The role of metal sulfates in thermochemical sulfate reduction (TSR) of hydrocarbons: Insight from the yields and stable carbon isotopes of gas products

The mechanism of thermochemical sulfate reduction (TSR) was investigated by separately heating n-C₂₄ with three different sulfates (CaSO₄, Na₂SO₄, MgSO₄) in sealed gold tubes at 420 °C and measuring the stable carbon isotope values of hydrocarbon (C₁-C₅) and non-hydrocarbon (CO₂) products. Extensive TSR was observed with the MgSO₄ reactant as reflected by increasing concentrations of H₂S, ¹³C depleted CO₂ and relatively low concentrations of H₂ (compared to the control). H₂S yields were already very high at the first monitoring time (12 h) when the temperature had just reached 420 °C, suggesting that TSR had commenced well prior to this temperature. Only trace amounts of n-C₂₄ and secondary C₃-C₅ alkanes were detected at 12 h, reflecting the efficient TSR utilization of the reactant and lower molecular weight alkane products. Ethane levels were still relatively high at 12 h, but declined thereafter as it was subject to TSR in the absence of higher molecular weight alkanes which had already been utilized. Methane yields were consistently high throughout the 48 h MgSO₄ treatment. The temporal decrease in the concentrations of alkanes available for TSR may also contribute to the sharp enhancement of CO₂ after 36 h. Absence or dampening of the molecular and isotopic trends of MgSO₄ TSR was observed with Na₂SO₄ and CaSO₄ respectively, directly reflecting the levels of TSR reached using these sulfate treatments.For all treatments, the δ¹³C values of C_1-5n-alkanes showed an increase with both molecular weight and treatment time. MgSO₄ TSR led to a 5-10‰ increase in the δ¹³C values of the C₁-C₅ hydrocarbons and a 20‰ decrease in the δ¹³C value of CO₂. The significant ¹³C depletion of the CO₂ may be due to co-production of ¹³C enriched MgCO₃, although this remains unproven as the δ¹³C of MgCO₃ was not measured. The difference in the δ¹³C values of ethane and propane (Δδ¹³C_EP) increased in magnitude with the degree of TSR, and this trend could be used to help evaluate the occurrence and extent of TSR in subsurface gas reservoirs.     

Hydromechanical behavior of unsaturated soil with different initial densities over a wide suction range

Acta Geotechnica - Many civil engineering projects are related to hydromechanical behavior of unsaturated soils over a wide suction range, which was investigated by imposing suctions on clayey silt...     

Effects of seismic force and pore water pressure on stability of 3D unsaturated hillslopes

Natural Hazards - Three-dimensional (3D) kinematic limit analysis of unsaturated hillslopes is presented in this paper. Different from the traditional two-dimensional (2D) mechanism based on the...     

Seismic Zoning of Croatia

The territory of Croatia and neighboring regions is divided into 17 seismic source zones, considering available seismological and geological data. On this basis, seismic hazard elements (seismicity rate, maximum magnitude, b-value, probabilities of exceedance and return periods for a predefined set of magnitudes) are computed using the maximum likelihood method appropriate for treating data-sets with variable completeness thresholds. The values of long term expected peak horizontal acceleration obtained by using a combination of the deterministic and the probabilistic procedure are the highest in the Dubrovnik zone, while the Zagreb zone has the highest earthquake hazard in the continental part of the country. This revised version was published online in June 2006 with corrections to the Cover Date.     

Northern Adriatic phytoplankton response to short Po River discharge pulses during summer stratified conditions

A 275‐km‐long transversel Northern Adriatic profile from the mouth of the Po River (Italian Adriatic coast) to the Kvarner region (Croatian coastal island area) was investigated in three successive case studies in August 2008, 2009 and 2010. The short Po River pulses in August result in the surface advection of riverine water, nutrients and phytoplankton from the western to the eastern side of the Adriatic. This surface spreading exhibits inter‐annual variability depending on the riverine discharge in the preceding period. The Po River discharge pulse in August 2010 in particular resulted in an extraordinary tongue‐like advection of riverine water, nutrients, and phytoplankton towards the Eastern Adriatic coast. The phenomenon was detected using both satellite imagery and classical oceanographic measurements. In the advective water, toxic dinoflagellates were most abundant in August 2010, when the influence of the Po was greatest.     

