Quantifying annual groundwater recharge and storage in the central Sierra Nevada using naturally occurring 35S

Identifying aquifer vulnerability to climate change is of vital importance in the Sierra Nevada and other snow‐dominated basins where groundwater systems are essential to water supply and ecosystem health. Quantifying the component of new (current year's) snowmelt in groundwater and surface water is useful in evaluating aquifer vulnerability because significant annual recharge may indicate that streamflow will respond rapidly to annual variability in precipitation, followed by more gradual decreases in recharge as recharge declines over decades. Hydrologic models and field‐based studies have indicated that young (<1 year) water is an important component of streamflow. The goal of this study was to utilize the short‐lived, naturally occurring cosmogenic isotope sulfur‐35 (³⁵S) to quantify new snowmelt contribution to groundwater and surface waters in Sagehen Creek Basin (SCB) and Martis Valley Groundwater Basin (MVGB) located within the Tertiary volcanics of the central Sierra Nevada, CA. Activities of ³⁵S were measured in dissolved sulfate (³⁵SO₄^2?) in SCB and MVGB snowpack, groundwater, springs, and streamflow. The percent of new snowmelt (PNS) in SCB streamflow ranged from 0.2 ± 6.6% during baseflow conditions to 14.0 ± 3.4% during high‐flow periods of snowmelt. Similar to SCB, the PNS in MVGB groundwater and streamflow was typically <30% with the largest fractions occurring in late spring or early summer following peak streamflow. The consistently low PNS suggests that a significant fraction of annual snowmelt in SCB and MVGB recharges groundwater, and groundwater contributions to streamflow in these systems have the potential to mitigate climate change impacts on runoff.     

Holocene relative sea‐level changes in Harris,Outer Hebrides,Scotland, UK

Evidence for relative sea‐level changes during the middle and late Holocene is examined from two locations on the Atlantic coast of Harris, Outer Hebrides, Scotland, using morphological mapping and survey, stratigraphical, grain size and diatom analysis, and radiocarbon dating. The earliest event identified is a marine flood, which occurred after 7982–8348 cal. a (7370 ± 80 ¹⁴C a) BP, when the sea crossed a threshold lying at ?0.08 m Ordnance Datum Newlyn (OD) (?2.17 m mean high water springs (MHWS)) before withdrawing. This could have been due to a storm or to the Holocene Storegga Slide tsunami. By 6407–6122 cal. a (5500 ± 60 ¹⁴C a) BP, relative sea levels had begun to fall from a sandflat surface with an indicated MHWS level of between 0.08 and ?1.96 m (?2.01 to ?4.05 m). This fall reached between ?0.30 and ?2.35 m (?2.39 to ?4.44 m) after 5841–5050 cal. a (4760 ± 130 ¹⁴C a) BP, but was succeeded by a relative sea‐level rise which reached between 0.54 and ?1.57 m (?1.55 to ?3.66 m) by 5450–4861 cal. a (4500 ± 100 ¹⁴C a) BP. This rise continued, possibly with an interruption, until a second sandflat surface was reached between 2.34 and ?0.26 m (0.25 to ?2.35 m) between 2952–3375 cal. a (3000 ± 80 ¹⁴C a) and 1948–2325 cal. a (2130 ± 70 ¹⁴C a) BP, before present levels were reached. The regressive episode from the earliest sandflat is correlated with the abandonment of the Main Postglacial Shoreline. It is maintained that the fluctuations in relative sea level recorded can be correlated with similar events elsewhere on the periphery of the glacio‐isostatic centre and may therefore reflect secular changes in nearshore sea surface levels. Despite published evidence from trim lines of differential ice sheet loading across the area, no evidence of variations in uplift between the locations concerned could be found. Copyright © 2009 John Wiley & Sons, Ltd.     

The use of airborne laser scanning to develop a pixel-based stratification for a verified carbon offset project

Background  

The voluntary carbon market is a new and growing market that is increasingly important to consider in managing forestland. Monitoring, reporting, and verifying carbon stocks and fluxes at a project level is the single largest direct cost of a forest carbon offset project. There are now many methods for estimating forest stocks with high accuracy that use both Airborne Laser Scanning (ALS) and high-resolution optical remote sensing data. However, many of these methods are not appropriate for use under existing carbon offset standards and most have not been field tested.     

