Degassing of Cl, F, Li, and Be during extrusion and crystallization of the rhyolite dome at Volcán Chaitén, Chile during 2008 and 2009

We investigated the distribution of Cl, F, Li, and Be in pumices, obsidians, and crystallized dome rocks at Chaitén volcano in 2008?C2009 in order to explore the behavior of these elements during explosive and effusive volcanic activity. Electron and ion microprobe analyses of matrix and inclusion glasses from pumice, obsidian, and microlite-rich dome rock indicate that Cl and other elements were lost primarily during crystallization of the rhyolitic dome after it had approached the surface. Glass in pumice and microlite-free obsidian has 888?±?121?ppm Cl, whereas residual glass in evolved microlite-rich dome rock generally retains less Cl (as low as <100?ppm). Estimated Cl losses were likely >0.7?Mt Cl, with a potential maximum of 1.8?Mt for the entire 0.8-km³ dome. Elemental variations reflect an integrated bulk distribution ratio for Cl?>?1.7 (1.7 times more Cl was degassed or incorporated into crystals than remained in the melt). Because Cl is lost dominantly as the very last H₂O is degassed, and Cl is minimally (if at all) partitioned into microlites, the integrated vapor/melt distribution ratio for Cl exceeds 200 (200 times more Cl in the evolved vapor than in the melt). Cl is likely lost as HCl, which is readily partitioned into magmatic vapor at low pressure. Cl loss is accelerated by the change in the composition of the residual melt due to microlite growth. Cl loss also may be affected by open-system gas fluxing. Integrated vapor-melt distribution ratios for Li, F, and Be all exceed 1,000. On degassing, an unknown fraction of these volatiles could be immediately dissolved in rainwater.     

Evaluation of seismic displacement demands from the September 19, 2017 Puebla‐Morelos (Mw = 7.1) earthquake in Mexico City

This short communication presents the assessment of seismic inelastic and elastic displacement demands computed from earthquake ground motions (EQGMs) recorded in Mexico City during the intermediate‐depth intraslab Puebla‐Morelos earthquake on 19 September 2017 (Mw = 7.1). Evaluation is conducted by means of peak elastic and inelastic displacement demand spectra, inelastic displacement ratio, C_R, spectra, and generalized interstory drift spectra computed for selected recording stations located in different soil sites of Mexico City, including those located in areas of reported collapsed buildings. Results of this study confirm previous observations made from interplate (subduction) EQGMs that peak inelastic displacement demands are greater than corresponding elastic counterparts for short‐to‐medium period structures, while the opposite is true for medium‐to‐long period structures. Possible basin site effects were identified from generalized interstory drift spectra. It is also shown that an equation introduced in the literature to obtain estimates of C_R developed from interplate EQGMs provides also a good estimate for mean C_R computed from the intermediate‐depth intraslab EQGMs.     

Characterization of the dynamic behavior of a concrete arch dam by means of forced vibration tests and numerical models

The characterization of the dynamic behavior of an arch dam, and its evolution throughout the structure's lifetime, provides important data for the safety control process. Forced vibration tests remain a reliable technique for this purpose. The Baixo Sabor dam is a 123 m high arch dam recently built in Portugal. Forced vibration tests were performed before and after the reservoir filling. Two techniques for forced vibration test are compared, discrete frequency scanning, the standard methodology, and continuous frequency scanning (sine sweep), a new proposed methodology, which allowed faster results without loss of precision. For the interpretation of test results two numerical models of the dam-reservoir-foundation system were built, and calibrated with the experimental data. A good match of numerical and experimental results was obtained for the six lowest frequencies and corresponding mode shapes.     

Channel incision by headcut migration: Reconnection of the Colorado River to its estuary and the Gulf of California during the floods of 1979–1988

The macrotidal Colorado River Delta at the northern end of the Gulf of California in Mexico is hydrologically complex. We review historical accounts, data, field notes and photographs to evaluate the hydrological processes active on the delta prior to the advent of upstream dams. We also employ satellite imagery as well as recent LIDAR data to illustrate the critical role played by headcut erosion in restoring the river's fluvial/tidewater connection during the 1979–1988 floods. Prior to human manipulation, the river's contribution of fresh water to the Gulf was periodically interrupted by natural overflowing, avulsing, and flooding into the sub-sea level Salton Sink on the north slope of the delta plain. River flow south towards the Gulf was also subject to occasional overflow into Laguna Salada, another sub-sea level basin. In the mid-20th century, the Delta was disconnected from its fluvial supply following installation of upstream dams and reservoirs. A tidal sediment obstruction developed in the estuary channel, forming a final barrier to fluvial connectivity. Release of Colorado River floodwaters into Mexico between 1979 and 1988 provided a natural experiment on the hydrological response of a long-disconnected macrotidal delta to restoration of fluvial supply.     

