The physical properties of quartz-micaschist and their application to freeze-thaw weathering studies in the maritime antarctic

As part of a study on freeze-thaw weathering in the maritime Antarctic an investigation was made of the physical properties of the local rock. Tests were made of point-load compressive strength, Schmidt hammer in situ rock strength, moisture content, indentor resistance and the size range of weathering products. The resulting data were used to consider the form of freeze-thaw weathering operative in the field and its relationship to laboratory simulations. A distinct difference between ‘massive rock’ and ‘intact rock’ is observed in the field. It is suggested that future studies should generate a greater database pertaining to rock properties as it is an invaluable aid in the study of mechanical weathering.     

Some exact solutions of unsteady boundary layer equations-I

Summary Unsteady boundary layer flows generated in a homogeneous, non-rotating viscous fluid are considered. The method of Laplace transform is used to obtain exact solutions of the unsteady boundary layer equations in a more general situation. The structures of the unsteady velocity field and the associated boundary layers are determined. Several particular solutions are recovered as special cases of the present general theory. The physical implications of the mathematical results are investigated.     

Non-linear earthquake response of concrete gravity dams part 1: Modelling

A finite element procedure to model the non-linear earthquake response of concrete gravity dam systems is presented. A two-dimensional idealization is adopted for the dam and water in order to simplify the analysis and reduce the computational effort. The foundation of the dam is modelled as a rigid rectangular massless plate attached to a three-dimensional viscoelastic half-space. The non-linear behaviour is represented by smearing techniques and includes tensile cracking with subsequent opening, closing and sliding, as well as water cavitation in the reservoir. Special treatments are applied to suppress spurious oscillations in the water response associated with cavitation and to prevent cracks in the dam from spreading into wide zones. Experience from non-linear analyses is cited as it affects the design of the algorithm.     

Two field applications of the rotating current EM method1

The rotating current EM method has been applied to the delineation of two conductive orebodies, Elura near Cobar, NSW, and Thalanga near Charter's Towers, Queensland. The field data were collected in the form of observations of the vertical magnetic field strength ratio and phase difference using a Turam-style receiver with twin vertical coils. By reconstituting this data back to the ring source field and phase, i.e. the observed H_z, phasor, it is possible to present contoured maps of the EM field. Anomaly phasors are obtained by subtracting theoretical phasors from the observed phasors in the complex plane of the H_z phasor. The theoretical phasors for the finite source are based on horizontally layered, half-space earth models, computed at each point of the survey grids, then normalized to selected points of the observed fields. Use is made of the intrinsic circular symmetry of the method in X–Y plots of field versus source-receiver distance to ascertain geoelectric parameters for the earth models. A steel picket fence at Thalanga is modelled by a line source grounded at each end and its H_z, phasor is removed by the same process. A considerable improvement in anomaly delineation is gained over previous Turam-style anomalies and the two survey examples illustrate the limitations of the method in the presence of a conductive overburden (Elura) and its abilities in the absence of a conductive overburden (Thalanga).     

Dissolved and particulate trace metals in a Scottish sea loch: an example of a pristine environment?

In the near pristine environment of a silled fjord on the west coast of Scotland samples were taken for the determination of dissolved and particulate trace metals (Fe, Mn, Cu, Ni, Cd, Zn and Pb), together with nutrient and hydrographic data, during 19 surveys carried out over a year. An indication of the pristine nature of the environment are the low concentrations of dissolved silicon, phosphate and nitrate which are considerably lower than those of coastal waters which are subject to larger anthropogenic burdens. Distributions of dissolved Cu, Ni and Cd were found to broadly reflect conservative mixing of freshwater and seawater with both end members having similar concentrations. The concentration of dissolved Cu and Ni in seawater entering upper Loch Linnhe (Cu 0.28 μg l⁻¹; Ni 0.26 μg l⁻¹) was consistent with the 1:1 conservative mix of Irish Sea water and North Atlantic surface water predicted from radio-caesium tracer experiments (Mackay & Baxter, 1985). Atmospheric input of trace metals to upper Loch Linnhe appeared to be a relatively minor term in the mass balance relative to fluvial inputs. Values of distribution coefficients Kd were similar to those previously reported for the coastal environment. Iron showed the strongest affinity for the suspended sediments; with particulate percentages of the total load usually greater than 80%. Lead and Mn showed a similar strong affinity to the particle phase. For Cu, Ni and Zn the mass of the element in the dissolved phase was generally greater than that in the particulate fraction. Cadmium, was least associated with the particles, with typically greater than 90% existing in the dissolved phase.     

