Sulfur isotope variations from orebody to hand-specimen scale at the Mežica lead–zinc deposit, Slovenia: a predominantly biogenic pattern

The Mississippi Valley-type (MVT) Pb–Zn ore district at Mežica is hosted by Middle to Upper Triassic platform carbonate rocks in the Northern Karavanke/Drau Range geotectonic units of the Eastern Alps, northeastern Slovenia. The mineralization at Mežica covers an area of 64 km² with more than 350 orebodies and numerous galena and sphalerite occurrences, which formed epigenetically, both conformable and discordant to bedding. While knowledge on the style of mineralization has grown considerably, the origin of discordant mineralization is still debated. Sulfur stable isotope analyses of 149 sulfide samples from the different types of orebodies provide new insights on the genesis of these mineralizations and their relationship. Over the whole mining district, sphalerite and galena have δ ³⁴ S values in the range of –24.7 to –1.5‰ VCDT (–13.5 ± 5.0‰) and –24.7 to –1.4‰ (–10.7 ± 5.9‰), respectively. These values are in the range of the main MVT deposits of the Drau Range. All sulfide δ ³⁴ S values are negative within a broad range, with δ ³⁴ S _pyrite <δ ³⁴ S _sphalerite <δ ³⁴ S _galena for both conformable and discordant orebodies, indicating isotopically heterogeneous H₂S in the ore-forming fluids and precipitation of the sulfides at thermodynamic disequilibrium. This clearly supports that the main sulfide sulfur originates from bacterially mediated reduction (BSR) of Middle to Upper Triassic seawater sulfate or evaporite sulfate. Thermochemical sulfate reduction (TSR) by organic compounds contributed a minor amount of ³⁴S-enriched H₂S to the ore fluid. The variations of δ ³⁴ S values of galena and coarse-grained sphalerite at orefield scale are generally larger than the differences observed in single hand specimens. The progressively more negative δ ³⁴ S values with time along the different sphalerite generations are consistent with mixing of different H₂S sources, with a decreasing contribution of H₂S from regional TSR, and an increase from a local H₂S reservoir produced by BSR (i.e., sedimentary biogenic pyrite, organo-sulfur compounds). Galena in discordant ore (–11.9 to –1.7‰; –7.0 ± 2.7‰, n = 12) tends to be depleted in ³⁴ S compared with conformable ore (–24.7 to –2.8‰, –11.7 ± 6.2‰, n = 39). A similar trend is observed from fine-crystalline sphalerite I to coarse open-space filling sphalerite II. Some variation of the sulfide δ ³⁴ S values is attributed to the inherent variability of bacterial sulfate reduction, including metabolic recycling in a locally partially closed system and contribution of H₂S from hydrolysis of biogenic pyrite and thermal cracking of organo-sulfur compounds. The results suggest that the conformable orebodies originated by mixing of hydrothermal saline metal-rich fluid with H₂S-rich pore waters during late burial diagenesis, while the discordant orebodies formed by mobilization of the earlier conformable mineralization.     

Chemostratigraphy of the Tamengo Formation (Corumbá Group,Brazil): A contribution to the calibration of the Ediacaran carbon-isotope curve

The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ¹³C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ¹³C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ¹³C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ¹³C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.     

Groundwater recharge in irrigated semi-arid areas: quantitative hydrological modelling and sensitivity analysis

For semi-arid regions, methods of assessing aquifer recharge usually consider the potential evapotranspiration. Actual evapotranspiration rates can be below potential rates for long periods of time, even in irrigated systems. Accurate estimations of aquifer recharge in semi-arid areas under irrigated agriculture are essential for sustainable water-resources management. A method to estimate aquifer recharge from irrigated farmland has been tested. The water-balance-modelling approach was based on VisualBALAN v. 2.0, a computer code that simulates water balance in the soil, vadose zone and aquifer. The study was carried out in the Campo de Cartagena (SE Spain) in the period 1999–2008 for three different groups of crops: annual row crops (lettuce and melon), perennial vegetables (artichoke) and fruit trees (citrus). Computed mean-annual-recharge values (from irrigation+precipitation) during the study period were 397 mm for annual row crops, 201 mm for perennial vegetables and 194 mm for fruit trees: 31.4, 20.7 and 20.5% of the total applied water, respectively. The effects of rainfall events on the final recharge were clearly observed, due to the continuously high water content in soil which facilitated the infiltration process. A sensitivity analysis to assess the reliability and uncertainty of recharge estimations was carried out.     

