Refining the estimation of metal loads dissolved in acid mine drainage by continuous monitoring of specific conductivity and water level

The accurate estimation of metal loads transported by streams is necessary to calculate reliable mass transfers of metals between compartments, both at local and global scales. This estimation is particularly relevant in the case of the Tinto and Odiel Rivers (SW Spain) due to their significant contribution to the total metal transfer from continents to the ocean. At a local scale, the metal load transported by streams plays a key role in predicting the biogeochemical evolution of water reservoirs affected by Acid Mine Drainage (AMD). This work uses the relationships between specific conductivity (SC) and dissolved elements to calculate the metal load of the River Meca, a tributary of the Odiel. The SC and the water level were continuously monitored from April 2009 to June 2010. Water samples were also collected and measurements of the discharge were carried out manually once a month. The relationships between the SC and the concentration of dissolved elements are, in general, very good (R² > 0.90). However, some key elements such as Fe show a very poor correlation. A simple methodology based on the MIX code (a maximum likelihood method to estimate mixing ratios) was used to elucidate their different behaviours. During the dry period (April–December, 2009) the Fe concentration was lower than that deduced from the SC recorded value due to the precipitation of Fe-oxihydroxides, which also reduced the concentrations of As, Cr, Pb and, to a lesser extent, Cu. At the same time Na, Sr, Ca and Li were enriched because of the higher interaction with the riverbed materials. Correlations between the SC and the metal concentration improved significantly when each period was considered separately. A second dry period (April–June 2010) shows high SC values, although no dissolution/precipitation of solid phases is evidenced. This indicates that SC alone is not enough to predict the dissolved metal loads in Mediterranean AMD streams. The metal load transported by the River Meca was determined for the hydrological year 2009/10 as 1933 ± 129 tonnes of Fe, 990 ± 155 of Al and 378 ± 41 of Zn.     

Evaluating Kinematic Controls on Planar Translational Slope Failure Mechanisms Using Three-Dimensional Distinct Element Modelling

This paper investigates the importance of kinematic release mechanisms on planar translational slope failure using three-dimensional distinct element codes. The importance of the dip and dip direction of the rear, basal and lateral release surfaces and their influence on failure mechanism, dilation, and the development of step-path failures is illustrated. The three-dimensional block shape and volume of the unstable rock masses simulated with the different discontinuity set geometries are characterized. Two assumed three-dimensional slope models are investigated in order to assess the importance of varying kinematic confinement/release mechanisms. These two assumed boundary conditions are shown to be critical in the development of asymmetrical rock mass deformation patterns. Scale effects due to the block size and discontinuity persistence are shown to control the calculated displacement and failure mechanisms. The numerical modelling results are also demonstrated to be sensitive to the assumed normal and shear stiffness of the discontinuities. The influence of the factors investigated on the failure of a single rock block versus a rock mass are compared and discussed.     

Mountain glaciation and paleoclimate reconstruction in the Picos de Europa (Iberian Peninsula,SW Europe)

Geomorphic mapping and stratigraphic analysis of a lake core document the late Quaternary glacial history of the Central and Eastern Massifs of the Picos de Europa, northwestern Spain. The distribution of glacial deposits indicates that at their most advanced positions glaciers occupied 9.1 km², extended as far as 7 km down-valley and had an estimated equilibrium-line altitude (ELA) ranging between 1666 and 1722 m. Radiocarbon dating of sediment deposited in a lake dammed by moraines of this advance show that the maximum glacial extent was prior to 35,280 ± 440 cal yr BP. This advance was followed by two subsequent but less extensive late Pleistocene advances, recorded by multiple moraines flanking both massifs and sedimentary characteristics in the lake deposits. The last recognized glacial episode is the 19th-century maximum extent of small Little Ice Age glaciers in the highest cirques above 2200 m.     

The impact of African aridity on the isotopic signature of Atlantic deep waters across the Middle Pleistocene Transition

A high resolution analysis of benthic foraminifera as well as of aeolian terrigenous proxies extracted from a 37 m-long marine core located off the Mauritanian margin spanning the last ~ 1.2 Ma, documents the possible link between major continental environmental changes with a shift in the isotopic signature of deep waters around 1.0–0.9 Ma, within the so-called Mid-Pleistocene Transition (MPT) time period. The increase in the oxygen isotopic composition of deep waters, as seen through the benthic foraminifera δ¹⁸O values, is consistent with the growth of larger ice sheets known to have occurred during this transition. Deep-water mass δ¹³C changes, also estimated from benthic foraminifera, show a strong depletion for the same time interval. This drastic change in δ¹³C values is concomitant with a worldwide 0.3‰ decrease observed in the major deep oceanic waters for the MPT time period. The phase relationship between aeolian terrigeneous signal increase and this δ¹³C decrease in our record, as well as in other paleorecords, supports the hypothesis of a global aridification amongst others processes to explain the deep-water masses isotopic signature changes during the MPT. In any case, the isotopic shifts imply major changes in the end-member δ¹⁸O and δ¹³C values of deep waters.     

