Os isotopes in mantle xenoliths from the Eifel volcanic field and the Vogelsberg (Germany): age constraints on the lithospheric mantle

The effects of mantle metasomatism on the sulfide phase in mantle xenoliths in general, and on the Os isotopic system in particular, have received increased attention in recent years. Here, we report on Os isotopic systematics of metasomatized mantle xenoliths from the late Quaternary Eifel (Dreiser Weiher and Meerfelder Maar) and neighboring Vogelsberg volcanic fields, which provide insight into the effects of melt extraction and metasomatism on Os isotopes and place constraints on the evolution of the lithospheric mantle component beneath central Europe. Sixteen harzburgite, lherzolite, and pyroxenite xenoliths from the Eifel and two lherzolite xenoliths from the Vogelsberg were analyzed for Os isotopes. Samples from the anhydrous peridotite suite (Ib) are highly variable in their Os isotopes, ranging from subchondritic values (¹⁸⁷Os/¹⁸⁸Os=0.1236) to suprachondritic values (¹⁸⁷Os/¹⁸⁸Os=0.1420), indicating that some of these samples have been overprinted by the addition of radiogenic Os and have lost the primary mantle Os that was presumably present. The suprachondritic values suggest a source for this Os in a reservoir with a time-integrated Re/Os ratio greater than that of the bulk Earth. Eifel samples with Os contents >1.5 ng/g from the hydrous suite (Ia) have relatively unradiogenic Os isotope compositions (¹⁸⁷Os/¹⁸⁸Os=0.1208-0.1237) and Al₂O₃-Os isotopic systematics consistent with ancient melt depletion and isolation from the convecting asthenospheric mantle for time periods similar to the age of the overlying crust (~1.5 Ga) as well with results from peridotite massifs in the European region. The LREE-metasomatism and the enrichment of Os (up to 6.47 ng/g) and As (sulfide metasomatism?) in the hydrous suite is strongly inversely correlated with the Os isotope ratios, demonstrating that mantle processes such as metasomatism can significantly modify the Os isotope chemistry of mantle xenoliths.     

Transnational elites in global cities: British expatriates in Singapore's financial district

Skilled international migration is as an important process of both contemporary globalization and the global city. The establishment of a transnational elite of expatriate labour in international finance plays a vital part in the accumulation of capital within international financial centres (IFCs). Expatriate labour has become a major determinant of the IFC, creating financial capital through complex social relations, knowledge networks, practices and discourses. The principal argument being made in this paper is that expatriates are major agents in the accumulation and transfer of financial knowledge in the IFC, and that such processes are undertaken through expatriate global–local knowledge networks and other social practices. The paper is divided into three major parts. Following a discussion of transnational elites as expatriates in global cities, which also conceptualises their contribution to the spatialization of financial knowledge networks, the empirical study investigates the working, social and cultural knowledge networks and practices of British expatriates in Singapore. Finally, the paper revisits the conceptual work on transnational elites and suggests that expatriates were deeply embedded in global–local relations in the workplace and the business/social sphere through interaction with local ‘western educated/experienced' Singaporeans, but were disembedded from the local in the home and other household social spaces due to the invisibility of the local population in their interactions. Both the theoretical and empirical analyses suggests that expatriates are flow in the Castellian spatial logic of the network society.     

Late Quaternary Water-Level Variations and Vegetation History at Crooked Pond, Southeastern Massachusetts

