Numerical simulation of three-dimensional tidal current in the Bobal Sea

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Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.     

Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

The alleged kimberlite-carbonatite relationship: evidence from ilmenite and spinel from Premier and Wesselton mines and the Benfontein sill,South Africa

Carbonate-rich, SiO₂-poor residua are developed in some kimberlites solidifying as ocelli, layers, or discrete dikes which satisfy petrographic definitions of carbonatite. Arguments that these rocks have mineralogies, antecedents, and comagmatic rocks differing from those of the carbonatites in alkaline rock complexes, including the specific observation that kimberlites and carbonatites contain ilmenites and spinels of different composition, have been used to refute the alleged kimberlite-carbonatite relationship. New microprobe analyses of ilmenites and spinels from carbonate-rich rocks associated with kimberlites in three South African localities correspond to spinels and ilmenites of carbonatites from alkalic complexes, or have characteristics intermediate between those of carbonatites and kimberlites. The ilmenites are distinguished from kimberlite ilmenites by higher MnO, FeTiO₃, and Nb₂O₅, and by negligible Cr₂O₃. The spinels are distinguished from kimberlite spinels by their Al₂O₃ and Cr₂O₃ contents. There is clearly a genetic relationship between the kimberlites and the carbonate-rich rocks, despite the observation that their ilmenites and spinels are distinctly different, which indicates that the same observation is not a valid argument against a petrogenetic relationship between kimberlites and carbonatites. These rocks are among the diverse products from mantle processes influenced by CO₂, and we believe that the petrogenetic links among them are forged in the upper mantle. We see insufficient justification to deny the name carbonatite to carbonate-rich rocks associated with kimberlites if they satisfy the petrographic definition in terms of major mineralogy.     

The middle Pleistocene transition: characteristics, mechanisms, and implications for long-term changes in atmospheric pCO2

The emergence of low-frequency, high-amplitude, quasi-periodic (100-kyr) glacial variability during the middle Pleistocene in the absence of any significant change in orbital forcing indicates a fundamental change internal to the climate system. This middle Pleistocene transition (MPT) began 1250 ka and was complete by 700 ka. Its onset was accompanied by decreases in sea surface temperatures (SSTs) in the North Atlantic and tropical-ocean upwelling regions and by an increase in African and Asian aridity and monsoonal intensity. During the MPT, long-term average ice volume gradually increased by 50 m sea-level equivalent, whereas low-frequency ice-volume variability experienced a 100-kyr lull centered on 1000 ka followed by its reappearance 900 ka, although as a broad band of power rather than a narrow, persistent 100-kyr cycle. Additional changes at 900 ka indicate this to be an important time during the MPT, beginning with an 80-kyr event of extreme SST cooling followed by the partial recovery and subsequent stabilization of long-term North Atlantic and tropical ocean SSTs, increasing Southern Ocean SST variability primarily associated with warmer interglacials, the loss of permanent subpolar sea-ice cover, and the emergence of low-frequency variability in Pacific SSTs and global deep-ocean circulation. Since 900 ka, ice sheets have been the only component of the climate system to exhibit consistent low-frequency variability. With the exception of a near-universal organization of low-frequency power associated with marine isotope stages 11 and 12, all other components show an inconsistent distribution of power in frequency-time space, suggesting a highly nonlinear system response to orbital and ice-sheet forcing.Most hypotheses for the origin of the MPT invoke a response to a long-term cooling, possibly induced by decreasing atmospheric pCO₂. None of these hypotheses, however, accounts for the geological constraint that the earliest Northern Hemisphere ice sheets covered a similar or larger area than those that followed the MPT. Given that the MPT was associated with an increase in ice volume, this constraint requires that post-MPT ice sheets were substantially thicker than pre-MPT ice sheets, indicating a change in subglacial conditions that influence ice dynamics. We review evidence in support of the hypothesis that such an increase in ice thickness occurred as crystalline Precambrian Shield bedrock became exposed by glacial erosion of a thick mantle of regolith. This exposure of a high-friction substrate caused thicker ice sheets, with an attendant change in their response to the orbital forcing. Marine carbon isotope data indicate a rapid transfer of organic carbon to inorganic carbon in the ocean system during the MPT. If this carbon came from terrigenous sources, an increase in atmospheric pCO₂ would be likely, which is inconsistent with evidence for widespread cooling, Apparently rapid carbon transfer from terrestrial sources is difficult to reconcile with gradual erosion of regolith. A more likely source of organic carbon and nutrients (which would mitigate pCO₂ rise) is from shelf and upper slope marine sediments, which were fully exposed for the first time in millions of years in response to thickening ice sheets and falling sealevels during the MPT. Modeling indicates that regolith erosion and resulting exposure of crystalline bedrock would cause an increase in long-term silicate weathering rates, in good agreement with marine Sr and Os isotopic records. We use a carbon cycle model to show that a post-MPT increase in silicate weathering rates would lower atmospheric pCO₂ by 7–12 ppm, suggesting that the attendant cooling may have been an important feedback in causing the MPT.     

Comparative study of As,Cd, Cu,Cr, Mg,Mn, Ni,Pb and Zn concentrations between sediment and water from estuary and port

The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).     

