Second-order closure study of the covariance between chemically reactive species in the surface layer

A second-order modelling technique is used to investigate the influence of turbulence on chemical reactions. The covariance and variance equations for the NO-O₃-NO₂ system are developed as a function of the ratio of the timescale of turbulence ( _t ) and the timescale of chemistry (_Ch): the first Damköhler number ( _t /_Ch). Special attention is given to the calculation of the covariance between NO and O₃ normalized by the product of their means, the so-called intensity of segregation (I _S ). This parameter quantifies the state of mixing of two chemical species.The intensity of segregation is calculated as a function of the flux of NO and the first Damköhler number. The model results presented illustrate the importance of taking the effect of turbulence on chemical reactions into account for higher values of the NO flux, for values of the ratio O₃/NO larger than 12.5 and for values of the ratio _t /_CH larger than 0.1. For such cases, the effective reaction rates are slower than if the chemical species are assumed to be uniformly mixed.     

Petrographic and geochemical evidence for multiphase formation of carbonates in the Martian orthopyroxenite Allan Hills 84001

Martian meteorites can provide valuable information about past environmental conditions on Mars. Allan Hills 84001 formed more than 4 Gyr ago, and owing to its age and long exposure to the Martian environment, and this meteorite has features that may record early processes. These features include a highly fractured texture, gases trapped during one or more impact events or during formation of the rock, and spherical Fe‐Mg‐Ca carbonates. In this study, we have concentrated on providing new insights into the context of these carbonates using a range of techniques to explore whether they record multiple precipitation and shock events. The petrographic features and compositional properties of these carbonates indicate that at least two pulses of Mg‐ and Fe‐rich solutions saturated the rock. Those two generations of carbonates can be distinguished by a very sharp change in compositions, from being rich in Mg and poor in Fe and Mn, to being poor in Mg and rich in Fe and Mn. Between these two generations of carbonate is evidence for fracturing and local corrosion.     

Evolutionary calculations of carbon dredge-up in helium envelope white dwarfs

We investigate the evolution of cooling helium atmosphere white dwarfs using a full evolutionary code, specifically developed to follow the effects of element diffusion and gravitational settling on white dwarf cooling. The major difference between this work and previous work is that we use more recent opacity data from the OPAL project. Since, in general, these opacities are higher than those available 10 years ago, at a given effective temperature, convection zones go deeper than in models with older opacity data. Thus convective dredge-up of observationally detectable carbon in helium atmosphere white dwarfs can occur for thicker helium layers than found by Pelletier et al. We find that the range of observed C to He ratios in different DQ white dwarfs of similar effective temperature is well explained by a range of initial helium layer mass between 10⁻³ and 10⁻² M⊙, in good agreement with stellar evolution theory, assuming a typical white dwarf mass of 0.6 M⊙. We also predict that oxygen will be present in DQ white dwarf atmospheres in detectable amounts if the helium layer mass is near the lower limit compatible with stellar evolution theory. Determination of the oxygen abundance has the potential of providing information on the profile of oxygen in the core and hence on the important ¹²C(α,γ)¹⁶O reaction rate.     

Climate teleconnections at monthly time scales in the Ligurian Sea inferred from satellite data

The existence and spatial distribution of possible teleconnections between the South Pacific and North Atlantic oceans and the Ligurian Sea (North-western Mediterranean) are investigated in the present paper. Teleconnections are searched by cross-correlating monthly spatio-temporal time series of 1.1 km resolution sea surface temperature (SST), and a 22.2 km resolution sea level anomaly (SLA), measured from satellite from March 1993 to August 1999, with two indices characterising the South Pacific and the North Atlantic variability: the Southern Oscillation (SO) and the North Atlantic Oscillation (NAO) indices, respectively. Concerning the variability induced by the North Atlantic Ocean, it is shown that it mostly influences the SLA field in the Ligurian Sea. Specifically, relevant anti-correlations between SLA and North Atlantic variability have been found in all the Ligurian sub-basin. As expected by geographical proximity, the effects of North Atlantic on the SLA field in the Ligurian Sea are instantaneous at monthly time scales. Instead, correlations between SST and NAO Index are found at time lag τ = 1 month in the southern part of the basin highlighting the memory of the ocean related to their heat capacity. Significant anti-correlations between SO Index and the SST field in the Ligurian Sea, were obtained at time lag τ = 4 months in the coastal areas of the sub-basin. Results also indicate that the impact of teleconnections in the area studied is not geographically uniform.