Sediment cores collected along a transect in Crooked Pond, southeastern Massachusetts, provide evidence of water-level changes between 15,000 cal yr B.P. and present. The extent of fine-grained, detrital, organic accumulation in the basin, inferred from sediment and pollen stratigraphies, varied over time and indicates low water levels between 11,200 and 8000 cal yr B.P. and from ca. 5300 to 3200 cal yr B.P. This history is consistent with the paleohydrology records from nearby Makepeace Cedar Swamp and other sites from New England and eastern Canada and with temporal patterns of regional changes in effective soil moisture inferred from pollen data. The similarities among these records indicate that (1) regional conditions were drier than today when white pine (Pinus strobus) grew abundantly in southern New England (11,200 to 9500 cal yr B.P.); (2) higher moisture levels existed between 8000 and 5500 cal yr B.P., possibly caused by increased meridonal circulation as the influence of the Laurentide ice sheet waned; and (3) drier conditions possibly contributed to the regional decline in hemlock (Tsuga) abundances at 5300 cal yr B.P. Although sea-level rise may have been an influence, moist climatic conditions during the late Holocene were the primary reason for a dramatic rise in water-table elevations.     

A 29Si MAS NMR study of sub-Tg amorphization of stishovite at ambient pressure

Stishovite, a high-pressure SiO₂ polymorph in which each Si is coordinated by six O atoms, transforms to an amorphous phase when undergoing heat treatment below the glass transition temperature at ambient pressure. We have applied ²⁹Si magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR) to study this amorphization process. We found that the amorphous phase generated after heating stishovite for up to 3 days at around 600 ° C consisted exclusively of four-coordinate Si, similar to glasses quenched from melts at ambient pressure. Furthermore, our data suggest that there are subtle structural differences between the amorphous phase transformed from stishovite at 600 ° C and glasses quenched from melts at ambient pressure: the amorphous phase from stishovite had a smaller mean Si-O-Si angle initially, and it gradually relaxed toward the latter with increasing heating time. There was no detectable change in the stishovite structure even after about 80% of it had been converted to the amorphous phase. The mechanism of the amorphization of stishovite is discussed in light of these results.     

Periodic frontogenesis in a region of freshwater influence

Observations are presented from a series of three conductivity-temperature-depth (CTD) surveys of the salinity and temperature structure of Liverpool Bay, a region that is strongly influenced by the input of fresh water from the rivers of northwest England. The surveys demonstrate the development, seaward movement, and eventual decay of a haline front. The frontogenesis is driven by the relaxation of a freshwater-induced horizontal density gradient following the decrease in tidal range at neap tides. It results in the area of Liverpool Bay being stratified for a period of 8 d before the increase in tidal mixing as the spring tide approaches returns the region to its initial vertically mixed state. In Liverpool Bay this process usually repeats on the spring-neap cycle, though strong wind-mixing may prevent the frontogenesis and subsequent stratification. Analysis with a 1-dimensional numerical model suggests that relaxation of an initially nonlinear horizontal density field, creating the front, is triggered by the stability produced by tidal straining of the water column during the ebb half-cycle. The reduction in tidal mixing energy approaching neap tide does not lead to frontogenesis without this initial stability. Such a regular stratification signal will have a marked effect on the local environment. The periodic frontogenesis will act as a tidal pump, moving buoyant substances in the water column offshore, while the onshore residual currents lower in the water column will more deeper dissolved substances inshore. The cycling of stability on the springneap time scale is considerably faster than the seasonal cycle of thermal stratification in the shelf seas, but is similar in creating the conditions required for phytoplankton blooms. Conditions favorable for enhanced primary production may therefore occur frequently in such regions of freshwater influence.     

Bonding and dynamical phenomena in MgO: A high temperature 17O and 25Mg NMR study

