The use of GPR and VES in delineating a contamination plume in a landfill site: a case study in SE Brazil

This paper presents the results of the application of the Ground Penetrating Radar (GPR) method, or Georadar, in outlining a zone of contamination due to solid residues at the waste burial site of Rio Claro in the state of São Paulo, SE Brazil. A total of eight GPR profiles with 50- and 100-MHz antennae were surveyed. Six profiles were located within the landfill site and the remaining two were outside. The main objective of the GPR survey was to evaluate the side extension of contamination. A Vertical Electric Sounding (VES) survey was performed at four points within the site in order to investigate the vertical extent of the contamination plume and to define the bottom of the landfill. Two additional VESs were done outside the landfill with the purpose of determining the top of the ground water table and the geoelectric stratigraphy of the background. From the interpretation of the GPR profiles, it was possible to locate the top of the contamination plume and to infer that it was migrating laterally beyond the limits of the waste disposal site. This was observed along the profile situated close to the highway SP-127, which was about 20 m from the limit of the site. The signature of the contaminant appears as a discontinuous reflector that is believed to be a shallow ground water table. The discontinuity is marked by a shadow zone, which is characteristic of conductive contaminant residues. The contamination did not move far enough to reach a sugar cane plantation located at approximately 100 m from the border of the site. In the regions free from contamination, the ground water table was mapped at approximately 10 m of depth, and it was characterized by a strong and continuous reflector. The radar signal penetrated deep enough and enabled the identification of a second reflector at approximately 14 m deep, interpreted as the contact between the Rio Claro and the Corumbataí formations. The contact is marked by the presence of gravel characterized by ferruginous concretes, which cause the strong amplitude reflection in the GPR profile. Within the landfill site, the quantitative interpretation of the VES results showed the contamination zone. The base of the landfill varies between 11 and 15 m deep. Outside the landfill site, the VES results showed no indication of contamination and allowed the determination of the top of the ground water table and the contact between the Rio Claro and the Corumbataí formations. The results of GPR and VES showed a good agreement and the integrated interpretations were supported by local geology and information from several boreholes, about 17 m depth, on average. The bottom of the landfill reaches a maximum of 14.5 m depth.     

Assessing land use/cover changes: a nationwide multidate spatial database for Mexico

A nationwide multidate GIS database was generated in order to carry out the quantification and spatial characterization of land use/cover changes (LUCC) in Mexico. Existing cartography on land use/cover at a 1:250,000 scale was revised to select compatible inputs regarding the scale, the classification scheme and the mapping method. Digital maps from three different dates (the late 1970s, 1993 and 2000) were revised, evaluated, corrected and integrated into a GIS database. In order to improve the reliability of the database, an attempt was made to assess the accuracy of the digitalisation procedure and to detect and correct unlikely changes due to thematic errors in the maps. Digital maps were overlaid in order to generate LUCC maps, transition matrices and to calculate rates of conversion. Based upon this database, rates of deforestation between 1976 and 2000 were evaluated as 0.25 and 0.76% per year for temperate and tropical forests, respectively.     

Submillimeter-wave and observations of the event on 28 November, 2001

We present a detailed study of a 1B/M6.9 impulsive flare combining high time resolution (1 ms) and instantaneous emission source localization observations at submillimeter frequencies (212 GHz), obtained with the solar submillimeter telescope (SST), and Hα data from the Hα solar telescope for argentina (HASTA). The flare, starting at 16:34 UT, occurred in active region (AR) 9715 (NOAA number) on November 28, 2001, and was followed by an Hα surge. We complement our data with magnetograms from the Michelson Doppler Imager (SOHO/MDI). SST observed a short impulsive burst at 212 GHz, presenting a weak bulk emission (of about 90 sfu) composed of a few shorter duration structures. The integrated Hα and the 212 GHz light curves present a remarkable agreement during the impulsive phase of the event. The delay between both curves stays below 12 s (the time resolution of the Hα telescope). The flare as well as the surge are linked to new flux emergence very close to the main AR bipole. Taking into account the AR magnetic field evolution, we infer that magnetic field reconnection, occurring at low coronal levels, could have been at the origin of the flare; while in the case of surge this would happen at the chromospheric level.     

Correcting the Smoothing Effect of Ordinary Kriging Estimates

The smoothing effect of ordinary kriging is a well-known dangerous effect associated with this estimation technique. Consequently kriging estimates do not reproduce both histogram and semivariogram model of sample data. A four-step procedure for correcting the smoothing effect of ordinary kriging estimates is shown to be efficient for the reproduction of histogram and semivariogram without loss of local accuracy. Furthermore, this procedure provides a unique map sharing both local and global accuracies. Ordinary kriging with a proper correction for smoothing effect can be revitalized as a reliable estimation method that allows a better use of the available information.     

Chemical and carbon isotopic evolution of hydrocarbons during prograde metamorphism from 100°C to 550°C: Case study in the Liassic black shale formation of Central Swiss Alps