A substructure method for earthquake analysis of structures including structure-soil interaction

A general substructure method for analysis of response of structures to earthquake ground motion, including the effects of structure-soil interaction, is presented. The method is applicable to complex structures idealized as finite element systems and the soil region treated as either a continuum, for example as a viscoelastic halfspace, or idealized as a finite element system. The halfspace idealization permits reliable analysis for sites where essentially similar soils extend to large depths and there is no rigid boundary such as soil-rock interface. For sites where layers of soft soil are underlain by rock at shallow depth, finite element idealization of the soil region is appropriate; in this case, the direct and substructure methods would lead to equivalent results but the latter provides the better alternative. Treating the free field motion directly as the earthquake input in the substructure method eliminates the deconvolution calculations and the related assumption—regarding type and direction of earthquake waves—required in the direct method. Spatial variations in the input motion along the structure-soil interface of embedded structures or along the base of long surface supported structures are included in the formulation. The substructure method is computationally efficient because the two substructures—the structure and the soil region—are analysed separately; and, more important, it permits taking advantage of the important feature that response to earthquake ground motion is essentially contained in the lower few natural modes of vibration of the structure on fixed base.     

Thermal Drying and Alkaline Treatment of Biosolids: Effects on Nitrogen Mineralization

Biosolids from the Cañeveralejo WWTP were dehydrated by filter press and then applied two processes to reduce pathogens (PRP): thermally dried biosolid (TDB) and alkalinized biosolid (AB). Untreated, dehydrated biosolid (DB) was used as a control. We evaluated the impact of thermal drying and alkaline treatments on nitrogen mineralization in these substrates. Moreover, agronomic rates for biosolid applications to sugarcane were estimated for each of the treatments leading to application rates of 35.8, 36.4, and 54.5 t/ha for DB, TDB, and AB, respectively, to meet the nitrogen requirement (200 kg N/ha) for sugarcane cultivation (Saccharum officinarum). The results showed that the biosolid rates used increased the mineral nitrogen content of soils by an average of 93.8 and 439.8 mg/kg for all biosolids and the PRP (thermal drying and alkaline treatment) in biosolids had significant effects on mineralization rate, showing better results for the TDBs.     

Groundwater recharge assessment in a rural,arid, mid-mountain basin in North-Central Chile

ABSTRACT

A basic component of any hydrogeological study is the magnitude and temporal variation of groundwater recharge. This can be difficult to assess accurately, particularly in arid and semi-arid rainfed mid-mountain zones, as is the situation in the rural, low population density zones of North-Central Chile. In this study, recharge in the Punitaqui Basin, North-Central Chile, was characterized, contrasting the results of two methods: a modified Thornthwaite-Mather (MTM) and discharge recession analysis (DRA). We found a recharge rate of between 1 and 4% of average annual precipitation. Average recharge estimated by the MTM method is consistently higher than that estimated by DRA. Also, DRA tends to smooth the recharge values, resulting in a lower inter-annual variation coefficient. Both methods identified a threshold value of total annual precipitation, above which recharge can be expected to occur, of the order of 180 mm year^?1, consistent with values reported in similar areas.     

Post-Last Glacial Maximum evolution of a “fjord-type” lake based on high-resolution seismic data: the Lago Roca/Acigami (southern Tierra del Fuego,Argentina/Chile)

Lago Roca/Acigami is a “fjord-type” lake located in the southernmost part of South America, in the proximity of the Beagle Channel. A high-resolution seismic survey was carried out to analyse the seismic stratigraphy of the lake and to shed some light on the post-Last Glacial Maximum history of the area. Six seismic units were recognised, and their nature and depositional context were interpreted using seismic stratigraphy and acoustic facies analysis. A buried large ridge was identified within the glacial unit (SU1), interpreted as a frontal moraine that indicates a stabilisation phase. After retreat of the glacier from the basin, the trough was flooded by meltwater and a lake developed (SU2). The seismic facies, from bottom to top, depict a transition from ice-contact (SU2; SU3) to ice-distal proglacial conditions (SU4). A thick draping unit (SU5) marks a marine transgressive event and the instauration of a fjord environment in the basin. The marine transgression was a rapid event preceded by a fall in the lake level that caused an erosional unconformity. During the fjord phase the sedimentation remained controlled by meltwater discharge. Sea level fall, and subsequent disconnection from the Beagle Channel was accompanied by a progradation of the glaciofluvial deltaic sediments and the occurrence of several mass-wasting deposits (SU6). © 2019 John Wiley & Sons, Ltd.