Evolution of the late Pleistocene Mojanda–Fuya Fuya volcanic complex (Ecuador), by progressive adakitic involvement in mantle magma sources

The Mojanda–Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of viscous Si-rich andesitic lavas and dacitic domes, and the emission of a thick sequence of pyroclastic-flow and fallout deposits which include two voluminous rhyolitic layers. An intermediate construction phase at Fuya Fuya is represented by a mainly effusive cone, andesitic in composition (San Bartolo edifice), the construction of which was interrupted by a major sector collapse in the Late Pleistocene. Finally, a complex of thick siliceous lavas and domes was emplaced within the avalanche amphitheatre, forming the Upper Fuya Fuya volcanic centre. This paper shows that the general evolution from an effusive to an explosive eruptive style is related to a progressive adakitic contribution to the magma source. Although all the rocks of the complex are included in the medium-K field of continental arcs, the Fuya Fuya suite (61–75 wt.% SiO₂) shows depletion in Y and HREE and high Sr/Y and La/Yb values, compared to the less silicic Mojanda suite (55–66.5 wt.% SiO₂). The Mojanda calc-alkaline suite was generated by partial melting of an adakite-metasomatised mantle source that left a residue with 2% garnet, followed by fractional crystallization of dominant plagioclase + pyroxene + olivine at shallow, intra-crustal depths. For Fuya Fuya, geochemical and mineralogical data suggest either (1) partial melting of a similar metasomatised mantle with more garnet in the residue (4%), followed by fractional crystallization involving plagioclase, amphibole and pyroxene, or (2) mixing of mafic mantle-derived magma from the Mojanda suite and slab melts, followed by the same fractional crystallization process.     

The relationship of Irgarol and its major metabolite to resident phytoplankton communities in a Maryland marina, river and reference area

The objectives of this study were to: (1) measure water column concentrations of Irgarol 1051 and its major metabolite GS26575 annually (2004-2006) during mid-June and mid-August at 14 sites in a study area comprised of three sub-regions chosen to reflect a gradient in Irgarol exposure (Port Annapolis marina, Severn River and Severn River reference area); (2) use a probabilistic approach to determine ecological risk of Irgarol and its major metabolite in the study area by comparing the distribution of exposure data with toxicity-effects endpoints; and (3) measure both functional and structural resident phytoplankton parameters concurrently with Irgarol and metabolite concentrations to assess relationships and determine ecological risk at six selected sites in the three study areas described above. The three-year summer mean Irgarol concentrations by site clearly showed a gradient in concentrations with greater values in Back Creek (400-500 ng/L range), lower values in the Severn River sites near the confluence with Back Creek (generally values less than 100 ng/L) and still lower values (<10 ng/L) at the Severn River reference sites at the confluence with Chesapeake Bay. A similar spatial trend, but with much lower concentrations, was also reported for GS26575. The probability of exceeding the Irgarol plant 10th centile of 193 ng/L and the microcosm NOEC (323 ng/L) suggested high ecological risk from Irgarol exposure at Port Annapolis marina sites but much lower risk at the other sites. There were no statistically significant differences among the three site types (marina, river and reference) with all years combined or among years within a site type for the following functional and structural phytoplankton endpoints: algal biomass, gross photosynthesis, biomass normalized photosynthesis, chlorophyll a, chlorophyll a normalized photosynthesis and taxa richness. Therefore, based on the above results, Irgarol adverse effects predicted from the plant 10th centile and the microcosm NOEC in the high Irgarol exposure area (Back Creek/Port Annapolis marina) were not confirmed with the actual field data for the receptor species (phytoplankton). These results also highlight the importance of unconfined field studies with a chemical gradient in providing valuable information regarding the responses of resident phytoplankton to herbicides.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

MODAL ANALYSIS OF AIRPHOTO LINEARS,CENTRAL IDAHO

Approximately 3,000 airphoto linears from an 8,300 km² area of central Idaho are plotted, classified for azimuthal orientation, counted for frequency, and measured for length. Dominant linear orientations, weighted for length, are compared to equivalent central tendency measures for joints, dikes, and foliation. Variations in linear density are also compared to differing lithologies. Statistical analysis reveals the following: (1) the dominant lineation mode is statistically independent of the dominant foliation mode; (2) no statistically significant difference exists between the dominant lineation mode and the average directional mode of dikes; (3) no statistically significant difference exists between the dominant lineation mode and the average directional mode of joints; (4) linear frequency is statistically independent of lithology. Visual comparison of raised relief maps with the isopleth map of directionally dominant linears reveals a pronounced correspondence between those areas exhibiting strong structural control over landforms and highs on the isopleth surface.