Characterisation and multifaceted anisotropy assessment of Corvio sandstone for geological CO2 storage studies

We present a comprehensive characterisation of the physical, mineralogical, geomechanical, geophysical, and hydrodynamic properties of Corvio sandstone. This information, together with a detailed assessment of anisotropy, is needed to establish Corvio sandstone as a useful laboratory rock‐testing standard for well‐constrained studies of thermo–hydro–mechanical–chemical coupled phenomena associated with CO₂ storage practices and for geological reservoir studies in general. More than 200 core plugs of Corvio sandstone (38.1 and 50 mm diameters, 2:1 length‐to‐diameter ratio) were used in this characterisation study, with a rock porosity of 21.7 ± 1.2%, dry density 2036 ± 32 kg m^?3, and unconfined compressive and tensile strengths of 41 ± 3.28 and 2.3 ± 0.14 MPa, respectively. Geomechanical tests show that the rock behaves elastically between ～10 and ～18 MPa under unconfined conditions with associated Young's modulus and Poisson's ratio of 11.8 ± 2.8 GPa and 0.34 ± 0.01 GPa, respectively. Permeability abruptly decreases with confining pressure up to ～10 MPa and then stabilises at ～1 mD. Ultrasonic P‐ and S‐wave velocities vary from about 2.8–3.8 km s^?1 and 1.5–2.4 km s^?1, respectively, over confining and differential pressures between 0.1 and 35 MPa, allowing derivation of associated dynamic elastic moduli. Anisotropy was investigated using oriented core plugs for electrical resistivity, elastic wave velocity and attenuation, permeability, and tracer injection tests. Corvio sandstone shows weak transverse isotropy (symmetry axis normal to bedding) of <10% for velocity and <20% for attenuation.     

Episodic Biogeochemical Variability in a Low-Flow Mediterranean Estuary

To investigate to what extent episodic physical processes regulate nutrient availability and phytoplankton assemblages of the Mahon estuary (Minorca Island), we carried out an intensive field study during 2010–2011. During the study period, environmental conditions spanned from intense stratification to a continuous mixing and from lack of riverine inflow to intense runoff. Our data reveals a sequence of biogeochemical states of the estuary that result from the interplay between runoff, other non-periodic forcings (winds, sea level oscillations), and variations in water renewal. Seasonal runoff was revealed as a major driver of winter circulation and of the influx of inorganic nutrients, in particular nitrate. However, because of the combination between runoff and flushing time, the effects of floodwater events on phytoplankton are short-lived (days). Conversely, during summer, when freshwater influx declines, water renewal relies on pulsed atmospheric forcing that may be of local or remote origin. As depicted from the low nitrate concentrations (<1 μM) and enhanced ammonium (>1 μM), this change in circulation and external loads carries nutrient assimilation within the estuary head and forces the use of remnant nutrients through regenerating pathways to sustain an enhanced phytoplankton biomass at the lower estuary. Episodic variability represented between 52 and 65% of the annual chlorophyll variance. Despite the fact that episodic pulses represented intense departures from base biogeochemical state of the estuary, at time scale larger than weeks, the phytoplankton community composition and dynamics was largely regulated by the integrated effect of these episodes and other environmental drivers associated with seasonality rather than by individual storm events only. Our results suggest that even though the system presents good recovery capacity to individual storm episodes, it may be more vulnerable to increased nutrient fluxes during summer, as well as to changes in episode timing and frequency.     

The importance of fishing method, gear and origin: The Spanish hake market

Recently, how different attributes influence the price of fish has received increased attention. This is partly due to the perceived impact of different attributes on quality and price, but lately environmental concerns are also playing a part. In contrast to earlier studies that focus on the Ex-Vessel or retail level, this study investigates wholesale data, for hake in Spain. The wholesale data provide information on a wide range of origins as the hake market has increasingly become global. The empirical analysis is conducted by estimating a hedonic price function. The results indicate that while fishing gear and size are important attributes, the origin of the fish is in this case the clearly most important attribute in determining the price. The price more than doubles for fish from the most preferred source, Catalonia, relatively to the fish from the least preferred source, Namibia.     

