Mercury and methylmercury in water and sediment of the Sacramento River Basin, California

Mercury (Hg) and methylmercury (CH₃Hg⁺) concentrations in streambed sediment and water were determined at 27 locations throughout the Sacramento River Basin, CA. Mercury in sediment was elevated at locations downstream of either Hg mining or Au mining activities where Hg was used in the recovery of Au. Methylmercury in sediment was highest (2.84 ng/g) at a location with the greatest wetland land cover, in spite of lower total Hg at that site relative to other river sites. Mercury in unfiltered water was measured at 4 locations on the Sacramento River and at tributaries draining the mining regions, as well as agricultural regions. The highest levels of Hg in unfiltered water (2248 ng/l) were measured at a site downstream of a historic Hg mining area, and the highest levels at all sites were measured in samples collected during high streamflow when the levels of suspended sediment were also elevated. Mercury in unfiltered water exceeded the current federal and state recommended criterion for protection of aquatic life (50 ng/l as total Hg in unfiltered water) only during high streamflow conditions. The highest loading of Hg to the San Francisco Bay system was attributed to sources within the Cache Creek watershed, which are downstream of historic Hg mines, and to an unknown source or sources to the mainstem of the Sacramento River upstream of historic Au mining regions. That unknown source is possibly associated with a volcanic deposit. Methylmercury concentrations also were dependent on season and hydrologic conditions. The highest levels (1.98 ng/l) in the Sacramento River, during the period of study, were measured during a major flood event. The reactivity of Hg in unfiltered water was assessed by measuring the amount available for reaction by a strong reducing agent. Although most Hg was found to be nonreactive, the highest reactivity (7.8% of the total Hg in water) was measured in the sample collected from the same site with high CH₃Hg⁺ in sediment, and during the time of year when that site was under continual flooded conditions. Although Hg concentrations in water downstream of the Hg mining operations were measured as high as 2248 ng/l during stormwater runoff events, the transported Hg was found to have a low potential for geochemical transformations, as indicated by the low reactivity to the reducing agent (0.0001% of the total), probably because most of the Hg in the unfiltered water sample was in the mercury sulfide form.     

Integrated scenarios of acidification and climate change in Asia and Europe

Two integrated assessment models, one for climate change on a global scale (IMAGE 2) and another for the regional analysis of the impacts of acidifying deposition (RAINS), have been linked to assess the impacts of reducing sulphur emission on ecosystems in Asia and Europe. While such reductions have the beneficial effect of reducing the deposition of acidifying compounds and thus the exceedance of critical loads of ecosystems, they also reduce the global level of sulphate aerosols and thus enhance the impact of increased emissions of greenhouse gases, and consequently increase the risk of potential vegetation changes. The calculations indicate that about 70% of the ecosystems in Asia would be affected by either acid deposition or climate change in the year 2100 (up from 20% in 1990) for both sulphur emission scenarios (controlled and uncontrolled), whereas in Europe the impacted area would remain at a level of about 50%, with a dip early next century. More generally, the effects of reducing sulphur emissions and thus enhancing climate change would about balance for the Asian region, whereas for Europe the desirable impact of sulphur emission reductions would greatly outweigh its undesirable effects.     

Sources and paleoclimatic significance of Holocene Bignell Loess, central Great Plains, USA

This paper reexamines the stratigraphy, sources, and paleoclimatic significance of Holocene Bignell Loess in the central Great Plains. A broadly similar sequence of loess depositional units and paleosols was observed in thick Bignell Loess sections up to 300 km apart, suggesting that these sections record major regional changes in the balance between dust deposition and pedogenesis. New optical ages, together with previously reported radiocarbon ages, indicate Bignell Loess deposition began 9000–11,000 yr ago and continued into the late Holocene; some Bignell Loess is <1000 yr old. There is little evidence that Holocene Loess was derived from flood plain sources, as previously proposed. Instead, thick Bignell Loess occurs mainly near the downwind margins of inactive dune fields, particularly atop escarpments facing the dunes. Thus, the immediate loess source was dust produced when the dunes were active. Previous work indicates that widespread episodes of dune activity are likely to have resulted from drier-than-present climatic conditions. The regionally coherent stratigraphy of Bignell Loess can be interpreted as a near-continuous record of climatically driven variation in dune field activity throughout the Holocene.     

