 5 cm to 120 cm and for the outermost 1.3 m of an object having a radius of 10 m. The calculations are based on our current best knowledge of the particle spectra and the cross sections for the relevant nuclear reactions. The model usually describes the production rates for cosmogenic radionuclides within their uncertainties; exceptions are ⁵³Mn and ⁶⁰Fe, possibly due to normalization problems. When an average S content of about 1 ± 0.5% is assumed for Grant and Carbo samples, which is consistent with our earlier study, the model predictions for ³He, ²¹Ne, and ³⁸Ar are in agreement. For ⁴He the model has to be adjusted by 24%, possibly a result of our rather crude approximation for the primary galactic α particles. For reasons not yet understood the modeled ³⁶Ar/³⁸Ar ratio is about 30–40% higher than the ratio typically measured in iron meteorites. Currently, the only reasonable explanation for this discrepancy is the lack of experimentally determined neutron induced cross sections and therefore the uncertainties of the model itself. However, the new model predictions, though not yet perfect, enable determining the radius of the meteoroid, the exposure age, the sulphur content of the studied sample as well as the terrestrial residence time. The determination of exposure ages is of special interest because of the still open question whether the GCR was constant over long time scales. Therefore we will discuss in detail the differences between exposure ages determined with different cosmogenic nuclides. With the new model we can calculate exposure ages that are based on the production rates (cm³STP/(gMa)) of noble gases only. These exposure ages, referred to as noble gas exposure ages or simply ^3,4He, ²¹Ne, or ^36,38Ar ages, are calculated assuming the current GCR flux. Besides calculating noble gas ages we were also able to improve the ⁴¹K‐⁴⁰K‐and the ³⁶Cl‐³⁶Ar dating methods with the new model. Note that we distinguish between ³⁶Ar ages (calculated via ³⁶Ar production rates only) and ³⁶Cl‐³⁶Ar ages. Exposure ages for Grant and Carbo, calculated with the revised ⁴¹K‐⁴⁰K method, are 628 ± 30 Ma and 841 ± 19 Ma, respectively. For Grant this is equal to the ages obtained using ³He, ²¹Ne, and ³⁸Ar but higher than the 3⁶Ar‐ and ³⁶Cl‐³⁶Ar ages by ?30%. For Carbo the ⁴¹K‐⁴⁰K age is ?40% lower than the ages obtained using ³He, ²¹Ne, and ³⁸Ar but equal to the ³⁶Ar age. These differences can either be explained by our still insufficient knowledge of the neutron‐induced cross sections or by a long‐term variation of the GCR.     

Constraints of archaeomagnetic dating and field intensity determinations in three ancient tile kilns in Belgium

The aim of this study is to date by the archaeomagnetic method the last heatingcooling cycle of one Roman and two Medieval tile kilns, discovered in Belgium. The investigation demonstrates the limitations when well-documented local directional secular variation curves of the geomagnetic field in the past are used for dating and the difficulties when trying to determine field intensities from “in situ” baked clays from the kilns. The three kilns yielded very well defined ancient field directions but two possible dating solutions for each of them when no a priori time constraints are taken into account, due to field direction recurrence. As an increase of the dating accuracy and reduction of the number of dating solutions can be expected using the full field vector information, also field intensity determinations on burnt clays from the kilns were attempted. Field intensities from samples of the Roman and of one of the Medieval kilns are quite scattered. On the other hand, results obtained applying the Thellier-Thellier method and the modified method developed by Dekkers and Böhnel on sister samples from the Roman kiln agree fairly well. Rock magnetic properties reveal high variance in the kilns that point to varying spatial heating and cooling conditions in the kilns. Even well burnt material from the kilns shows irreversible changes when heated in air in the laboratory. Reliable field intensities on “in situ” baked materials from kilns themselves can therefore only be obtained when measuring sufficient number of samples from different parts of the kiln, taking into account the spatial-temporal conditions during kiln operation and cooling history. More reference intensity data is needed in our regions in order to improve dating based on directional reference data only.     