Rockfall risk assessment to persons travelling in vehicles along a road: the case study of the Amalfi coastal road (southern Italy)

The paper deals with the assessment of rockfall risk to persons travelling in vehicles along the SS163 road, an important transportation corridor supporting a high vehicle traffic within the well-known tourist area of the Amalfi Coast (southern Italy). To this aim, the Rockfall Hazard Rating System (RHRS) and quantitative risk assessment (QRA) procedures, in this latter case for three rockfall risk scenarios, are applied. With reference to a large portion (33.820 out of a total of 50.365 km) of the SS163 road, the obtained QRA results highlight that, although the estimated individual risk to life satisfies the adopted tolerable risk criterion, the computed societal risk cannot be tolerated. Starting from this result, site-specific QRA analyses—carried out with reference to some road sections chosen on the basis of the RHRS results—allow the detection of the SS163 portions where the individual risk to life exceeds the tolerable risk threshold and, then, the recourse to mitigation measures could reveal necessary. In this regard, RHRS and QRA methods can be considered complementary tools in prioritizing the road sections where construction funds can be profitably spent in order to mitigate the rockfall risk with reference to both direct consequences (life loss) and indirect ones (traffic delay and diversions).     

Canelles landslide: modelling rapid drawdown and fast potential sliding

A large landslide (40 × 10⁶ m³) was reactivated on the left bank of Canelles reservoir, Spain. The instability was made evident after a considerable reduction of the reservoir level. The drawdown took place during the summer of 2006 after several years of high water levels. The drawdown velocity reached values between 0.5 and 1.2 m/day (registered at low elevations). The paper reports the geological and geotechnical investigations performed to define the movement. The geometry of the slip surface was established from the detailed analysis of the continuous cores recovered in deep borings and from limited information provided by inclinometers. Deep piezometric records provided also valuable information on the pore water pressure in the vicinity of the failure surface. These data allowed validating a flow–deformation coupled calculation model, which takes into account the changes in water level that occurred 4  years previous to the failure as well as the average rainfall. The analysis indicates that the most likely reason for the instability is the rapid drawdown that took place during the summer of 2006. The potential sudden acceleration of the slide is also analysed in the paper introducing coupled thermal hydraulic and mechanical effects that may develop at the basal shearing surface of the sliding mass. The results indicate that the slide velocity may reach values around 16 m/s when displacement reaches 250 m.     

Determination of the near field distance for point and line sources acting on the surface of an homogeneous and viscoelastic half-space

A methodology to determine the near field region, defined as the region where volumetric waves significantly influence the surface vibration levels, is presented. This interference region between Rayleigh and volumetric waves is calculated for the case of an homogeneous and viscoelastic half-space excited by a surface point source and a surface infinite line source. This calculation is performed following an analytical approach. The effects of the mechanical properties of the ground on the dimensions of this interference region, characterized here by the near field distance, are also investigated. The results show near field distances for both infinite line and point sources and for five different real grounds, typical of the Barcelona (Spain) metropolitan area.     

Water and nutrient fluxes off Northwest Africa

A historical data set is used to describe the coastal transition zone off Northwest Africa during spring 1973 and fall 1975, from 17° to 26°N, with special emphasis on the interaction between subtropical (North Atlantic Central Waters) and tropical (South Atlantic Central Waters) gyres. The near-surface geostrophic circulation, relative to 300 m, is quite complex. Major features are a large cyclonic pattern north of Cape Blanc (21°N) and offshore flow at the Cape Verde front. The large cyclone occurs in the region of most intense winds, and resembles a large meander of the baroclinic southward upwelling jet. The Cape Verde frontal system displays substantial interleaving that may partly originate as mesoscale features at the coastal upwelling front. Property–property diagrams show that the front is an effective barrier to all properties except temperature. The analysis of the Turner angle suggests that the frontal system is characterized by large heat horizontal diffusion as a result of intense double diffusion, which results in the smoothing of the temperature horizontal gradients. Nine cross-shore sections are used to calculate along-shore geostrophic water-mass and nutrient transports and to infer exchanges between the coastal transition zone and the deep ocean (import: deep ocean to transition zone; export: transition zone to deep ocean). These exchanges compare well with mean wind-induced transports and actual geostrophic cross-shore transport estimates. The region is divided into three areas: southern (18–21°N), central (21–23.5°N), and northern (23.5–26°N). In the northern area geostrophic import is roughly compensated with wind-induced export during both seasons. In the central area geostrophic import is greater than wind-induced export during spring, resulting in net import of both water (0.8 Sv) and nitrate (14 kmol s⁻¹), but during fall both factors again roughly cancel. In the southern area geostrophy and wind join to export water and nutrients during both seasons, they increase from 0.6 Sv and 3 kmol s⁻¹ during fall to 2.9 Sv and 53 kmol s⁻¹ during spring.     

