Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization

Oxidation of mackinawite (FeS) and concurrent mobilization of arsenic were investigated as a function of pH under oxidizing conditions. At acidic pH, FeS oxidation is mainly initiated by the proton-promoted dissolution, which results in the release of Fe(II) and sulfide in the solution. While most of dissolved sulfide is volatilized before being oxidized, dissolved Fe(II) is oxidized into green rust-like precipitates and goethite (α-FeOOH). At basic pH, the development of Fe(III) (oxyhydr)oxide coating on the FeS surface inhibits the solution-phase oxidation following FeS dissolution. Instead, FeS is mostly oxidized into lepidocrocite (γ-FeOOH) via the surface-mediated oxidation without dissolution. At neutral pH, FeS is oxidized via both the solution-phase oxidation following FeS dissolution and the surface-mediated oxidation mechanisms. The mobilization of arsenic during FeS oxidation is strongly affected by FeS oxidation mechanisms. At acidic pH (and to some extent at neutral pH), the rapid FeS dissolution and the slow precipitation of Fe (oxyhydr)oxides results in arsenic accumulation in water. In contrast, the surface-mediated oxidation of FeS at basic pH leads to the direct formation of Fe (oxyhydr)oxides, which provides effective adsorbents for As under oxic conditions. At acidic and neutral pH, the solution-phase oxidation of dissolved Fe(II) accelerates the oxidation of the less adsorbing As(III) to the more adsorbing As(V). This study reveals that the oxidative mobilization of As may be a significant pathway for arsenic enrichment of porewaters in sulfidic sediments.     

Estimation of the methane flux from mud volcanoes along Chishan Fault,southwestern Taiwan

Because of the increasing public awareness of the greenhouse effect, geological emissions of methane (GEM) have gained more attention. The Intergovernmental Panel on Climate Change included GEM in the natural sources of methane category in the Fourth Assessment Report in 2007. The methane flux from mud volcanoes (MVs) is the second leading source within GEM. However, given that gas flux from MVs has been measured directly only in Sicily and Azerbaijan, the global methane estimation is still a conservative assumption based on limited data. The behavior of MV activities is seldom reported. This study attempts to estimate annual methane emissions through MVs by using a video recorder to record MV activities along the Chishan Fault and determining the bubble size and flux rate of each MV. Observation results, after a 1 year observation period, indicate that the annual emissions of the 19 MVs along the Chishan Fault are 0.1–0.2% of the global methane flux from MVs, highlighting that the methane emission from these MVs should not be neglected. In addition, the continuous monitoring of a particular MV disclosed periodic characteristics of MV activities. These results manifest the spatial and temporal variations of MV activities along the Chishan Fault. The spatial variations are related to the extensional kinematics of the Chishan fault, while the temporal variation relates to the earth-tide-related MV activities. The estimated annual methane emissions from the study are far more than those of previous studies and are still considered conservative. Results of this study may provide valuable information for researchers attempting to estimate the quantity of GEM.     

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Availability of coastal groundwater discharge as an alternative water resource in a large-scale reclaimed land,Korea

This study was conducted to identify the availability of coastal groundwater discharge (CGD), subsurface fluids flowing from inland through the coastal area to sea, as an alternative water resource for a large-scale reclaimed land. The behaviors of stable isotopes indicated that groundwater originated from inland precipitation and traveled as CGD along the coast line. Most of the groundwater samples collected from domestic wells installed along the old coast line were considered to be relatively fresh from the correlation analysis among chemical constituents. The average electrical conductivity (EC) values of the samples were identified as averaging 1,125–1,297 μS cm^?1, corresponding to appropriate crop growth. A weathered-rock layer in a small catchment within the reclaimed land was proved to be a main CGD pathway, with electrical resistivity anomalies ranging from 7 to 14 Ω m. Five monitoring wells were placed in this catchment to delineate the occurrence of CGD. Long-term vertical EC profiling results for the monitoring wells indicated that CGD occurs within a depth of 30 m below the ground surface. Annual monitoring data for groundwater level and EC demonstrated that the water quality of CGD was improved by introducing fresh terrestrial groundwater. A remarkable improvement in water quality (EC decrease of 900–1,600 μS cm^?1) of CGD was observed during the saline water pumping test that explains how CGD could be an alternative water resource for the reclaimed land.     

Geochemical survey of rare earth elements (REEs) in the concealed ore body of Hongcheon,Korea

Because of the risk of diminishing supplies of rare earth elements (REEs) worldwide due to China’s dominance over REE supply, the necessity of developing domestic resources of REE has been realized in other countries. To explore new ore bodies, a geochemical survey was conducted at one existing carbonatite REE deposit in the Hongcheon area of Korea. Proper sampling strategies and baseline data for the interpretation of the results were determined through a pilot study conducted in the area. Enrichment in the concentration of light REE (LREE) over that of heavy REE, which is typical in carbonatite-type deposits, was observed in stream sediments and heavy mineral samples collected during the geochemical survey. Maximum concentrations of LREE were 2,299 and 27,798 mg/kg for stream sediments and heavy minerals, respectively. Among LREEs, La and Ce are the dominant components of all REEs, comprising approximately 68 % of mean concentrations. Considering the distribution pattern of La + Ce contents and the associations with the existing outcropping ore bodies, the zone of prospective REE mineralization was determined to be in the south-western part of the area. A detailed follow-up soil survey of the zone found even higher concentrations of La and Ce (2,450 and 3,100 mg/kg, respectively), and suggested the possible extension of the existing ore bodies. Likewise, a systematic geochemical survey for REE is feasible for locating concealed ore bodies in the area, where the mineralization is mostly covered with soil, and rock outcrops are scarce.     