Equivalent-linear site response analysis on the site of the historical Trakošćan Castle,Croatia, using HVSR method

This paper presents a major extension of seismic vulnerability research project on the site of Trako??an Castle based on the initial horizontal-to-vertical-spectral-ratio (HVSR) results from Stanko et al. (2016). The estimated HVSR site frequencies and HV amplification at Trako??an Castle can only be used as an indication of the initial soil site frequency and amplification, so-called natural soil model, corresponding to the subsoil profile without the influence of an earthquake. The equivalent-linear (EQL) site response analysis has been carried out for different earthquake scenarios for a maximum input rock peak ground acceleration (PGA_ROCK) that corresponds to return periods of 95 (0.08 g), 475 (0.18 g) and 1000 years (0.31 g). The aim of the research is to evaluate structural seismic design responses and to determine type and degree of damage caused by local site effect, which is the result of an alluvial basin and topographic influences. The main objective of this research is the formation of local microseismic zones based on an EQL analysis: surface spectral acceleration and amplification maps at the predominant frequency. Based on the HVSR frequency response of the core structure of Trako??an Castle and the Tower itself (fundamental and higher frequency modes), maps of surface spectral acceleration and soil amplification at different frequencies (3, 5 and 10 Hz) are developed for different input PGA_ROCK levels (0.08, 0.18 and 0.31 g) to evaluate seismic response of the Castle. Observed amplifications are correlated with ground motion polarization and directionality of the ground motion from the alluvial basin to the hilltop. Shortening of predominant frequencies (lengthening of the period), particularly in the alluvial basin, has been observed with higher input PGA_ROCK in the EQL analysis. This effect is not manifested in the Trako??an hill, and predominant frequencies match HVSR frequencies. The use of certain geophysical survey methods at historical sites is a big problem, because terrain features (e.g. steep hills, mountains, ridges, slopes, cliffs) create lack of space and make it impossible to carry out geophysical investigation. Microtremor measurements at historical sites can overcome this limitation and provide local seismic response and vulnerability behaviour of historical monuments without destroying their authenticity. Also, computational modelling can greatly improve the results. The EQL site response analysis on the site of Trako??an Castle has confirmed and improved the results of seismic response and vulnerability based on HVSR method.     

Stratigraphy of the sediment infill in Bosphorus Strait: water exchange between the Black and Mediterranean Seas during the last glacial Holocene

The sediment infill over the Paleozoic bedrock in the Bosphorus Strait consists of four sedimentary units which were deposited in the last 26,000 ¹⁴C years B.P. The stratigraphy of these units suggests that this part of the Bosphorus was a freshwater lake between 26,000 and 5,300 ¹⁴C years B.P., depositing sands with a freshwater mollusc fauna of Black Sea neo-euxinian affinity (Dreissena rostriformis, Dreissena polymorpha, and Monodacna pontica). The first appearance of euryhaline Mediterranean molluscs (e.g., Ostrea edulis, Mytilus edulis) was observed at 5,300 ¹⁴C years B.P. in this part of the Bosphorus. Deposition of coarse Mytilus-bank and Ostrea-bank units suggests that the establishment of the present dual-flow regime in the Bosphorus took place at about 4,400 ¹⁴C years B.P.     

Active fault database of Turkey

We have updated the active fault map of Turkey and built its database within GIS environment. In the study, four distinct active fault types, classified according to geochronological criteria and character, were delineated on the 1:25,000 base map of Turkey. 176 fault segments not included in the former active fault map of Turkey, have been identified and documented. We infer that there are 485 single fault segments which are substantially potential seismic sources. In total 1964 active-fault base-maps were transferred into the GIS environment. Each fault was attributed with key parameters such as class, activity, type, length, trend, and attitude of fault plane. The fault parameters are also supported by slip-rate and seismogenic depth inferred from available GPS, seismological and paleoseismological data. Additionally, expected maximum magnitude for each fault segment was estimated by empirical equations. We present the database in a parametric catalogue of fault segments to be of interest in earthquake engineering and seismotectonics. The study provides essential geological and seismological inputs for regional seismic hazard analysis of all over Turkey and its vicinity.     

An improved earthquake catalogue (<Emphasis Type="Italic">M</Emphasis> ≥ 4.0) for Turkey and its near vicinity (1900–2012)

Many catalogues, agency reports and research articles have been published on seismicity of Turkey and its surrounding since 1950s. Given existing magnitude heterogeneity, erroneous information on epicentral location, event date and time, this past published data however is far from fulfilling the required standards. Paucity of a standardized format in the available catalogues have reinforced the need for a refined and updated catalogue for earthquake related hazard and risk studies. During this study, ~37,000 earthquakes and related parametric data were evaluated by utilizing more than 41 published studies and, an integrated database was prepared in order to analyse all parameters acquired from the catalogues and references for each event. Within the scope of this study, the epicentral locations of M ≥ 5.0 events were firstly reappraised based on the updated Active Fault Map of Turkey. An improved catalogue of 12.674 events for the period 1900–2012 was as a result recompiled for the region between 32–45N° and 23–48E° by analyzing in detail accuracy of all seismological parameters available for each event. The events consist of M ≥ 4.0 are reported in several magnitude scales (e.g. moment magnitude, M_w; surface wave magnitude, M_S; body-wave magnitude m_b; local magnitude M_L and duration magnitude M_d) whereas the maximum focal depth reaches up to 225-km. In order to provide homogenous data, the improved catalogue is unified in terms of M_w. Fore-and aftershocks were also removed from the catalogue and completeness analyses were performed both separately for various tectonic sources and as a whole for the study region of interest. Thus, the prepared homogenous and declustered catalogue consisting of 6573 events provides the basis for a reliable input to the seismic hazard assessment studies for Turkey and its surrounding areas.