Pilot‐Scale Degradation of Organic Contaminants in a Continuous‐flow Reactor by the Helielectro‐Fenton Method

The feasibility of pilot‐scale mineralization of organic pollutants in wastewaters using the Electro‐Fenton® process is demonstrated. The treatment was applied in a continuous‐flow reactor, to solutions of nitrobenzene, 2,4‐D and benzoic acid and to actual wastewaters from a fine chemicals company along with a pulp and paper company. The results showed mineralization yields from 60 to 84% by simply applying the Electro‐Fenton® process. When a subsequent exposure to sunlight was carried out (Helielectro‐Fenton method), this mineralization almost went to completion, except for the effluent from the fine chemicals industry.     

Gamma-ray emission from individual classical novae

Classical novae are important producers of radioactive nuclei, such as ⁷Be, ¹³N, ¹⁸F, ²²Na and ²⁶Al. The disintegration of these nuclei produces positrons (except for ⁷Be) that through annihilation with electrons produce photons of energies 511 keV and below. Furthermore, ⁷Be and ²²Na decay producing photons with energies of 478 and 1275 keV, respectively, well in the γ-ray domain. Therefore, novae are potential sources of γ-ray emission. We have developed two codes in order to analyse carefully the γ-ray emission of individual classical novae: a hydrodynamical one, which follows both the accretion and the explosion stages, and a Monte Carlo one, able to treat both production and transfer of γ-ray photons. Both codes have been coupled in order to simulate realistic explosions. The properties of γ-ray spectra and γ-ray light curves (for the continuum and for the lines at 511, 478 and 1275 keV) have been analysed, with a special emphasis on the difference between carbon–oxygen and oxygen–neon novae. Predictions of detectability of individual novae by the future SPI spectrometer on board the INTEGRAL satellite are made. Concerning ²⁶Al, its decay produces photons of 1809 keV but this occurs on a time-scale much longer than the typical time interval between nova outbursts in the Galaxy, making it undetectable in individual novae. The accumulated emission of ²⁶Al from many Galactic novae has not been modelled in this paper.     

Soil fertility evolution and landscape dynamics in a Mediterranean area: a case study in the Sant Llorenç Natural Park (Barcelona, NE Spain)

The cartography of land covers was used to study fertility and soil evolution in a mountainous Mediterranean area during the anthropocene period ( Crutzen P J 2002 Geology of mankind Nature 415 23). The aim was to determine changes in fertility as agricultural lands were abandoned in the 14 000 hectare area that constitutes Sant Llorenç del Munt Natural Park in a pre-coastal Catalan mountain range (north-eastern Iberian Peninsula). The analysis of land covers using vegetation maps, orthorectified images and aerial photography has allowed us to differentiate six vegetation groups: holm-oak wood, pine grove, oak wood, scrub, active agricultural fields and abandoned agricultural fields. The anthropic covers over the past 100 years were subdivided into five categories: active fields and those abandoned over four time periods. Study variables include field shape (concave, convex, flat), orientation (north, south) and slope (ranging from 12º to 24º). The parameters used for the physical-chemical soil analysis included organic material, phosphorous and potassium; fertility was classified based on groups, types and classes. The results indicate that even when the visual appearance of certain landscapes is similar, the edaphic characteristics may be very different. Changes induced by human disturbance share this phenomenon. Therefore, land management should be considered globally, taking into account vegetation, soils and water as interdependent factors, since it is their interaction that produces landscape and most affects its evolution over time.