A methane fuse for the Cambrian explosion: carbon cycles and true polar wander

The dramatic diversification of animal groups known as the Cambrian Explosion (evolution's ‘Big Bang’) remains an unsolved puzzle in Earth Science. The Vendian–Cambrian interval is characterized by anomalously high rates of apparent plate motion, interpreted as True Polar Wander (TPW), and by more than a dozen large, high-frequency perturbations in carbon isotopes that dwarf all others observed through the past 65 million years. We suggest that these biological, tectonic, and geochemical events are intimately related in the following fashion. First, tropical continental margins and shelf-slopes which formed during fragmentation of the supercontinent Rodinia accumulated massive quantities of isotopically-light organic carbon during Late Neoproterozoic time, as indicated by strikingly heavy isotope ratios in inorganic carbon during interglacial intervals. Second, an initial phase of Vendian TPW moved these organic-rich deposits to high latitude, where conditions favored trapping biogenic methane in layers of gas hydrate and perhaps permafrost. Continued sedimentation during Late Vendian time added additional hydrate/gas storage volume and stabilized underlying units until the geothermal gradient moved them out of the clathrate stability field, building up deep reservoirs of highly pressurized methane. Finally, a burst of TPW brought these deposits back to the Tropics, where they gradually warmed and were subjected to regional-scale thermohaline eddy variation and related sedimentation regime changes. Responding to the stochastic character of such changes, each reservoir reached a critical failure point independently at times throughout the Cambrian. By analogy with the Late Paleocene Thermal Maximum event, these methane deposits yield transient, greenhouse-induced pulses of global warming when they erupt. Temperature correlates powerfully with biodiversity; the biochemical kinetics of metabolism at higher temperature decrease generation time and maintain relatively rich and dense invertebrate populations. Repeated thermal pulses along with progressive disruption and alteration of global ocean circulation patterns by TPW could cause the increase in diversity that accompanied the radiation of metazoans. We suggest that a methane ‘fuse’ ignited the Cambrian Evolutionary Explosion.     

A geopotential error analysis for a non planar satellite to satellite tracking mission

This study is concerned with gravity field recovery from low-low satellite to satellite range rate data. Compared against a coplanar mission an improvement is predicted in errors associated with certain parts of the geopotential by the separation of the orbital planes of the two satellites. Using Hill's equations an analytical scheme is developed to model the range rate residuals. It is flexible enough to model the residuals between pairs of satellites in the same orbital plane or whose planes are separated in right ascension. This scheme should allow the possibility of larger planar separations than previously since no small angle approximation is made. The effects of such an orientation on gravity field recovery can therefore be analysed by means of an extensive error analysis. The results of this analysis indicate that a significant improvement in the errors of the near sectorial coefficients are obtained when the satellite's orbital planes are separated. Received: 9 April 1996; Accepted: 26 September 1996     

Carbon cycling in a shallow turbid estuary of southeast Texas: The use of plant pigment biomarkers and water quality parameters

Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l^?1) and particulate organic carbon (1.1 mg l^?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l^?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l^?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources.     

The glacilacustrine sedimentary environment of Bowser Lake in the northern Coast Mountains of British Columbia, Canada

Bowser Lake, a fiord lake in the northern Coast Mountains of British Columbia, contains a thick Holocene fill consisting mainly of silt and clay varves. These sediments were carried into the lake by proglacial Bowser River which drains a high-energy, heavily glacierized basin. Sedimentation in the lake is controlled by seasonal snow and ice melt, by autumn rainstorms, and by rare, but very large jökulhlaups from glacier-dammed lakes in the upper Bowser River basin which complicate environmental inferences from the sedimentary record. Sediment is dispersed through the deep western part of the lake by energetic turbidity currents. The turbidity currents apparently do not overtop a sill that separates the western basin from much shallower areas to the east. Large amounts of silt and clay are deposited from suspension in the eastern part of the lake, but sediment accumulation rates there are much lower than to the west. Several strong acoustic reflectors punctuate the varved fill in the western basin; these may be thick or relatively coarse beds deposited during jökulhlaups or exceptionally large storms. The contemporary sediment yield to Bowser Lake, estimated from sediments in the lake, is about 360 t km^-2a^-1. This is a relatively high value, but it is less than yields insome other, similar montane basins with extensive snow and ice cover.The most likely explanation for the difference is that large amounts of sediment have been, and continue to be, stored on the Bowser delta andin small proglacial lakes.     

Modelling of soil temperature profiles using data from the pilot experiment at Anand

We present some preliminary results from a multi-layer soil temperature finite-difference model using the data set obtained during the pilot experiment on land surface processes at Anand. We hope that the present results will prove useful during the final field experiments scheduled for the coming monsoon season.     