Hydrologic modelling of the effect of snowmelt and temperature on a mountainous watershed

Snowmelt-runoff modelling in a mountainous basin is perceived as difficult due to the complexity of simulation. Theoretically, the snowmelt process should be influenced by temperature changes. It is still controversial as how to incorporate the temperature changes into the snowmelt-runoff model in a mountainous basin. This paper presents the results of a study in the North Fork American River basin where the snowmelt-runoff mechanism is modelled by relating the temperature changes to the elevation band in the basin. In this study, a distributed hydrologic model is used to explore the orographic effects on the snowmelt-runoff using the snowfall-snowmelt routine in Soil and Water Assessment Tool (SWAT). Three parameters, namely maximum snowmelt factor, minimum snowmelt factor, and snowpack temperature lag were analysed during the simulation. The model was validated using streamflow data from October 1, 1991 to September 30, 1994 with and without considering the elevation band. The result of this study suggests that the snowmelt-runoff model associated with the elevation band better represents the snowmelt-runoff mechanism in terms of Nash–Sutcliffe coefficient (E _NS ), R ², and Root Mean Square Error (RMSE).     

Meteoric activities during the 11th century

We have analysed the meteor records in the chronicles that describe the era of the Song dynasty ( ad 960–1279). The data are complementary to the record-vacant 10th century of the Koryo dynasty ( ad 918–1392). The annual activity of sporadic meteors analysed shows a generic sinusoidal behaviour as in modern observations. In addition, we have also found that there are two prominent meteor showers, one in August and the other in November, appearing on the fluctuating sporadic meteors. The date of occurrence of the August shower indicates it to be the Perseids. By comparing the date of occurrence of the November shower with those of the Leonid showers of the Koryo dynasty, recent visual observations and the world-wide historical meteor storms, we conclude that the November shower is the Leonids. The regression rate of the Leonids is obtained to be     days per century, which agrees with recent observations.     

Improvement of daily precipitation estimations using PRISM with inverse-distance weighting

Improved daily precipitation estimations were attempted using the parameter-elevation regressions on a parameter-elevation regression on independent slopes model (PRISM) with inverse-distance weighting (IDW) and a precipitation-masking algorithm for precipitation areas. The PRISM (PRISM_ORG) suffers two overestimation problems when the daily precipitation is estimated: overestimation of the precipitation intensity in mountainous regions and overestimation of the local precipitation areas. In order to solve the problem of overestimating the precipitation intensity, we used the IDW technique that employs the same input stations as those used in the PRISM regression (PRISM_IDW). A precipitation-masking algorithm that selectively masks the precipitation estimation grid points was additionally applied to the PRISM_IDW results (PRISM_MSK). For 6 months from March to August 2012, daily precipitation data were produced in a horizontal resolution of 1 km based on the above two experiments and PRISM_ORG. Afterwards, each experiment was evaluated for improvements. The monthly root mean squared errors (RMSEs) of PRISM_IDW and PRISM_MSK were reduced by 0.83 mm/day and 0.86 mm/day, respectively, compared to PRISM_ORG.     

Active Region Coronal Rain Event Observed by the Fast Imaging Solar Spectrograph on the NST

The Fast Imaging Solar Spectrograph (FISS) is being operated on the New Solar Telescope of the Big Bear Solar Observatory. It simultaneously records spectra of Hα and Ca ii 8542 Å lines, and this dual-spectra measurement provides an estimate of the temperature and nonthermal speed components. We observed a loop structure in AR 11305 using the FISS, SDO/AIA, and STEREO/EUVI in 304 Å, and found plasma material falling along the loop from a coronal height into the umbra of a sunspot, which accelerated up to 80 km?s^?1. We also observed C2 and C7 flare events near the loop. The temperature of the downflows was in the range of 10?000?–?33?000 K, increasing toward the umbra. The temperature of the flow varied with time, and the temperature near the footpoint rose immediately after the C7 flare, but the temperature toward the umbra remained the same. There seemed to be a temporal correlation between the amount of downflow material and the observed C-class flares. The downflows decreased gradually soon after the flares and then increased after a few hours. These high-speed red-shift events occurred continuously during the observations. The flows observed on-disk in Hα and Ca ii 8542 Å appeared as fragmented, fuzzy condensed material falling from the coronal heights when seen off-limb with STEREO/EUVI at 304 Å. Based on these observations, we propose that these flows were an on-disk signature of coronal rain.     

Total current of the auroral electrojet estimated from the IMS Alaska meridian chain of magnetic observatories

Based on magnetic data from the IMS Alaska meridian chain of observatories, the total current of the westward auroral electrojet flowing across the meridian is estimated by using two independent methods. The first one is a simple integration of the north-south component of magnetic perturbations along the meridian, providing the quantity F in units of nT·km. The other is to use the forward method, providing the total current I in units of A. It is shown that F and I have nearly identical time variations. Thus, by normalizing the two quantities and taking the numerical value of F in units of nT·km, it is possible to estimate the total electrojet current flowing across a magnetic meridian, with an accuracy of 90%, by using the latitudinal profile of the H component, namely I (A) = 2.0 F (nT·km).