Hydrocarbon distributions and stable isotope ratios of carbonates (δ¹³C_car, δ¹⁸O_car), kerogen (δ¹³C_ker), extractable organic matter (δ¹³C_EOM) and individual hydrocarbons of Liassic black shale samples from a prograde metamorphic sequence in the Swiss Alps were used to identify the major organic reactions with increasing metamorphic grade. The studied samples range from the diagenetic zone (<100°C) to amphibolite facies (∼550°C). The samples within the diagenetic zones (<100 and 150°C) are characterized by the dominance of C_<20n-alkanes, suggesting an origin related with marine and/or bacterial inputs. The metamorphic samples (200 to 550°C) have distributions significantly dominated by C₁₂ and C₁₃n-alkanes, C₁₄, C₁₆ and C₁₈n-alkylcyclopentanes and to a lesser extend C₁₅, C₁₇ and C₂₁n-alkylcyclohexanes. The progressive ¹³C-enrichment (up to 3.9‰) with metamorphism of the C_>17n-alkanes suggests the occurrence of cracking reactions of high molecular weight compounds. The isotopically heavier (up to 5.6‰) C_<17n-alkanes in metamorphic samples are likely originated by thermal degradation of long-chain homologous with preferential release of isotopically light C₁ and C₂ radicals. The dominance of specific even C-number n-alkylcyclopentanes suggests an origin related to direct cyclization mechanism (without decarboxylation step) of algal or bacterial fatty acids occurring in reducing aqueous metamorphic fluid conditions. The regular increase of the concentrations of n-alkylcycloalkanes vs. C_>13n-alkanes with metamorphism suggests progressive thermal release of kerogen-linked fatty acid precursors and degradation of n-alkanes. Changes of the steroid and terpenoid distributions are clearly related to increasing metamorphic temperatures. The absence of 18α(H)-22,29,30-trisnorneohopane (Ts), the occurrence of 17β(H)-trisnorhopane, 17β(H), 21α(H)-hopanes in the C₂₉ to C₃₁ range and 5α(H),14α(H),17α(H)-20R C₂₇, C₂₉ steranes in the low diagenetic samples (<100°C) are characteristic of immature bitumens. The higher thermal stress within the upper diagenetic zone (150°C) is marked by the presence of Ts, the disappearance of 17β(H)-trisnorhopane and thermodynamic equilibrium of the 22S/(22S + 22R) homohopane ratios. The increase of the ααα-sterane 20S/(20S + 20R) and 20R ββ/(ββ + αα) ratios (from 0.0 to 0.55 and from 0.0 to 0.40, respectively) in the upper diagenetic zone indicates the occurrence of isomerization reactions already at <150°C. However, the isomerization at C-20 (R → S) reaches thermodynamic equilibrium values already at the upper diagenesis (∼150°C) whereas the epimerisation at C-14 and C-17 (αα → ββ) arrives to constant values in the lower anchizone (∼200°C). The ratios Ts vs. 17α(H)-22,29,30-trisnorneohopane [(Ts/(Ts + Tm)] and 18α(H)-30-norneohopane (C₂₉Ts) vs. 17α(H),21β(H)-30-norhopane [C₂₉Ts/(C₂₉Ts + C₂₉)] increase until the medium anchizone (200 to 250°C) from 0.0 to 0.96 and from 0.0 to 0.44, respectively. An opposite trend towards lower values is observed in the higher metamorphic samples.The occurrence of specific hydrocarbons (e.g., n-alkylcyclopentanes, cadalene, hydrogenated aromatic compounds) in metamorphic samples points to kerogen degradation reactions most probably occurring in the presence of water and under reducing conditions. The changes of hydrocarbon distributions and carbon isotopic compositions of n-alkanes related to metamorphism suggest that the organic geochemistry may help to evaluate the lowest grades of prograde metamorphism.     

Throughfall patterns in sugarcane and riparian forest: understanding the effect of sugarcane age and land use conversion

Sugarcane is an annual crop with a dynamic canopy that changes over time mainly because of genetic adaptation. There is uncertainty about the temporal trends of throughfall (TF) in this important commercial crop. In the present paper, we used troughs to measure TF in a third and fourth ratoon and subsequently in a fourth and fifth ratoon. Additional measurements were carried out in an adjacent riparian forest. There were no significant differences between cycles of sugarcane, growth phases and riparian forest. The TF results for ratoon crop and riparian forest in 2011/2012 were 76% and 79.5% of gross rainfall, respectively, while in 2012/2013, they were 79% and 78%, respectively. However, TF was remarkably lower in the riparian forest relative to ratoon from the second half of the culm formation and elongation phase (280 days after harvest) until harvest. Copyright © 2016 John Wiley & Sons, Ltd.     

Using hydrogeochemical signatures of stream water to assess pathways for rainfall events: towards a predictive model

Thanks to its simple division into agricultural and forestry land use, the Corbeira catchment (Galicia, Spain) is used as a case study to build a predictive model using hydrogeochemical signatures. Stream data acquired under recessional flow conditions over a one year period were obtained from a sampling station near the downstream end of the catchment, and using principal component analysis, it is shown that some of the analytical parameters are covariant, and some are negatively correlated. These findings support inferences about the pathways of rainfall in the catchment. Specific signatures may be associated with the dominant hydrological source, either surface runoff or subsurface waters: additionally, the dominant land use in that part of the catchment, where the flow originated, can also be predicted. The dominant runoff shows a strong covariance between suspended solids (SS) and particulate phosphorus (PP), with a clear negative correlation with pH. Dissolved organic carbon (DOC) data are associated with this covariant set when these compounds are available in the soils in question. Dissolved phosphorus, total organic nitrogen and dissolved nitrates are also associated with the same covariant set when the runoff flows through areas of extensive agricultural use. The SS ? PP covariance is less significant at lower flows. Typical base flow regimes show a significant covariance between salinity and pH, with a marked negative correlation with SS ? PP set, confirming the dominance of subsurface waters in the baseflow, as expected. Seasonally divergent DOC ? SS behaviour proves to be a useful tracer for rainfall regimes. The DOC trend shows a sinusoidal annual variation in amplitude, determined by the rainfall regime. As a result, flow from the catchment is dominated by surface water whenever there is synchronicity between the peaks of DOC and SS. Copyright © 2013 John Wiley & Sons, Ltd.     

Bismuth‐melt trails trapped in cassiterite–quartz veins

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.     

Metals discharged during different flow conditions from a mixed agricultural‐forest catchment (NW Spain)

Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.