Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.     

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.     

Use of Rhodamine water tracer in the marshland upwelling system

Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS.     

Effects of trace metal and exposure to air on serotonin and dopamine levels in tissues of the mussel Perna perna

We evaluated levels of serotonin (5HT) and dopamine (DOPA) in muscle and digestive glands of the mussel, Perna perna, collected at different times of day; exposed to air for 24 h, followed by re-submersion; and after exposure to different metals. Mussels collected at different periods of day showed little oscillation in 5HT and DOPA levels. Mussels exposed to metals showed significant changes in 5HT and DOPA levels in digestive gland and muscle, as did mussels exposed to air. Our data suggest that analyses of 5HT and DOPA in tissues of mussels could serve as a tool to evaluate the presence and effects of heavy metal contamination in mussels. Care in data interpretation is required, however, since other environmental factors such as exposure of mussels to air (i.e. at low tides) can also cause changes in DOPA and 5HT levels. Additional research is necessary to separate such natural environmental effects from effects of contaminants.     

Pressure covariability over the Atlantic,Europe and N. Africa. application: Centers of action for temperature,winter precipitation and summer winds in Athens,Greece

Summary This paper deals with the surface pressure covariability over the Altantic/European sector of the Northern Hemisphere, using monthly grid point data for the 100 year period 1890–1989. Factor analysis is applied to 90 grid point time series for January, February, July, and August. The initial 90 pressure variables can be reduced to 7–8 factors in winter and 10 in summer. A winter teleconnection was identified, known as the seesaw phenomenon, between the Icelandic low and the Azores subtropical anticyclone. In order to define the centers of action for temperature, winter precipitation and summer northerly wind frequency (etesian days) in Athens and in the Aegean sea, the variability of the factor scores and of these weather elements is compared. It is shown that the center of action for temperature in Athens is found to be in north and northwest Europe (centered over southern Scandinavia). For winter precipitation, the center of action is located in the west and southwest Mediterranean and northwest Africa. Finally, for the etesian winds frequency variability, this center of action is found over the northern Adriatic and northern former Yugoslavia, while there is no evidence of influence by the southwest Asia thermal low.With 12 Figures     

Climate Change Impacts on Urban Flooding

This paper estimates changes in thepotential damage of flood events caused by increasesof CO₂ concentration in the atmosphere. It ispresented in two parts: 1. the modelling of floodfrequency and magnitude under global warming andassociated rainfall intensities and 2. the use ofgreenhouse flood data to assess changes in thevulnerability of flood prone urban areas, expressingthese in terms of direct losses.Three case studies were selected: theHawkesbury–Nepean corridor, the Queanbeyan and UpperParramatta Rivers. All three catchments are located insoutheastern Australia, near Sydney and Canberra.These were chosen because each had detailed buildingdata bases available and the localities are situatedon rivers that vary in catchment size andcharacteristics. All fall within a region that willexperience similar climate change under the availablegreenhouse scenarios. The GCMs' slab model scenariosof climate change in 2030 and 2070 will cause onlyminor changes to urban flood damage but the doubleCO₂ scenarios estimated using the StochasticWeather Generator technique will lead to significantincreases in building damage.For all the case studies, the hydrological modellingindicates that there will be increases in themagnitude and frequency of flood events under thedouble CO₂ conditions although these vary fromplace to place. However, the overall pattern of changeis that for the Upper Parramatta River the 1 in 100-year flood under currentconditions becomes the 1 in44-year event, the 1 in 35-year flood for theHawkesbury–Nepean and the 1 in 10 for Queanbeyan andCanberra. This indicates the importance of usingrainfall-runoff modelling in order to estimate changesin flood frequencies in catchments with differentphysical characteristics.     

Sensitivity of the Earth’s radiation budget to interannual variations in cloud amount

 Using two pairs of coincident long-term satellite derived cloud and earth radiation budget data sets (Nimbus-7 ERB/Nimbus-7 Cloud Climatology and ERBE Scanner/ISCCP-C2), estimates are made of the sensitivity of the top of the atmosphere radiation budget to interannual variations in the total cloud amount. Both sets of analyses indicate that the largest net warming due to interannual cloud cover changes occurs over desert regions, while the largest net cooling occurs in areas of persistent marine stratiform cloud. There is generally a large amount of cancellation between the large shortwave cooling and longwave warming effects in tropical convection regions. However, the Nimbus-7 analysis identifies an area of net warming in the tropical eastern Pacific Ocean which is shown to be associated with the 1982–83 ENSO event. In the zonal mean the Nimbus-7 data sets indicate that interannual cloud cover changes lead to a net warming at low latitudes and net cooling polewards of 25° in both hemispheres. In contrast, the analysis of the ERBE and ISCCP data sets indicates net cooling everywhere except for the Northern Hemisphere equatorwards of 20 °N. For the spatial average between 60 °N and 60 °S the ratio of the shortwave and longwave effects is 0.94 in the Nimbus-7 analysis (i.e. clouds cause a small net warming) and 1.21 in the ERBE-ISCCP analysis (i.e. a net cooling). Given their improved spatial and temporal sampling the analysis using the ERBE and ISCCP data sets should be the more reliable. However, the large differences between the two analyses still raises some issues concerning the confidence with which the sign of the effect of clouds on the radiation budget at these time scales is currently known. Received: 24 October 1995 / Accepted: 8 August 1996     

Estimation of Surface-Layer Scaling Parameters in the Unstable Boundary Layer: Implications for Orographic Flow Speed-Up

A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer.     

The meteorological observations of Bento Sanches Dorta, Rio de Janeiro, Brazil: 1781–1788

Bento Sanches Dorta was an astronomer and geographer in the Portuguese colony of Rio de Janeiro in Brazil from 1781 to 1788. He recorded daily readings of meteorological and geomagnetic variables during that period. This dataset provides, to the best of our knowledge, the earliest known continuous 8-year-long instrumental meteorological observations for any South American site. His data show that the winters in this period were relatively cool, and that 1785 was the rainiest and hottest year, and 1787 the driest and coolest. The records display a distinct seasonal cycle and a variability that are comparable with the modern data.     

Principal Components Analysis of Rainfall and Associated Synoptic Models of the Southwest Monsoon over India

Summary  The summer monsoon circulation shows various spatial and temporal oscillations and often a combination of systems produces an integrated effect. In this study phases of the southwest (SW) monsoon have been identified in an objective manner with the help of T-mode principal component analysis (PCA) of weekly rainfall anomalies. Mean composite charts have been prepared utilising all available upper air data (1977–1986) for each category of the SW monsoon epochs identified by the PCA. These sets of charts have been constructed for both the strong and weak phases associated with the first four significant principal components (PCs). A well defined east-west oriented trough system, extending from about 28° N Latitude/65° E Longitude to 20° N Latitude/90° E Longitude, in the lower levels, has been the main feature associated with the strong phase of the monsoon corresponding to PC I. The trough in the lower levels is more marked in the eastern half compared to the western half in both the sets of charts associated with strong phases of the monsoon related to the PC II and PC III. With PC II, the position of the troughs in the lower levels is further north of its location in PC III. The east-west trough system associated with the strong phase of PC IV has a large southward tilt with height. The charts corresponding to the weak phases of these PCs have synoptic features, such as the position of the trough close to the foothills of the Himalayas, and the shifting of middle and upper tropospheric anticyclones to the south. The study suggests an objective method of interpretation of principal components by utilising synoptic data. In addition, synoptic models and data sets corresponding to different phases of the monsoon can also be prepared in an objective manner by such PCA. Received July 18, 1997 Revised April 30, 1999