We have measured the isotropic chemical shifts (δ_iso) and the spin-lattice relaxation times (T₁) for ¹⁷O and ²⁵Mg in MgO from room temperature up to 1300° C. The ¹⁷O chemical shifts increase linearly from 47 ppm at room temperature to 57 ppm at 1300° C, and over the same temperature range the ²⁵Mg chemical shift increases linearly from 25 to 27 ppm. These changes are not the result of changes in the bulk magnetic susceptibility of the samples, but may be due to increased orbital overlap which is the result of the increase in thermal vibration of the ions with temperature. In the case of ²⁵Mg, the shift to lower shielding with increasing temperature is opposite to that expected from simple bond length versus chemical shift trends established for the oxides at room temperature. If this is a general phenomenon, high-temperature NMR data may be biased to lower shielding. Spin-lattice relaxation times (T₁) were measured in order to study the energetics of defect motion. T₁'s for ¹⁷O and ²⁵Mg exhibit similar behavior over the range of temperatures studied. Up to 800° C, T₁'s decrease gradually, but above 800° C, T₁'s drop rapidly, with slopes corresponding to apparent activation energies of 192±9 kJ/mol (2.0±0.1 eV) for ¹⁷O and 151±6 kJ/mol (1.56±0.06 eV) for ²⁵Mg. While direct comparison of these activation energies to those derived from diffusion or conductivity measurements is complicated, the similar behavior for both nuclei suggests their relaxation phenomena are related.     

Crust-mantle interaction in continental arcs: inferences from the Mesozoic arc in the southwestern United States

Arc magmas ranging in composition from basaltic andesites to rhyolites and intrusive equivalents were emplaced into the western margin of the North American craton starting in Late Triassic time giving way to rift0related sedimentation in the Late Jurassic. The region of this study cuts across Proterozoic basements of contrasting Nd model ages, 1.7–1.8 Ga (average ɛ_Nd∼−11) in eastern Arizona and 2.0 to 2.3 GA (average ɛ_Nd∼−18) in western Arizona and eastern California (Bennett and DePaolo 1987). The Mesozoic rocks have initial ɛ_Nd of -3.4 to-6.4 in the eastern part of the study area and -7.1 to -9.2 in the western part. All of the rocks have elevated ⁸⁷Sr/⁸⁷Sr initial ratios (>0.706). Trends in initial ɛ_Nd values of Mesozoic arc rocks are directly correlated with the Nd model ages of the basement through which they passed. Simple two-component mixing calculations indicate that recycled continental crust in the arc magmas represents on average about 65%. A minimum of 35% mantle input into continental arc magmas, as recent as the Mesozoic, represents a significant contribution to the growth of the continental crust, in the absence of a return flow of continental material into the mantle of similar magnitude. In a detailed study in the Santa Rita Mountains. Arizona, there is a pattern of increase of ɛ_Nd with time: early basaltic andesites have more negative ɛ_Nd than later felsic rocks. A correlated pattern of depletion with time is also observed with trace element and major element data. We attribute this either to progressive hybridization of the lower crust by repeated injection of mantle magmas, or the progressive thinning of the continental crust during prolonged arc magmatism. The present data do not allow distinction between the two models. Progressive decrease in crustal contribution to arc magmas with time may be an important feature of continental arc evolution. Hybridization of the lower crust due to repeated injection of mantle melts during arc magmatism may help contribute to small-scale heterogeneities in lower crust inferred from seismic and xenolith data. Similarly, whether there is a well defined MOHO or sharp crust-mantle boundary in any given segment of the continental crust may in part depend on the extent of crust modification as a result of continental arc magmatism.     

THREE-DIMENSIONAL, CROSS-SEMIVARIOGRAM CALCULATIONS FOR HYDROGEOLOGICAL DATA

Abstract. Geostatistics is a powerful tool for the analysis of hydrogeological data, but few well-documented computer programs for performing the necessary calculations have been presented in the technical literature. This is especially true for applications that require either three-dimensional or multivariate analyses. This paper describes a FORTRAN subroutine, VARIO, that can be used to compute experimental direct- and cross-semivariograms from a set of sample data, for any specified direction in one-, two-, or three-dimensional space. The subroutine combines into groups those sample pairs that fall within predetermined angular tolerances of the specified direction. The number of sample pairs used to compute the value of the experimental semivariogram at each value of separation can be specified in four different ways, depending on the nature of the available data. Written in FORTRAN 77, VARIO can be used on any computer that supports a FORTRAN 77 compiler. Source code listing, user instructions, and example input and output data for VARIO are presented.