The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

Guided wave propagation in laterally varying media - II. Lg-waves in north-western Europe

Summary. Lg -wave observations at NORSAR from a sequence of explosions straddling the Central Graben in the North Sea, show that the phase is almost extinguished by passing through this structure. For models of the graben structure, based on seismic refraction experiments, with crustal thinning beneath a zone of thickened sediments, numerical modelling of Lg propagation shows very poor transmission. The inclusion of attenuation simulating the effects of scattering from faults and other complex structures further diminishes the transmittivity. The theoretical effect of a crustal pinch is to redistribute S energy over a wide range of groups velocities, a pattern that fits well with the observations.
Three components recordings at NORSAR of explosive charges fired in water covering a wide range of azimuths, show significant transverse components to the seismograms. The transverse energy builds up with travel time and for Lg is of the same order as the vertical component. These results are consistent with the theoretical prediction of progressive net transfer of energy from Rayleigh to Love modes as the wavetrain propagates through a three-dimensionally heterogeneous medium.     

VELOCITY DISPERSION OF SEISMIC WAVES*

In well velocity surveys made to calibrate Sonic (CV) Logs the calibration survey uses frequencies around 50 Hz whereas the Sonic Logging tool uses frequencies around 20 kHz. There thus exists the possibility of making a direct measure of velocity dispersion. In any one survey the disturbing factors, both instrumental and operational, will often mask any dispersive effect that might exist. Consequently this paper reports on a statistical analysis of the velocity differences resulting from calibration surveys and Sonic logs. Only Borehole Compensated Sonic Logs were used. Four areas were investigated: the North Sea, Abu Dhabi, Libya and Alaska. After rejecting logs and calibration records which were obviously in error there remained 424000 feet (about 130 km) of usable log distributed throughout 66 wells. The four areas were analysed separately and in no case was the estimated dispersion significantly different from zero. However, the mean values did correlate with lithology from (? 0.17 ± 0.18)% for the essentially carbonate section in Abu Dhabi to (+ 0.45 ± 0.25)% for the sand-shale section in Alaska, a positive sign meaning that the higher frequencies travelled faster. Except for Alaska the calibration surveys were made with a wall-clamp geophone, and for these areas amplitude measurements were made. After suitable corrections estimates of the absorption parameter Q were obtained. These varied from 20 to 200 with mean values of 63 for Libya, 70 for Abu Dhabi and 88 for the North Sea (excluding the Tertiary). If, as is usually assumed, the absorption mechanism is linear and is described by a Q which is independent of frequency, then these values would necessarily imply dispersion of several percent. As instanced above no such dispersion was observed. It is possible that the expected dispersion was compensated for by invasion of the mud filtrate into the borehole walls, but it is more likely that the absorption mechanism was substantially non-linear.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

The neotectonics and geodynamics of the Lower Oka Region (East European Craton)

The neotectonic structures of the Lower Oka (Nizhneokskii) Region formed under different geodynamic conditions. This is attested by the morphology, orientation, internal structure, and jointing of the structures. The Oka-Tsna arc formed under the effect of tension from an inner source on the one hand and stress from the Alpian belt on the other hand. The latitudinally-oriented structures of the northwestern slope of the Tokmovo arc emerged as a result of uplift and widening. Both types of structure are combined within the limits of the Oka-Murom trough, which is a geodynamically active zone.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Star counts in M15 onU,B andV plates

We present new counts of stars in M15, using plates inB, V andU. We are able to explore relatively close to the central parts of the cluster (0.1 pc) and we derive the best fitting parameters for the star distribution.     

Intrusive processes at ocean ridges: Evidence from the sheeted dyke complex of Masirah, Oman

Masirah Island largely consists of a late Mesozoic ophiolite which includes extensive areas of near-vertical, ENE—WSW striking, sheeted dykes. Previously the possibility has been suggested of a correlation between the similarly-aged ophiolites of Masirah and the Semail Complex of the Oman Mts. However, the Masirah ENE–WSW trend contrasts with N—S dyke trends from the Wadi Jizi area of the Semail, possibly suggesting two unrelated spreading centres. The dykes pass up into a pillow lava—minor sediment sequence, down into both layered and unlayered gabbros and are bounded to the west by a major N—S mélange zone which may have originated as a ridge transform fault. Age relations of the dykes and the gabbros are complex: the dykes contain a variable proportion of gabbro screens representing earlier crystallization, but they are also intruded by several small gabbro bodies which are themselves cut by still later dykes. The lava and dyke—gabbro screen sequence shows evidence of metamorphism from zeolite to low amphibolite grade. This metamorphism was caused by ridge hydrothermal activity which appears to have been effective approximately to the lower levels of the dykes. The rapid passage from low-amphibolite dykes to fresh gabbro suggests lithological control of the metamorphism. A combination of structural, geochemical and mineral phase studies may indicate generation in a slow spreading ridge environment and near-ridge metamorphism caused by a geothermal gradient of approximately 200°C/km.     

The reserves of extracted resources: Historical data

The available data on known reserves of extracted resources have not previously been tabulated and graphed. In this article we compile the reserves data in one place for the first time. This serves to (1) show the trends in the reserves series, (2) make the series available to others, and (3) place the reserves data in the context of price data for which longer series have been available, and with which they can now be seen to be consistent in both showing increasing availability rather than increasing scarcity.