Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.     

Comparison of AMSR-2 wind speed and sea surface temperature with moored buoy observations over the Northern Indian Ocean

The Northern Indian Ocean (NIO) is unique due to seasonal reversal of wind patterns, the formation of vortices and eddies which make satellite observations arduous. The veracity of sea surface wind (SSW) and sea surface temperature (SST) products of sun-synchronous AMSR-2 satellite are compared with high-temporal moored buoy observations over the NIO. The two year-long (2013–2014) comparisons reveal that the root-mean-square-error (RMSE) of AMSR-2 SST and SSW is \(<0.4{^{\circ }}\hbox {C}\) and \(<1.5\hbox { ms}^{-1}\), respectively, which are within the error range prescribed for the AMSR-2 satellite (\(\pm 0.8{^{\circ }}\hbox {C}\), \(\pm 1.5\hbox { ms}^{-1})\). The SST–wind relation is analyzed using data both from the buoy and satellite. As a result, the low-SST is associated with low-wind condition (positive slope) in the northern part of the Bay of Bengal (BoB), while low SST values are associated with high wind conditions (negative slope) over the southern BoB. Moreover, the AMSR-2 displayed larger slope for SST–wind relation and could be mainly due to overestimation of SST and underestimation of wind as compared to the buoy. The AMSR-2 SSW exhibited higher error during post-monsoon followed by monsoon season and could be attributed to the high wind conditions associated with intense oceanic vortices. The study suggests that the AMSR-2 products are reliable and can be used in tropical air–sea interactions, meso-scale features, and weather and climate studies.     

Application of infinite slope analysis to subaqueous sediment instability,Mississippi delta

Submarine landslides are described on very low angle slopes (0.5°–1.7°) in the Mississippi prodelta area and are evaluated using infinite slope analysis. For instability to occur, pore water pressure ratios in excess of hydrostatic (u/γ_wz) and approaching geostatic (u/γ′z) are needed. These calculated values, based on three sets of effective strength parameters and for two sediment depths to failure, are in close agreement with measured pore water pressure data from in situ piezometers. Ratios of (u/γ′z) as large as 0.986 have been monitored. Mud vents are also indicative of large internal pressures within the sediments, generated by rapid sedimentation, wave perturbation, and biogenic methane. The analysis suggests that the reduction in effective stress may be sufficient to cause failure by gravitational stresses alone.     

Land use change assessment in coastal mangrove forests of Iran utilizing satellite imagery and CA–Markov algorithms to monitor and predict future change

Mangrove forest stores large organic carbon stocks in a setting that is highly vulnerable to climate change and direct anthropogenic influences. As such there is a need to elucidate the causes and consequences of land use change on these ecosystems that have high value in terms of ecosystem services. We examine the areal pattern of land types in a coastal region located in southern Iran over a period of 14 years to predict future loss and gain in land types to the year 2025. We applied a CA–Markov model to simulate and predict mangrove forest change. Landsat satellite images from 2000 to 2014 were used to analyze the land cover changes between soil, open water and mangroves. Major changes during this period were observed in soil and water which could be attributed to rising sea level. Furthermore, the mangrove area in the more seaward position was converted to open water due to sea-level rise. A cellular automata model was then used to predict the land cover changes that would occur by the year 2025. Results demonstrated that approximately 21 ha of mangrove area will be converted to open water, while mangroves are projected to expand by approximately 28 ha in landward direction. These changes need to be delineated to better inform precise mitigation and adaptation measures.     

Excess air during aquifer storage and recovery in an arid basin (Las Vegas Valley, USA)

The Las Vegas Valley Water District in Nevada, USA, has operated an artificial recharge (AR) program since 1989. In summer 2001, observations of gas exsolving from tap water prompted a study that revealed total dissolved gas (TDG) pressures approaching 2?atm with a gas composition that it is predominantly air. Measurements of TDG pressure at well heads and in the distribution system indicated two potential mechanisms for elevated TDG pressures: (1) air entrainment during AR operations, and (2) temperature changes between the winter recharge season and the summer withdrawal season. Air entrainment during pumping was investigated by intentionally allowing the forebay (upstream reservoir) of a large pumping station to drawdown to the point of vortex formation. This resulted in up to a 0.7?atm increase in TDG pressure. In general, the solubility of gases in water decreases as the temperature increases. In the Las Vegas Valley, water that acquired a modest amount of dissolved gas during winter artificial recharge operations experienced an increase in dissolved gas pressure (0.04?atm/°C) as the water warmed in the subsurface. A combination of air entrainment during AR operations and its amplification by temperature increase after recharge can account for most of the observed amounts of excess gas at this site.     