Xixth International Congress of Photogrammetry and Remote Sensing

The XIXth International Congress of Photogrammetry and Remote Sensing was held at the Amsterdam RAI International Exhibition and Congress Centre, the Netherlands, from 16th to 23rd July 2000. Reports are given on the Congress as a whole, including the General Assembly, some Technical Commission activities and the Congress Exhibition. Papers from the Congress are published in the International Archives of Photogrammetry and Remote Sensing, 33.     

Simulation of desert-scrub growth: A forcing to warmer and more pluvial climate

Desert-fringe vegetation growing over bright, sandy soils reduces the surface albedo from above 0.4 to well be-low 0.3. Called desert-scrub, these shrubs form a predominantly vertical clumps protruding from the soil-level, thereby significantly increasing the coefficient of turbulent heat transfer from the surface. The impact on global and desert-belt climate of changes in these two surface characteristics was simulated by a multi-layer energy balance model. Evaluated only as a forcing to a further climatic change (that is, without accounting for any possible feedbacks) the results are: if vegetation (such as apparently existed under the warmer climate of 6,000 BP) grows over large areas in the arid, currently bare-soil regions, the annual Northern Hemisphere surface temperature increases by 0.7oC (by 0.6oC in July ), the surface temperature over land in the 20-30oN zone increases by 0.9oC in both the annual and the July means, and the land-ocean annual temperature contrast in this zone increases by 0.25oC (0.2oC in July). These results represent the combined influence of the reduction in the surface albedo and of the increase in the coefficient of turbulent heat transfer. In the desert-belt zones, the increase in the transfer coefficient sharply reduces the land temperature and the land-ocean temperature contrast from the values produced by the albedo change alone. This reduction must be attributed to the increased land-to-ocean circulation (which our model does not evaluate ex-plicitly). Considering that a stronger circulation (resulting from land-ocean temperature contrast) generally forces a higher rainfall, the vegetation which emerged in the arid regions during the post-glacial optimum should be consid-ered a. significant positive feedback towards a still warmer, and also a more pluvial, climate. Our study may have im-plications for the 21st century, if the global warming expected from the enhanced greenhouse effects is accompanied by increased precipitation over the continents.     

Rare earth elements,iron formations and sea water

Iron formations probably formed as chemical sediments when an Fe-rich solution entered the sedimentary environment. The REE patterns of such sediments are affected by the amount and type of precipitating and detrital phases, the REE pattern of the iron source solution, the REE pattern of the sea water into which the solution flows, and the mixing which takes place between input solution and sea water. What is known about the different types of iron formation suggests that all of these factors may vary from one type to another. Therefore, variations in REE patterns cannot be attributed solely to changes in sea water REE patterns. Comparison of the REE patterns of Archean and Ordovician iron formations of the Algoma type shows that similar iron formations have similar REE patterns regardless of age. This implies similar genetic histories.     

Distribution of viral and bacterial pathogens in a coastal canal community

Significant concentrations of human enteric viruses and bacteria were found to be present in the water and sediment of a coastal canal community into which secondarily treated sewage was being discharged.     

Great-circle Rayleigh wave attenuation and group velocity,Part I: Observations for periods between 150 and 600 seconds for seven great-circle paths

Rayleigh wave attenuation coefficients and group velocities have been estimated for seven great-circle paths. The attenuation coefficient measurements cover the period range from 100 to 500 s, and group velocities the range from 100 to 600 s. Global average group velocities and attenuation coefficients have also been estimated for these period ranges. The spread of the individual path group velocities for 20-s averaging windows centred at 290, 250, 210, 180 and 150 s is less than 0.034, 0.028, 0.024, 0.048 and 0.071 km/s, respectively. Global average attenuation coefficients, when combined with global average group velocities, show that Q for Rayleigh waves has an approximately constant value of about 145 for periods between 150 and 220 s and slowly increases to a value of about 200 at a period of 400 s.