Palynological Evidence for Climatic Change and Human Activity during the Holocene on Minorca (Balearic Islands)

Four pollen diagrams from Minorca (Balearic Islands) have been correlated with other previously studied sequences from Majorca and Minorca to define a Holocene landscape sequence for the region from 8000 yr B.P. to the present. The lower part of the pollen diagrams reflects a climatic phase with more rain and less-marked seasonality than today. Significant quantities ofCorylus, Buxus,and mesophilous taxa are found. In the middle part, between 5000 and 4000 yr B.P., a strong change is recorded in composition and structure of the vegetational landscape, with vegetation appearing that was adapted to Mediterranean conditions. This episode coincided with the first human colonization of the island and also with a widespread climatic change in the western Mediterranean region. The change in taxa was complex and some sclerophyllous taxa suchOleaplayed an important role in the transformation of the landscape physiognomy from the mid-Holocene until the present. Although human activities have removed much of the Mediterranean vegetation on the Balearic Islands, it seems clear that the changes have been brought about, in part, by increasing dryness.     

Horizontal dynamic stiffness of pile groups: Approximate expressions

A number of solutions and computer programs are already available to determine the dynamic stiffness of complete pile foundations, assuming linear elastic soil behavior and perfect bonding between the piles and the surrounding soil. These are assumptions that would be generally valid for properly designed machine foundations where very small strains should be expected. A number of approximate formulations have also been developed. Among these the most commonly used one is that proposed by Poulos (1971) [12] for the static case, computing interaction coefficients between the heads of two piles considered by themselves, then forming a matrix of these coefficients to obtain the interaction between the heads of all the piles in the group. Additional approximations have been suggested, particularly for the computation of the interaction coefficients, using closed form expressions. In this paper, approximate expressions that can be used for preliminary estimates, at the very early stages of the design, without the need of computers, are presented. They are intended for pile groups with pile spacing of the order of 3 diameters, typical relations between the modulus of elasticity of the piles and that of the soil between 100 and 1000, and very small amplitude vibrations.     

Future change of climate in South America in the late twenty-first century: intercomparison of scenarios from three regional climate models

Regional climate change projections for the last half of the twenty-first century have been produced for South America, as part of the CREAS (Cenarios REgionalizados de Clima Futuro da America do Sul) regional project. Three regional climate models RCMs (Eta CCS, RegCM3 and HadRM3P) were nested within the HadAM3P global model. The simulations cover a 30-year period representing present climate (1961–1990) and projections for the IPCC A2 high emission scenario for 2071–2100. The focus was on the changes in the mean circulation and surface variables, in particular, surface air temperature and precipitation. There is a consistent pattern of changes in circulation, rainfall and temperatures as depicted by the three models. The HadRM3P shows intensification and a more southward position of the subtropical Pacific high, while a pattern of intensification/weakening during summer/winter is projected by the Eta CCS/RegCM3. There is a tendency for a weakening of the subtropical westerly jet from the Eta CCS and HadRM3P, consistent with other studies. There are indications that regions such of Northeast Brazil and central-eastern and southern Amazonia may experience rainfall deficiency in the future, while the Northwest coast of Peru-Ecuador and northern Argentina may experience rainfall excesses in a warmer future, and these changes may vary with the seasons. The three models show warming in the A2 scenario stronger in the tropical region, especially in the 5°N–15°S band, both in summer and especially in winter, reaching up to 6–8°C warmer than in the present. In southern South America, the warming in summer varies between 2 and 4°C and in winter between 3 and 5°C in the same region from the 3 models. These changes are consistent with changes in low level circulation from the models, and they are comparable with changes in rainfall and temperature extremes reported elsewhere. In summary, some aspects of projected future climate change are quite robust across this set of model runs for some regions, as the Northwest coast of Peru-Ecuador, northern Argentina, Eastern Amazonia and Northeast Brazil, whereas for other regions they are less robust as in Pantanal region of West Central and southeastern Brazil.     

Variability of ozone in the marine boundary layer of the equatorial Pacific Ocean

This study examines the processes controlling the diurnal variability of ozone (O₃) in the marine boundary layer of the Kwajalein Atoll, Republic of the Marshall Islands (latitude 8° 43′ N, longitude 167° 44′ E), during July to September 1999. At the study site, situated in the equatorial Pacific Ocean, O₃ mixing ratios remained low, with an overall average of 9–10 parts per billion on a volume basis (ppbv) and a standard deviation of 2.5 ppbv. In the absence of convective storms, daily O₃ mixing ratios decreased after sunrise and reached minimum during the afternoon in response to photochemical reactions. The peak-to-peak amplitude of O₃ diurnal variation was approximately 1–3 ppbv. During the daytime, O₃ photolysis, hydroperoxyl radicals, hydroxyl radicals, and bromine atoms contributed to the destruction of O₃, which explained the observed minimum O₃ levels observed in the afternoon. The entrainment of O₃-richer air from the free troposphere to the local marine boundary layer provided a recovery mechanism of surface O₃ mixing ratio with a transport rate of 0.04 to 0.2 ppbv per hour during nighttime. In the presence of convection, downward transport of O₃-richer tropospheric air increased surface O₃ mixing ratios by 3–12 ppbv. The magnitude of O₃ increase due to moist convection was lower than that observed over the continent (as high as 20–30 ppbv). Differences were ascribed to the higher O₃ levels in the continental troposphere and weaker convection over the ocean. Present results suggest that moist convection plays a role in surface-level O₃ dynamics in the tropical marine boundary layer.