Modeling the hydroclimatology of the midwestern United States. Part 1: current climate

An ensemble of six 22-year numerical experiments was conducted to evaluate the ability of Regional Climate Model version 3 (RegCM3) to simulate the energy and water budgets of the midwestern United States. RegCM3 was run using two surface physics schemes: Integrated Biosphere Simulator (IBIS) and Biosphere-Atmosphere Transfer Scheme 1e (BATS1e), and two convective closure assumptions: Fritsch & Chappell (FC80) and Arakawa & Schubert (AS74). Boundary conditions were provided by the National Centers for Environmental Prediction-Department of Energy Reanalysis 2 dataset and the ECHAM5 general circulation model. A companion paper examines the American Midwest under future climate scenarios. Overall, the model that reproduces the observed seasonal cycles of the midwestern United States climate system best is RegCM3 using IBIS and the AS74 convective closure assumption. IBIS simulates shortwave radiation more accurately, while BATS1e simulates longwave radiation more accurately. Summer two-meter air temperature is overestimated by the combination of IBIS and the FC80 convective closure assumption. All models contain a wet bias and overestimate evapotranspiration during the spring. Total runoff, surface runoff, groundwater runoff, and root zone soil moisture are best simulated by RegCM3 using IBIS and the AS74 convective closure assumption. While BATS1e does capture the seasonal cycle of total runoff, gross errors in the partitioning of total runoff between surface runoff and groundwater runoff exist. The seasonal cycle of root zone soil moisture simulated by RegCM3 using IBIS and the AS74 convective closure assumption is dry, but agrees with observations during the summer. The rest of the models underestimate root zone soil moisture.     

Perfluorinated compounds in estuarine and coastal areas of north Bohai Sea, China

Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed.     

Products of abiotic U(VI) reduction by biogenic magnetite and vivianite

Reductive immobilization of uranium by the stimulation of dissimilatory metal-reducing bacteria (DMRB) has been investigated as a remediation strategy for subsurface U(VI) contamination. In those environments, DMRB may utilize a variety of electron acceptors, such as ferric iron which can lead to the formation of reactive biogenic Fe(II) phases. These biogenic phases could potentially mediate abiotic U(VI) reduction. In this work, the DMRB Shewanella putrefaciens strain CN32 was used to synthesize two biogenic Fe(II)-bearing minerals: magnetite (a mixed Fe(II)-Fe(III) oxide) and vivianite (an Fe(II)-phosphate). Analysis of abiotic redox interactions between these biogenic minerals and U(VI) showed that both biogenic minerals reduced U(VI) completely. XAS analysis indicates significant differences in speciation of the reduced uranium after reaction with the two biogenic Fe(II)-bearing minerals. While biogenic magnetite favored the formation of structurally ordered, crystalline UO₂, biogenic vivianite led to the formation of a monomeric U(IV) species lacking U-U associations in the corresponding EXAFS spectrum. To investigate the role of phosphate in the formation of monomeric U(IV) such as sorbed U(IV) species complexed by mineral surfaces, versus a U(IV) mineral, uranium was reduced by biogenic magnetite that was pre-sorbed with phosphate. XAS analysis of this sample also revealed the formation of monomeric U(IV) species suggesting that the presence of phosphate hinders formation of UO₂. This work shows that U(VI) reduction products formed during in situ biostimulation can be influenced by the mineralogical and geochemical composition of the surrounding environment, as well as by the interfacial solute-solid chemistry of the solid-phase reductant.     

Oxygen sites in hydrous aluminosilicate glasses: the role of Al-O-Al and H2O

We describe here high-field ¹⁷O magic-angle-spinning (MAS) and triple-quantum MAS (3QMAS) NMR spectra for several alkali silicate and Na, K, and Ca aluminosilicate glasses containing up to 10 wt.% water. The H₂O site appears to have a large quadrupolar coupling constant, and its chemical shift increases from Na- to K- glasses, suggesting significant cation-H₂O interactions. In ¹⁷O one-pulse MAS and 3QMAS and ²⁷Al one-pulse NMR experiments, major differences were seen between spectra for anhydrous and hydrous calcium aluminosilicate glasses. The changes in the ¹⁷O MAS spectra can be explained by the addition of an H₂O peak and to the disappearance of an Al-O-Al peak from the ¹⁷O NMR spectrum for the hydrous glass. The ²⁷Al results are consistent with this interpretation.     

Sediment transport and trapping in the Hudson River estuary

The Hudson River estuary has a pronounced turbidity maximum zone, in which rapid, short-term deposition of sediment occurs during and following the spring freshet. Water-column measurements of currents and suspended sediment were performed during the spring of 1999 to determine the rate and mechanisms of sediment transport and trapping in the estuary. The net convergence of sediment in the lower estuary was approximately 300,000 tons, consistent with an estimate based on sediment cores. The major input of sediment from the watershed occurred during the spring freshet, as expected. Unexpected, however, was that an even larger quantity of sediment was transported landward into the estuary during the 3-mo observation period. The landward movement was largely accomplished by tidal pumping (i.e., the correlation between concentration and velocity at tidal frequencies) during spring tides, when the concentrations were 5 to 10 times higher than during neap tides. The landward flux is not consistent with the long-term sediment budget, which requires a seaward flux at the mouth to account for the excess input from the watershed relative to net accumulation. The anomalous, landward transport in 1999 occurred in part because the freshet was relatively weak, and the freshet occurred during neapetides when sediment resuspension was minimal. An extreme freshet occurred during 1998, which may have provided a repository of sediment just seaward of the mouth that re-entered the estuary in 1999. The amplitude of the spring freshet and its timing with respect to the spring-neap cycle cause large interannual variations in estuarine sediment flux. These variations can result in the remobilization of previously deposited sediment, the mass of which may exceed the annual inputs from the watershed.     