Land Use History and Site Formation Processes at the Punic Site of Pauli Stincus in West Central Sardinia

The site of Pauli Stincus is located near the town of Terralba, on the inland shores of the Gulf of Oristano in west central Sardinia, Italy, and was occupied between the mid‐4th and the late 2nd century B.C. The site and its surroundings were the object of a joint archaeopedological and geomorphological study, which complemented the data from archaeological excavations. This study allowed us to evaluate the suitability of the different landscape and soil components for crop production in the Punic period. The discovery of a buried plow soil at the site's edge enabled us to identify a set of agricultural practices carried out by Punic farmers. These included the removal of sandy topsoil to cultivate deeper horizons enriched in illuvial clay, the use of a "sodbuster" or "rip ard," and the periodic burning of weeds, stubble, and other harvesting residues. The present study helped us to better understand the formation processes of the archaeological record at Pauli Stincus. Large quantities of allochtonous calcareous material were imported to the site from wet areas closer to the coast in order to produce earth‐based construction material, such as bricks and daub. © 2013 Wiley Periodicals, Inc.     

Considerations for modeling burn probability across landscapes with steep environmental gradients: an example from the Columbia Mountains, Canada

Fire and land management in fire-prone areas can be greatly enhanced by estimating the likelihood of fire at every point on the landscape. In recent years, powerful fire simulation models, combined with an in-depth understanding of an area’s fire regime and fire environment, have allowed forest managers to estimate spatial burn probabilities. This study describes a methodology for selecting input data and model parameters when creating burn probability maps in difficult-to-model areas and reports the results of a case study for a large area of the Columbia Mountains, British Columbia, Canada. In addition to having particularly mountainous topography, the study area is covered by vegetation types that are poorly represented in fire behavior systems, even though these vegetation types have experienced considerable (if highly irregular) fire activity in premodern times (before 1920). Parameterization of the fire environment for simulation modeling was accomplished by combining various types of fire information (e.g., fire history studies, reconstructed fire climatologies), new technologies (high-resolution remotely sensed data, wind flow modeling), and—a must in data-limited areas—ample expert advice. In this study, we made extensive use of personal accounts from experienced fire behavior officers for the creation of model inputs. Despite difficulties in validating outputs of burn probability models, the multisource model-building approach described here provides a conservative, yet informative, means of estimating the likelihood of fire. Due to the data-intensive nature of the modeling and paucity of input data, an argument is made that modelers must focus on the inputs that are the most influential for their study area.     

Methodology and applications for the benefit cost analysis of the seismic risk reduction in building portfolios at broadscale

This article presents a methodology for an estimate of the benefit cost ratio of the seismic risk reduction in buildings portfolio at broadscale, for a world region, allowing comparing the results obtained for the countries belonging to that region. This methodology encompasses (1) the generation of a set of random seismic events and the evaluation of the spectral accelerations at the buildings location; (2) the estimation of the buildings built area, the economic value, as well as the classification in structural typologies; (3) the development of vulnerability curves for each typology; (4) the estimation of the annual average loss of the buildings portfolio in the current conditions as well as in the case of a hypothetical structural intervention. The benefit cost ratio is estimated as the difference between the estimates of the present value of these two annual average losses, divided by the retrofitting costs. This methodology has been applied to the portfolio of public schools of 14 countries of Latin America and the Caribbean, for evaluating the feasibility of the seismic risk reduction at a national scale.     

Granite emplacement by crustal boudinage: example of the Calmayo and El Hongo plutons (Córdoba,Argentina)

This study deals with the structure and emplacement of the Calmayo and El Hongo trondhjemite plutons (Famatinian belt of Córdoba, Argentina). It provides structural data from the granites and the country rocks and a study of the magnetic fabric in the plutons. New U/Pb geochronological data yield intrusion ages of 512.1 ± 3.4 Ma and 500.6 ± 4.5 Ma for the Calmayo and El Hongo plutons respectively. The El Hongo massif and the southern part of the Calmayo trondhjemite preserve magmatic structures, whereas the northern domain of Calmayo shows the imprint of solid‐state deformation. The main foliation in the country rocks outlines a boudin‐like pattern at the map scale and the granites are located along boudin necks, suggesting that the emplacement of these trondhjemite plutons was linked to large‐scale boudinage of the country rocks.