Perfluorinated compounds in estuarine and coastal areas of north Bohai Sea, China

Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed.     

Seasonal ground ice impacts on spring ecohydrological conditions in a western boreal plains peatland

Peatlands in the Western Boreal Plains act as important water sources in the landscape. Their persistence, despite potential evapotranspiration (PET) often exceeding annual precipitation, is attributed to various water storage mechanisms. One storage element that has been understudied is seasonal ground ice (SGI). This study characterized spring SGI conditions and explored its impacts on available energy, actual evapotranspiration, water table, and near surface soil moisture in a western boreal plains peatland. The majority of SGI melt took place over May 2017. Microtopography had limited impact on melt rates due to wet conditions. SGI melt released 139mm in ice water equivalent (IWE) within the top 30cm of the peat, and weak significant relationships with water table and surface moisture suggest that SGI could be important for maintaining vegetation transpiration during dry springs. Melting SGI decreased available energy causing small reductions in PET (<10mm over the melt period) and appeared to reduce actual evapotranspiration variability but not mean rates, likely due to slow melt rates. This suggests that melting SGI supplies water, allowing evapotranspiration to occur at near potential rates, but reduces the overall rate at which evapotranspiration could occur (PET). The role of SGI may help peatlands in headwater catchments act as a conveyor of water to downstream landscapes during the spring while acting as a supply of water for the peatland. Future work should investigate SGI influences on evapotranspiration under differing peatland types, wet and dry spring conditions, and if the spatial variability of SGI melt leads to spatial variability in evapotranspiration.     

Examining the geometry,age and genesis of buried Quaternary valley systems in the Midland Valley of Scotland,UK

Buried palaeo‐valley systems have been identified widely beneath lowland parts of the UK including eastern England, central England, south Wales and the North Sea. In the Midland Valley of Scotland palaeo‐valleys have been identified yet the age and genesis of these enigmatic features remain poorly understood. This study utilizes a digital data set of over 100 000 boreholes that penetrate the full thickness of deposits in the Midland Valley of Scotland. It identified 18 buried palaeo‐valleys, which range from 4 to 36 km in length and 24 to 162 m in depth. Geometric analysis has revealed four distinct valley morphologies, which were formed by different subglacial and subaerial processes. Some palaeo‐valleys cross‐cut each other with the deepest features aligning east–west. These east–west features align with the reconstructed ice‐flow direction under maximum conditions of the Main Late Devensian glaciation. The shallower features appear more aligned to ice‐flow direction during ice‐sheet retreat, and were therefore probably incised under more restricted ice‐sheet configurations. The bedrock lithology influences and enhances the position and depth of palaeo‐valleys in this lowland glacial terrain. Faults have juxtaposed Palaeozoic sedimentary and igneous rocks and the deepest palaeo‐valleys occur immediately down‐ice of knick‐points in the more resistant igneous bedrock. The features are regularly reused and the fills are dominated by glacial fluvial and glacial marine deposits. This suggests that the majority of infilling of the features happened during deglaciation and may be unrelated to the processes that cut them.     

Microzooplankton grazing and nitrogen excretion across a surface estuarine-coastal interface

The role of the microzooplankton community in regulating phytoplankton biomass was examined across a gradient from a river-dominated estuary to an oceanic-influenced coastal zone. Three stations located along a salinity gradient from the central region of Mobile Bay to 10 km off the coast were sampled from May 1994 to August 1995. Microzooplankton herbivory rates on phytoplankton and microzooplankton excretion of nitrogen derived from phytoplankton were estimated using the dilution technique. Microzooplankton grazing rates (range of station means=0.57–1.10 d⁻¹) and phytoplankton growth rates (0.70–1.62 d⁻¹) both increased across the salinity gradient from the bay station to the offshore station. However, the percent of primary production grazed per day was highest at the bay station (mean=83%) and decreased to a low at the offshore station (mean=64%). Excretion of phytoplankton-derived nitrogen by the microzooplankton was greatest at the bay and bay mouth stations. Excreted nitrogen could potentially supply 39%, 29%, and 20% of phytoplankton nitrogen demand at the bay, bay mouth, and offshore stations, respectively. These results support the idea that herbivorous microzooplankton are important in mediating nitrogen flow to both lower and higher trophic levels. *** DIRECT SUPPORT *** A01BY085 00012     