Harmonic Analysis of Sedimentary Cyclic Sequences in Kansas, Midcontinent, USA

Several stratigraphic sequences in the Upper Carboniferous (Pennsylvanian) in Kansas (Midcontinent, USA) were analyzed quantitatively for periodic repetitions. The sequences were coded by lithologic type into strings of datasets. The strings then were analyzed by an adaptation of a one-dimensional Fourier transform analysis and examined for evidence of periodicity. The method was tested using different states in coding to determine the robustness of the method and data. The most persistent response is in multiples of 8–10 ft (2.5–3.0 m) and probably is dependent on the depositional thickness of the original lithologic units. Other cyclicities occurred in multiples of the basic frequency of 8–10 with persistent ones at 22 and 30 feet (6.5–9.0 m) and large ones at 80 and 160 feet (25–50 m). These levels of thickness relate well to the basic cyclothem and megacyclothem as measured on outcrop. We propose that this approach is a suitable one for analyzing cyclic events in the stratigraphic record.     

Comparative study of activation energies of conductance and desiccation rates of some marine algae

Measurements of the activation energy of electrical conductance and desiccation rates on subtidal marine algae from Florida were compared to similar data from the Bay of Fundy, Nova Scotia, on intertidal marine algae frequently subjected to long periods of exposure to air. We have developed a method for calculating the reaction rate constant of desiccation of fully hydrated marine algae. Values of activation energies and desiccation rate constants are consistent with the requirements for survival of these algae under widely different environmental conditions.     

Hydrological connectivity of soil pipes determined by ground‐penetrating radar tracer detection

Soil pipes are common and important features of many catchments, particularly in semi‐arid and humid areas, and can contribute a large proportion of runoff to river systems. They may also signi?cantly in?uence catchment sediment and solute yield. However, there are often problems in ?nding and de?ning soil pipe networks which are located deep below the surface. Ground‐penetrating radar (GPR) has been used for non‐destructive identi?cation and mapping of soil pipes in blanket peat catchments. While GPR can identify subsurface cavities, it cannot alone determine hydrological connectivity between one cavity and another. This paper presents results from an experiment to test the ability of GPR to establish hydrological connectivity between pipes through use of a tracer solution. Sodium chloride was injected into pipe cavities previously detected by the radar. The GPR was placed downslope of the injection points and positioned on the ground directly above detected soil pipes. The resultant radargrams showed signi?cant changes in re?ectance from some cavities and no change from others. Pipe waters were sampled in order to check the radar results. Changes in electrical conductivity of the pipe water could be detected by the GPR, without data post‐processing, when background levels were increased by more than approximately twofold. It was thus possible to rapidly determine hydrological connectivity of soil pipes within dense pipe networks across hillslopes without ground disturbance. It was also possible to remotely measure travel times through pipe systems; the passing of the salt wave below the GPR produced an easily detectable signal on the radargram which required no post‐processing. The technique should allow remote sensing of water sources and sinks for soil pipes below the surface. The improved understanding of ?owpath connectivity will be important for understanding water delivery, solutional and particulate denudation, and hydrological and geomorphological model development. Copyright © 2004 John Wiley & Sons, Ltd.     

Wildlife management and land reform in southeastern Zimbabwe: a compatible pairing or a contradiction in terms?

This paper examines the melding of two discourses in southeastern Zimbabwe: land reform and wildlife management. The former seeks to redistribute large, ‘under-utilized’ landholdings to smallholders whilst the latter needs extensive land holdings to be viable. These two discourses are rooted in very different models of development. The land reform exercise emphasizes direct redistribution, equity and land for crops; whilst the wildlife management discourse tends to stress maximizing foreign exchange earnings, encouraging public-private partnerships and trickle down. Yet there has been a recent flurry of interest in the development of ‘wildlife models’ for land reform which would combine the two. This paper investigates whether the competing discourses about land for smallholders and wildlife-based land reform are compatible or can be successfully reconciled. It traces the ways they have come together in Zimbabwe’s southeast lowveld and examines the ‘science’ and politics underlying their melding. Finally it explores the potential implications for rural people’s livelihoods of this development. It concludes that land reform and wildlife management can be reconciled, but probably not in a particularly equitable way: it is more likely to provide an opening for an equitable land reform agenda to be usurped by local and non-local elites with wildlife interests.     

Environmental geochemistry of Zarshuran Au-As deposit, NW Iran

Zarshuran deposit is the most famous and important As-Au mine in Iran. However, there is no information on the impact of mining activity on the surrounding environment, especially on water systems. This paper attempts to document the concentration of arsenic and associated elements in waters and sediments resulting from the mining history of Zarshuran, a period covering hundreds of years. Water and sediment samples collected from Zarshuran Stream indicate high content of some potentially toxic elements, especially of As which ranges from 0.028 to 40 ng/l in water and 182 to 36,000 mg/kg in sediment samples. Mining activity, exposure of a large volume of mining wastes to weathering, and the anomalously high background of trace metals in the mining area are considered to be the main sources of heavy metal pollution.