CyberShake: A Physics-Based Seismic Hazard Model for Southern California

CyberShake, as part of the Southern California Earthquake Center??s (SCEC) Community Modeling Environment, is developing a methodology that explicitly incorporates deterministic source and wave propagation effects within seismic hazard calculations through the use of physics-based 3D ground motion simulations. To calculate a waveform-based seismic hazard estimate for a site of interest, we begin with Uniform California Earthquake Rupture Forecast, Version 2.0 (UCERF2.0) and identify all ruptures within 200?km of the site of interest. We convert the UCERF2.0 rupture definition into multiple rupture variations with differing hypocenter locations and slip distributions, resulting in about 415,000 rupture variations per site. Strain Green Tensors are calculated for the site of interest using the SCEC Community Velocity Model, Version 4 (CVM4), and then, using reciprocity, we calculate synthetic seismograms for each rupture variation. Peak intensity measures are then extracted from these synthetics and combined with the original rupture probabilities to produce probabilistic seismic hazard curves for the site. Being explicitly site-based, CyberShake directly samples the ground motion variability at that site over many earthquake cycles (i.e., rupture scenarios) and alleviates the need for the ergodic assumption that is implicitly included in traditional empirically based calculations. Thus far, we have simulated ruptures at over 200 sites in the Los Angeles region for ground shaking periods of 2?s and longer, providing the basis for the first generation CyberShake hazard maps. Our results indicate that the combination of rupture directivity and basin response effects can lead to an increase in the hazard level for some sites, relative to that given by a conventional Ground Motion Prediction Equation (GMPE). Additionally, and perhaps more importantly, we find that the physics-based hazard results are much more sensitive to the assumed magnitude-area relations and magnitude uncertainty estimates used in the definition of the ruptures than is found in the traditional GMPE approach. This reinforces the need for continued development of a better understanding of earthquake source characterization and the constitutive relations that govern the earthquake rupture process.     

Sorption of selenium(VI) onto anatase: Macroscopic and microscopic characterization

The sorption of selenium(VI) onto pure anatase, a polymorph of titanium dioxide, was investigated. At the macroscopic level, batch experiments and electrophoretic mobility measurements were performed. Selenium(VI) retention was found to be pH-dependent, i.e. sorption of selenium(VI) decreases with increasing pH (pH range 3.5-11). Selenium(VI) sorption dependence on the ionic strength was also evidenced, i.e. sorption increases while the ionic strength decreases. Electrophoretic mobility measurements showed that selenium(VI) sorption had no effect on the isoelectric point of anatase. At the microscopic level, XPS (X-ray Photoelectron Spectroscopy) measurements evidenced the absence of reduction of selenium(VI) during the sorption process. Furthermore, the nature of the sorbed surface species at the anatase/liquid interface was elucidated using Attenuated Total Reflection Fourier-Transform Infrared (ATR FT-IR) spectroscopy. The spectroscopic results strongly suggested the formation of outer-sphere complexes on the whole pH range, in agreement with batch sorption experiments and electrophoretic mobility findings.     

The Staffelegg Formation: a new stratigraphic scheme for the Early Jurassic of northern Switzerland

The deposits of the Early Jurassic in northern Switzerland accumulated in the relatively slowly subsiding transition zone between the southwestern part of the Swabian basin and the eastern part of the Paris basin under fully marine conditions. Terrigenous fine-grained deposits dominate, but calcarenitic and phosphorit-rich strata are intercalated. The total thickness varies between 25 and 50 m. In the eastern and central parts of N Switzerland, sediments Sinemurian in age constitute about 90% of the total thickness. To the West, however, in the Mont Terri area, Pliensbachian and Toarcian deposits form 70% of the total thickness. Stratigraphic gaps occur on a local to regional scale throughout N Switzerland. Such hiatus comprise a subzone to a stage in time. With respect to lithology and fossil content, the Early Jurassic deposits in northern Switzerland are similar to those in SW Germany. Nonetheless, an exact stratigraphic correlation is hardly possible, particulary in the southern and southwestern Folded Jura where distinct facies changes occur over short distances. Revised existing and new litho- and biostratigraphic data form the base to refine the stratigraphic subdivision of the deposits that have been informally called “Lias”. The name Staffelegg Formation is suggested and defined as the mapping unit for the Early Jurassic. The Staffelegg Formation is introduced for Early Jurassic sediments in northern Switzerland between the Doubs River and Mt. Weissenstein in the west and the Randen Hills located north of the city of Schaffhausen in the east. The Staffelegg Formation starts within the Planorbis zone of the Hettangian. The upper boundary to the overlying Aalenian Opalinus-Ton is diachronous. The lithostratigraphic names previously in use have been replaced by new ones, in accordance within the rules of lithostratigraphic nomenclature. The Staffelegg Formation comprises 11 members and 9 beds. Several of these beds are important correlation horizons in terms of allostratigraphy. Some of them correspond to strata or erosional unconformities encountered in the Swabian realm, some of them can be correlated with strata in the Paris basin. The facies transition to the Paris basin is expressed by introduction of a corresponding lithostratigraphic unit.     