Flow localization in fissure eruptions

 During a basaltic fissure eruption heat transfer from the hot magma to the surrounding rock causes a dramatic increase in the magmatic viscosity and solidification at the margins. Both viscosity contrast and solidification can amplify initial variations in the flow rate and lead to localization of the flow along the strike of the fissure. However, for typical parameters, amplification driven by solidification is slower and significantly weaker than amplification driven by viscosity variations. In fact, for the parameters examined, the amplification due to solidification is so weak that its effect is almost insignificant, whereas viscosity variation provides a strong active mechanism for flow localization. Laboratory experiments illustrate viscous localization and suggest that this mechanism is robust. The dependence of viscosity on temperature can cause a small change in the pressure of the magma chamber to lead to a large jump in the flow rate of magma through the fissure. Received: 13 March 1998 / Accepted: 27 September 1998     

Analytic investigation of climate stability on Titan: sensitivity to volatile inventory

We develop a semiempirical grey radiative model to quantify Titan’s surface temperature as a function of pressure and composition of a nitrogen-methane-hydrogen atmosphere, solar flux and atmospheric haze. We then use this model, together with non-ideal gas-liquid equilibrium theory to investigate the behavior of the coupled surface-atmosphere system on Titan. We find that a volatile-rich Titan is unstable with respect to a runaway greenhouse—small increases in solar luminosity from the present value can lead to massive increases in surface temperature. If methane has been photolyzed throughout Titan’s history, then this runaway can only be avoided if the photolytic ethane is removed from the surface-atmosphere system.     

有机和常规农业管理方式下的浮游植物群落特征及其影响因素

为了解不同农业施肥管理方式对水体浮游植物群落的影响,本研究以江苏句容戴庄有机示范村和常规农业管理区池塘浮游植物为对象,分析冬夏两季浮游植物群落特征及相关水环境因子.结果表明：冬季有机和常规农业区域的浮游植物分别检到7门95种和7门111种,夏季分别检到7门102种和6门112种,有机农业区浮游植物由冬季的隐藻—绿藻型向夏季的蓝藻—绿藻型变化,常规农业区从隐藻—绿藻型向蓝藻—硅藻型变化,蓝藻逐渐取代隐藻的优势地位.夏季各池塘浮游植物alpha多样性没有显著的区域差异,但冬季常规农业区浮游植物物种丰富度、蓝藻和裸藻的Shannon-Wiener多样性指数显著较高.指示物种分析显示,谷皮菱形藻(Nitzschia palea)和梅尼小环藻(Cyclotella meneghiniana)为有机农业区指示物种,而梭形裸藻(Euglena acus)、针形纤维藻(Ankistrodesmus acicularis)、肘状针杆藻(Synedra ulna)和狭形纤维藻(Ankistrodesmus angustus)为常规农业区指示物种,此6种藻为中、富营养化藻类,说明水体氮磷营养盐浓度较高,这与...     

Fast numerics for the spin orbit equation with realistic tidal dissipation and constant eccentricity

We present an algorithm for the rapid numerical integration of a time-periodic ODE with a small dissipation term that is \(C^1\) in the velocity. Such an ODE arises as a model of spin–orbit coupling in a star/planet system, and the motivation for devising a fast algorithm for its solution comes from the desire to estimate probability of capture in various solutions, via Monte Carlo simulation: the integration times are very long, since we are interested in phenomena occurring on timescales of the order of \(10^6\)–\(10^7\) years. The proposed algorithm is based on the high-order Euler method which was described in Bartuccelli et al. (Celest Mech Dyn Astron 121(3):233–260, 2015), and it requires computer algebra to set up the code for its implementation. The payoff is an overall increase in speed by a factor of about 7.5 compared to standard numerical methods. Means for accelerating the purely numerical computation are also discussed.