Appraising stone column settlement prediction methods using finite element analyses

Numerous approaches exist for the prediction of the settlement improvement offered by the vibro-replacement technique in weak or marginal soil deposits. The majority of the settlement prediction methods are based on the unit cell assumption, with a small number based on plane strain or homogenisation techniques. In this paper, a comprehensive review and assessment of the more popular settlement prediction methods is carried out with a view to establishing which method(s) is/are in best agreement with finite element predictions from a series of PLAXIS 2D axisymmetric analyses on an end-bearing column. The Hardening Soil Model in PLAXIS 2D has been used to model the behaviour of both the granular column material and the treated soft clay soil. This study has shown that purely elastic settlement prediction methods overestimate the settlement improvement for large modular ratios, while the methods based on elastic–plastic theory are in better agreement with finite element predictions at higher modular ratios. In addition, a parameter sensitivity study has been carried out to establish the influence of a range of different design parameters on predictions obtained using a selection of elastic–plastic methods.     

Influence of size on the constitutive equations of concrete or rock dowels

The numerical fracture analysis of non‐homogeneous rock or concrete dowels subjected to shear and compression is described in detail. The method of analysis allows the consideration of scale and rate effects due to material non‐homogeneity and fracture. The proposed approach is verified by comparing numerical predictions with experimental results reported in the literature for a series of small rock samples, since experimental evidence for large bodies is not yet available (2007). Results generated by Monte Carlo simulation using the so‐called discrete element method to model the dowels suggest that a simple three parameters law can be used to predict the relationship between tangential stress at the base and lateral distortion. It is observed that the larger the size of the cubes, the smaller both the peak tangential stress and the rupture distortion. Size effects are also evaluated in samples with vertical restraint. The influence of loading rate is likewise numerically assessed for two sample sizes. The effect is compatible with experimental evidence available for concrete using small samples. Copyright © 2008 John Wiley & Sons, Ltd.     

Sporadic meteor sources as observed by the Jicamarca high-power large-aperture VHF radar

We present, for the first time, the main sources of sporadic meteors as inferred from meteor-head echoes obtained by a high-power large-aperture radar (HPLAR). Such results have been obtained at the Jicamarca HPLAR (11.95° S, 76.87° W, 1° dip angle). Observations are based on close to 170,000 meteors detected in less than 90 h spread over 14 days, between November 2001 and February 2006. Meteors with solar orbits are observed to come from basically six previously known sources, i.e., North and South Apex, Helion, Anti-Helion, and North and South Toroidal, representing ∼91% of the observations. The other ∼9% represents meteors with observed velocities greater than the Sun's escape velocity at 1 AU, most of them of extra-solar origin. Results are given before and after removing the Earth's velocity and the sources are modeled with two-dimensional Gaussian distributions. In general, our results are in very good agreement with previously known sources reported by Jones and Brown [Jones, J., Brown, P.G., 1993. Mon. Not. R. Astron. Soc. 265, 524-532] using mainly specular meteor radar (SMR) data gathered over many years and different sites. However, we find slightly different locations and widths, that could be explained on the basis of different sensitivities of the two techniques and/or corrections needed to our results. For example, we find that the North and South Apex sources are well defined and composed each of them of two collocated Gaussian distributions, one almost isotropic with ∼10° width and the other very narrow in ecliptic longitude and wide in ecliptic latitude. This is the first time these narrow-width sources are reported. A careful quantitative analysis is needed to be able to compare the strengths of meteor sources as observed with different techniques. We also present speed and initial altitude distributions for selected sources. Using a simple angular sensitivity function of the combined Earth-atmosphere-radar instrument, and an altitude selection criteria, the resulting meteor sources are in better qualitative agreement with the results obtained with SMRs.     

Putative Meteoritic Craters in Río Cuarto (Central Argentina) Interpreted as Eolian Structures

Ten oblong aligned depressions in the Río Cuarto area (provincia de Córdoba, Argentina) were supposed to be the result of very-low-angle Holocene meteoroid impacts. However, we consider that authors that studied the structures did not demonstrated their extraterrestrial origin. We suggest that an eolian origin for the structures of Río Cuarto is more likely. Actually, these landforms integrate large systems of similar deflation/accumulation geoforms aligned according to predominant winds during different periods.     

Raman spectroscopic analysis of cyanobacterial colonization of hydromagnesite, a putative martian extremophile

Raman spectra of an extremophile cyanobacterial colony in hydromagnesite from Lake Salda in Turkey have revealed a biogeological modification which is manifest as aragonite in the stratum associated with the colony. The presence of key spectral biomarkers of organic protectant molecules such as β-carotene and scytonemin indicate that the survival strategy of the cyanobacteria is significantly one of UV-radiation protection. The terrestrial location of this extremophile is worthy of consideration further because of its possible putative link with the “White Rock” formations in Sabaea Terra and Juventae Chasma on Mars.     

Astrometry in the Kerr field inPPN approximation

The equation of motion written down using a metric obtained from the Kerr metric allows us to get both the deflection angle of light ray bending by the gravitational field of the Sun and its corresponding time delay. We reproduce the experimental data of Epstein-Shapiro and also it is in accordance with the theoretical results obtained by Brumberget al. (1990) using another approach to this problem.Presented at the 2nd UN/ESA Workshop, held in Bogotá, Colombia, 9–13 November, 1992.