Variation in sea temperature and the East Australian Current in the Solitary Islands region between 2001-2008

Improved understanding of the East Australian Current (EAC) and sea-temperature patterns within the Solitary Islands region of northern New South Wales, an area where tropical and temperate faunas overlap, is an essential step in explaining cross-shelf gradients in biotic patterns. Sea temperature at ∼10 m was logged using thermistors at seven stations every 30 minutes between January 2001 and December 2008. Stations were replicated in three distance-from-shore categories (<1.5; 1.5 to 6; and >6 km from the coast), corresponding with predominant assemblage patterns of reef fish. Daily, monthly, seasonal and yearly sea-temperature patterns were compared between and within stations and distance-from-shore categories. SST images were examined to determine the role of the EAC in producing short-period (2 to 4 days) temperature anomalies. Sea temperatures ranged between 16.6-27.5 °C and were highest offshore and lowest inshore. Offshore sites experienced average temperatures ∼1 °C higher than nearshore sites over the 8-year study. There was considerable variation in sea temperature between years, with 2002 and 2006 being the warmest and 2007 the coolest. These patterns correspond with strong inter-annual variability of the EAC at the scale of the Solitary Islands region. The EAC influenced shelf waters most strongly during late spring/summer when temperatures were also most variable over the smallest temporal scales (hours, days). Short-period anomalies between and within stations could largely be explained by variable encroachment of the EAC across the shelf and/or colder intrusions of water forming adjacent to the coastline. Previous assumptions that the EAC strongly influences gradients in the distribution of tropical species in this nearshore region are strongly supported.     

Chemical speciation and fate of tripolyphosphate after application to a calcareous soil

Adsorption and precipitation reactions often dictate the availability of phosphorus in soil environments. Tripolyphosphate (TPP) is considered a form of slow release P fertilizer in P limited soils, however, investigations of the chemical fate of TPP in soils are limited. It has been proposed that TPP rapidly hydrolyzes in the soil solution before adsorbing or precipitating with soil surfaces, but in model systems, TPP also adsorbs rapidly onto mineral surfaces. To study the adsorption behavior of TPP in calcareous soils, a short-term (48 h) TPP spike was performed under laboratory conditions. To determine the fate of TPP under field conditions, two different liquid TPP amendments were applied to a P limited subsurface field site via an in-ground injection system. Phosphorus speciation was assessed using X-ray absorption spectroscopy, total and labile extractable P, and X-ray diffraction. Adsorption of TPP to soil mineral surfaces was rapid (< 48 h) and persisted without fully hydrolyzing to ortho-P. Linear combination fitting of XAS data indicated that the distribution of adsorbed P was highest (~ 30–40%) throughout the site after the first TPP amendment application (high water volume and low TPP concentrations). In contrast, lower water volumes with more concentrated TPP resulted in lower relative fractions of adsorbed P (15–25%), but a significant increase in total P concentrations (~ 3000 mg P kg soil) and adsorbed P (60%) directly adjacent to the injection system. This demonstrates that TPP application increases the adsorbed P fraction of calcareous soils through rapid adsorption reactions with soil mineral surfaces.     

Investigating slow-moving landslides in the Zhouqu region of China using InSAR time series

In the Zhouqu region (Gansu, China), landslide distribution and activity exploits geological weaknesses in the fault-controlled belt of low-grade metamorphic rocks of the Bailong valley and severely impacts lives and livelihoods in this region. Landslides reactivated by the Wenchuan 2008 earthquake and debris flows triggered by rainfall, such as the 2010 Zhouqu debris flow, have caused more than 1700 casualties and estimated economic losses of some US$0.4 billion. Earthflows presently cover some 79% of the total landslide area and have exerted a strong influence on landscape dynamics and evolution in this region. In this study, we use multi-temporal Advanced Land Observing Satellite and Phased Array type L-band Synthetic Aperture Radar (ALOS PALSAR) data and time series interferometric synthetic aperture radar to investigate slow-moving landslides in a mountainous region with steep topography for the period December 2007–August 2010 using the Small Baseline Subsets (SBAS) technique. This enabled the identification of 11 active earthflows, 19 active landslides with deformation rates exceeding 100 mm/year and 20 new instabilities added into the pre-existing landslide inventory map. The activity of these earthflows and landslides exhibits seasonal variations and accelerated deformation following the Wenchuan earthquake. Time series analysis of the Suoertou earthflow reveals that seasonal velocity changes are characterized by comparatively rapid acceleration and gradual deceleration with distinct kinematic zones with different mean velocities, although velocity changes appear to occur synchronously along the landslide body over seasonal timescales. The observations suggest that the post-seismic effects (acceleration period) on landslide deformation last some 6–7 months.