Noble gases in Grant and Carbo and the influence of S‐ and P‐rich mineral inclusions on the 41K‐40K dating system

Abstract— Cosmogenic He, Ne, and Ar were measured in the iron meteorites Grant (IIIAB) and Carbo (IID) to re‐determine their preatmospheric geometries and exposure histories. We also investigated the influence of sulphur‐ and/or phosphorus‐rich inclusions on the production rates of cosmogenic Ne. Depth profiles measured in Grant indicate a preatmospheric center location 117 mm left from the reference line and 9 mm below bar B, which is clearly different (?10 cm) from earlier results (?165 mm left from the reference line on bar F). For Carbo the preatmospheric center location was found to be 120 mm right of the reference line and 15 mm above bar J, which is in agreement with literature data. The new measurements indicate a spherical preatmospheric shape for both meteorites and, based on literature ³⁶C1 data, the radii were estimated to be about 32 cm and 70 cm for Grant and Carbo, respectively. We demonstrate that minor elements like S and P have a significant influence on the production rates of cosmogenic Ne. In our samples, containing on average 0.5% S and/or P, about 20% of ²¹Ne was produced from these minor elements. Using measured ²¹Ne concentrations and endmember ²²Ne/²¹Ne ratios for Fe + Ni and S + P, respectively, we show that it is possible to correct for ²¹Ne produced from S and/or P. The thus corrected data are then used to calculate new ⁴¹K‐⁴⁰K exposure ages—using published K data—which results in 564 ± 78 Ma for Grant and 725 ± 100 Ma for Carbo. The correction always lowers the ²¹Ne concentrations and consequently decreases the ⁴¹K‐⁴⁰K exposure ages. The discrepancies between ³⁶Cl‐³⁶Ar and ⁴¹K‐⁴⁰K ages are accordingly reduced. The existence of a significant long‐term variation of the GCR, which is based on a former 30–50% difference between ⁴¹K‐⁴⁰K and ³⁶Cl‐³⁶Ar ages, may warrant re‐investigation.     

Effects of meteoroid shape on cosmogenic nuclide production processes

The shape of meteorites is one of the major factors influencing the production of cosmogenic nuclides. Numerical simulations using the Los Alamos Code System (LCS) particle production and transport codes were done to investigate particle fluxes and production rates of cosmogenic nuclides ¹⁰Be, ²⁶Al, and ⁶⁰Co in meteoroids of spherical, ellipsoidal, and cylindrical shapes. The calculations show that fluxes of nuclear active particles and also production rates of cosmogenic nuclides are sensitive to the shape of the irradiated parent body.     

Mass distribution in the asteroid belt

The dependence of the cumulative number of numbered asteroids (up to 3720) on their absolute magnitude is investigated. The differential mass index k is derived from these relations for fainter asteroids. A steeper slope (2.2 < k < 2.4) is found in the four most populous asteroid familes (Flora, Koronis, Eos and Themis) and a flatter slope (1.3 < k < 1.6) for non-family asteroids. This indicates that there are two different asteroid populations in the asteorid belt. Total masses of the asteroid families may be greater than it is commonly accepted.     

Elemental composition from gamma‐ray spectroscopy of the NEAR‐Shoemaker landing site on 433 Eros

Abstract— Elemental composition and composition ratios derived from gamma‐ray measurements collected by the NEAR‐Shoemaker spacecraft while on the surface of 433 Eros are reported. Performance of the gamma‐ray spectrometer (GRS) during cruise and orbit is reviewed. The best gamma‐ray data were collected on the surface of Eros after the spacecraft's controlled descent on 2001 February 12. Methods used in spectral analysis, to convert peak areas to incident photons, and photons to elemental composition are described in some detail. The elemental abundance of K and the Mg/Si, Fe/Si, Si/O and Fe/O abundance ratios were determined. The Mg/Si and Si/O ratios and the K abundance are roughly chondritic, but the Fe/Si and Fe/O ratios are low compared to expected chondritic values. Three possible explanations for the apparent Fe depletion are considered.     

Effects of land use,slope gradient,and soil and water conservation structures on runoff and soil loss in semi-arid Northern Ethiopia

April lightning production in Richmond County, Georgia, from 1995 to 2003 is considered with regard to the associated risk to golfers and spectators at the Master's Golf Tournament and courses throughout the county. An examination of the April lightning climatology of Georgia, focusing on Richmond County, reveals a minimum in lightning activity during the time of the tournament (the first full week of April). A discriminant analysis of Richmond County lightning production utilizes several meteorological variables in order to discern between three categories of April lightning days: little or no lightning activity, minimal lightning activity, and high lightning activity. The analysis distinguishes relatively well between the categories with only 13.5% of the events misclassified. A composite regional analysis of the three lightning categories illustrates the environmental differences between these events. Although the little or no lightning and high lightning categories are somewhat similar environmentally, the intensity of features separates these events and allows for interpretation. The statistical and synoptic analyses together emphasize the importance of low-level instability and frontal proximity and intensity in enhancing lightning production in thunderstorms during April in and surrounding Richmond County. A multitude of meteorological conditions can lead to thunderstorm development. Localized studies of these environments, especially during times of major outdoor sporting events, are needed to help mitigate the risk associated with lightning.