Electron-impact rotational excitation of linear molecular ions

Molecular R -matrix calculations are performed to give rotational excitation rates for electron collisions with linear molecular ions. Results are presented for CO⁺, HCO⁺, NO⁺ and H₂⁺ up to electron temperatures of 10 000 K. De-excitation rates and critical electron densities are also given. It is shown that the widely used Coulomb–Born approximation is valid for Δ j =1 transitions when the molecular ion has a dipole greater than about 2D, but otherwise is not reliable for studying electron-impact rotational excitation. In particular, transitions with Δ j >1 are found to have appreciable rates and are found to be entirely dominated by short-range effects.     

Incorporation of argon, krypton and xenon into clathrates on Mars

Calculations of the trapping of heavy noble gases within multiple guest clathrates under Mars-like conditions show that a substantial fraction of the martian Xe, perhaps even the vast majority, could be in clathrates. In addition, the Xe/Kr ratio in the clathrates would probably be much higher than in the atmosphere, so the formation or dissociation of a relatively small amount of clathrate could measurably change the atmospheric ratio. Relatively crude (factor of 2) measurements of the seasonal variability in that ratio by in situ spacecraft would be sensitive to ∼10% of the seasonal atmospheric CO₂ variability being a result of clathrates, rather than pure CO₂ frost. In addition, sequestration of Xe in clathrates remains a viable mechanism for explaining the variable Xe/Kr ratios seen in different suites of martian meteorites.     

Extreme Ultraviolet Variability Experiment (EVE) Multiple?EUV Grating Spectrographs (MEGS): Radiometric Calibrations and Results

The NASA Solar Dynamics Observatory (SDO), scheduled for launch in early 2010, incorporates a suite of instruments including the Extreme Ultraviolet Variability Experiment (EVE). EVE has multiple instruments including the Multiple Extreme ultraviolet Grating Spectrographs (MEGS) A, B, and P instruments, the Solar Aspect Monitor (SAM), and the Extreme ultraviolet SpectroPhotometer (ESP). The radiometric calibration of EVE, necessary to convert the instrument counts to physical units, was performed at the National Institute of Standards and Technology (NIST) Synchrotron Ultraviolet Radiation Facility (SURF III) located in Gaithersburg, Maryland. This paper presents the results and derived accuracy of this radiometric calibration for the MEGS A, B, P, and SAM instruments, while the calibration of the ESP instrument is addressed by Didkovsky et?al. (Solar Phys., 2010, doi: 10.1007/s11207-009-9485-8 ). In addition, solar measurements that were taken on 14 April 2008, during the NASA 36.240 sounding-rocket flight, are shown for the prototype EVE instruments.     

Reionization and the Cosmic Dawn with the Square Kilometre Array

The Square Kilometre Array (SKA) will have a low frequency component (SKA-low) which has as one of its main science goals the study of the redshifted 21 cm line from the earliest phases of star and galaxy formation in the Universe. This 21 cm signal provides a new and unique window both on the time of the formation of the first stars and accreting black holes and the subsequent period of substantial ionization of the intergalactic medium. The signal will teach us fundamental new things about the earliest phases of structure formation, cosmology and even has the potential to lead to the discovery of new physical phenomena. Here we present a white paper with an overview of the science questions that SKA-low can address, how we plan to tackle these questions and what this implies for the basic design of the telescope.     

Nitrogen utilisation by size‐fractionated phytoplankton assemblages associated with an upwelling event off Westland,New Zealand

Abstract

Uptake rates of ammonium (NH₄ ⁺ ), nitrate (NO₃ ^? ), and urea by three subgroups of phytoplankton (< 200, < 20, < 2 μm) off Westland, were measured using ¹⁵ N tracer techniques in midwinter 1988, after a recent upwelling. For all size fractions at surface irradiance (I₁₀₀), nitrogen (N) was taken up primarily as NO₃ ^?. This accounted for 67–85% of total N uptake (SρN), whereas at 40 and 7% of surface irradiance, the regenerated N (NH₄ ⁺ ) and urea) made up 31–72% of SρN. Depth profile experiments for all three size components showed that uptake of NO₃ ^? was most light‐sensitive, followed by that of NH₄ ⁺ and urea. The irradiance and nutrient availability plot indicated that light was substantially more important than the nutrient concentrations in controlling the assimilation of N by microplankton (20–200 μm). Nano‐ (2–20 μm) and picoplankton (< 2 μm) however, were not as sensitive to either light or nutrient concentrations. High winds and the resulting deep mixing, combined with offshore and alongshore advection in the midwinter, were suggested to be the major cause of the low biomass and N productivity.     

A discontinuous finite element baroclinic marine model on unstructured prismatic meshes

We describe the time discretization of a three-dimensional baroclinic finite element model for the hydrostatic Boussinesq equations based upon a discontinuous Galerkin finite element method. On one hand, the time marching algorithm is based on an efficient mode splitting. To ensure compatibility between the barotropic and baroclinic modes in the splitting algorithm, we introduce Lagrange multipliers in the discrete formulation. On the other hand, the use of implicit–explicit Runge–Kutta methods enables us to treat stiff linear operators implicitly, while the rest of the nonlinear dynamics is treated explicitly. By way of illustration, the time evolution of the flow over a tall isolated seamount on the sphere is simulated. The seamount height is 90% of the mean sea depth. Vortex shedding and Taylor caps are observed. The simulation compares well with results published by other authors.     

Characterizing and classifying urban watersheds with compositional and structural attributes

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.     

Avulsion regimes in southeast Texas rivers

Avulsions – relatively sudden changes in course, or establishment of new anabranches – are an important process in alluvial rivers. Their key role in floodplain construction and alluvial architecture, and the general conditions favouring avulsions, are well known. However, avulsion processes and evolution, and the factors controlling avulsion regimes, are poorly understood. In the southeast Texas coastal plain, where avulsions are common features of the river valleys, avulsions were studied on the lower Brazos, Navasota, Trinity, Neches and Sabine rivers using a combination of aerial imagery, digital elevation models and field surveys. Avulsions have important influences on the surface morphology and contemporary processes in all five rivers. Features associated with avulsions are active and distinct throughout the study area, and all the rivers have experienced geologically (if not historically) recent avulsions. However, no two of the study rivers have the same contemporary avulsion regime. First‐order differences in avulsion style are controlled by the stage of valley filling, and within the three rivers characterized by an unfilled incised valley, antecedent morphology associated with late Quaternary and Holocene coastal and fluvial‐deltaic processes accounts for the major differences. In the Navasota (27 avulsions in 185 km) and Neches (21 in 340 km) rivers, subchannels associated with avulsions exist in all stages of development from active to infilled, and some have occurred in recent decades. The other rivers have fewer avulsions, but both the Sabine and Trinity have experienced historic channel shifts. Only the Brazos River has experienced no avulsions within the past c. 300 years. Results show that even within a region of similar environmental controls and geological history local variations in inherited morphology can result in different avulsion regimes. Copyright © 2008 John Wiley & Sons, Ltd.