Effect of faceting on pore geometry in texturally equilibrated rocks: implications for low permeability at low porosity

The pore geometry of texturally equilibrated rocks is controlled by the interfacial energy ratio between grain boundaries and solid–liquid boundaries. Faceting at pore walls, which is a common feature of pore networks in rocks, strongly affects the liquid distribution. We investigated the effects of faceting on the equilibrium pore geometries based on image analysis of several systems with various degrees of faceting and dihedral angles. The degree of faceting was assessed by the F value, which is the ratio of the flat interface length at the pore wall to the length of total interfacial boundary between solid and liquid. The F values tend to increase with increasing liquid volume fraction. Little-faceted systems show relatively homogeneous liquid distribution. Moderately-faceted systems with a higher dihedral angle (∼55°) are characterized by development of large pores surrounded by faceted walls and complementary shrinkage of triple junction tubes, whereas strongly faceted systems with a low dihedral angle show no evidence of shrinking triple junction tubes, although most pores are surrounded by faceted pore walls. The faceted systems tend to produce more facet boundaries at the pore walls due to the difference of interfacial energies between the flat and curved surfaces. In the systems with the same degree of faceting, heterogeneity of liquid distribution tends to decrease with dihedral angle. For faceting systems, the permeability of texturally equilibrated rocks with low liquid fraction would be significantly decreased by the relative reduction of triple junction volumes or by closure of channels along grain edge due to the truncation of facet walls.     

Geochemistry of Neogene sedimentary rocks from Borneo Basin,East Malaysia: Paleo-weathering,provenance and tectonic setting

Multi-element geochemistry and mineralogy are used to characterize the chemical composition, degree of paleo-weathering, provenance and tectonic settings of the Neogene sedimentary rocks of Borneo Basin of east Malaysia. Sedimentary rocks are classified as extremely weathered sandstones (i.e. wacke, arkose, litharenite, Fe-sandstone and quartz arenite). Wacke, arkose, litharenite and Fe-sandstone are characterized by post-depositional K-metasomatism and zircon enrichment through sediment recycling. Geochemical characteristics suggest a mixed-nature provenance for the sandstones and the variable tectonic settings possibly mirror the complexity of the basin. Enriched Cr in quartz arenite and Fe-sandstone are related to the contribution from ophiolite or fractionation of Cr-bearing minerals.     

The sedimentology of river confluences

Channel confluences are key nodes within large river networks, and yet surprisingly little is known about their spatial and temporal evolution. Moreover, because confluences are associated with vertical scour that typically extends to several times the mean channel depth, the deposits associated with such scours should have a high preservation potential within the rock record. Paradoxically, such scours are rarely observed, and their preservation and sedimentological interpretation are poorly understood. The present study details results from a physically‐based morphodynamic model that is applied to simulate the evolution and alluvial architecture of large river junctions. Boundary conditions within the model were defined to approximate the junction of the Ganges and Jamuna rivers, Bangladesh, with the model output being supplemented by geophysical datasets collected at this junction. The numerical simulations reveal several distinct styles of sedimentary fill that are related to the morphodynamic behaviour of bars, confluence scour downstream of braid bars, bend scour and major junction scour. Comparison with existing, largely qualitative, conceptual models reveals that none of these can be applied simply, although elements of each are evident in the deposits generated by the numerical simulation and observed in the geophysical data. The characteristics of the simulated scour deposits are found to vary according to the degree of reworking caused by channel migration, a factor not considered adequately in current conceptual models of confluence sedimentology. The alluvial architecture of major junction scours is thus characterized by the prevalence of erosion surfaces in conjunction with the thickest depositional sets. Confluence scour downstream of braid bar and bend scour sites may preserve some large individual sets, but these locations are typically characterized by lower average set thickness compared to major junction scour and by a lack of large‐scale erosional surfaces. Areas of deposition not related to any of the specific scour types highlighted above record the thinnest depositional sets. This variety in the alluvial architecture of scours may go some way towards explaining the paradox of ancient junction scours, that while abundant large scours are likely in the rock record, they have been reported rarely. The present results outline the likely range of confluence sedimentology and will serve as a new tool for recognizing and interpreting these deposits in the ancient fluvial record.     

Discussion of ‘Coarse‐sand beach ridges at Cowley Beach,north‐eastern Australia: Their formative processes and potential as records of tropical cyclone history’ by Tamura et al. (2018), Sedimentology, 65, 721–744

The processes resulting in the formation of a coarse‐grained sand beach ridge plain at Cowley Beach, north‐east Australia have been questioned by Tamura et al. (2018). These authors now acknowledge the conclusions by Nott et al. (2009) and Nott (2014) that the dominant depositional mechanisms here are waves and inundations generated during tropical cyclones. The Tamura et al. (2018) new ground penetrating radar data highlights that scarping of incipient ridges is a common feature and occurs regularly under non‐storm conditions. The upper sedimentary units deposited during storms are not scarped and demonstrate the high preservation potential and usefulness of these deposits for reconstructing long‐term records of tropical cyclones. Tamura et al. (2018) question the robustness of the methodology used by Nott & Hayne (2001), Nott (2003) and Nott et al. (2009) in estimating the magnitude of the storms responsible for these sedimentary deposits. These supposed issues though have been dealt with in detail in a series of publications over the past nearly two decades. The shortcomings of the Tamura et al. (2018) criticisms are explained in detail here.