Understanding governance and networks: EU-US interactions and the regulation of genetically modified organisms

EU-US (European Union-United States) interactions in relation to the regulation of genetically modified organisms (GMOs) have been examined in detail in recent years. To do this scholars have tended to focus on a small number of high profile processes, such as the formal complaint of the US to the World Trade Organisation regarding the regulation of GMOs in the Europe. It is important to analyse developments of this kind but overemphasis on them has also lead to a distorted view of the case and a failure to appreciate the significance of other, less visible, types of interaction. In this paper we focus instead on trying to understand the roles played by various EU-US transnational networks—The Transatlantic Business Dialogue, The Transatlantic Economic Partnership, The Transatlantic Consumer Dialogue, The Transatlantic Environmental Dialogue and the EU-US Consultative Forum on Biotechnology. These networks have been trying to shape the regulation of GMOs in both jurisdictions since the mid 1990s. By analysing them through a ‘governance lens’ we find that we can better understand EU-US interactions and the dynamics and influences around the regulation of GMOs. This gives us valuable insights into processes of contemporary governance.     

A coupling of mixed and discontinuous Galerkin finite-element methods for poroelasticity

In this paper, we formulate a finite-element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. We approximate the flow variables by a mixed finite-element space and the displacement by a family of discontinuous Galerkin methods. Theoretical convergence error estimates are derived and, in particular, are shown to be independent of the constrained specific storage coefficient, c _o . This suggests that our proposed algorithm is a potentially effective way to combat locking, or the nonphysical pressure oscillations, which sometimes arise in numerical algorithms for poroelasticity.     

Origin and evolution of the Steamboat Springs siliceous sinter deposit, Nevada, U.S.A.

Siliceous hot spring deposits from Steamboat Springs, Nevada, U.S.A., record a complex interplay of multiple, changing, primary environmental conditions, fluid overprinting and diagenesis. Consequently these deposits reflect dynamic geologic and geothermal processes. Two surface sinters were examined—the high terrace, and the distal apron-slope, as well as 13.11 m (43 ft) of core material from drill hole SNLG 87-29. The high terrace sinter consists of vitreous and massive-mottled silica horizons, while the distal deposit and core comprise dominantly porous, indurated fragmental sinters. Collectively, the three sinter deposits archive a complete sequence of silica phase diagenetic minerals from opal-A to quartz. X-ray powder diffraction analyses and infrared spectroscopy of the sinters indicate that the distal apron-slope consists of opal-A and opal-A/CT mineralogy; the core yielded opal-A/CT and opal-CT with minor opal-A; and the high terrace constitutes opal-C, moganite, and quartz. Mineralogical maturation of the deposit produced alternating nano–micro–nano-sized silica particle changes. Based on filament diameters of microbial fossils preserved within the sinter, discharging thermal outflows fluctuated between low-temperatures (< 35 °C, coarse filaments) and mid-temperatures ( 35–60 °C, fine filaments). Despite transformation to quartz, primary coarse and fine filaments were preserved in the high terrace sinter. AMS ¹⁴C dating of pollen from three horizons within core SNLG 87-29, from depths of 8.13 to 8.21 m (26′8″ to 26′11″), 10.13 to 10.21 m (33′3″ to 33′6″), and 14.81 to 14.88 m (48′7″ to 48′10″), yielded dates of 8684 ± 64 years, 11,493 ± 70 years and 6283 ±60 years, respectively. In the upper section of the core, the stratigraphically out-of-sequence age likely reflects physical mixing of younger sinter with quartzose sinter fragments derived from the high terrace. Within single horizons, mineralogical and morphological components of the sinter matrix were spatially patchy. Overall, the deposit was modified by sub-surface flow of alkali-chloride thermal fluids depositing a second generation of silica, and periodically, by acidic steam condensate formed during periods when the water table was low. Local faulting produced considerable fracturing of the sinter. Hence, the Steamboat Springs sinter experienced a complex history of primary and secondary hydrothermal, geologic and diagenetic events, and their inter-relationships and effects are locked within the physical, chemical and biological signatures of the deposit.     

Emission spectrographic estimation of gold

A procedure for estimating minute quantities (parts per billion) of gold is described, based on dissolution of the sample in aqua regia, adsorption on activated charcoal, arcing of the charcoal ash, and measurement of the intensity of the emitted spectra.