Hydropyrolysis: A new technique for the analysis of macromolecular material in meteorites

The carbonaceous chondrite meteorites are fragments of asteroids that have remained relatively unprocessed since the formation of the Solar System 4.56 billion years ago. The major organic component in these meteorites is a macromolecular phase that is resistant to solvent extraction. The information contained within macromolecular material can be accessed by degradative techniques such as pyrolysis. Hydropyrolysis refers to pyrolysis assisted by high hydrogen gas pressures and a dispersed sulphided molybdenum catalyst. Hydropyrolysis of the Murchison macromolecular material successfully releases much greater quantities of hydrocarbons than traditional pyrolysis techniques (twofold greater than hydrous pyrolysis) including significant amounts of high molecular weight polyaromatic hydrocarbons (PAH) such as phenanthrene, carbazole, fluoranthene, pyrene, chrysene, perylene, benzoperylene and coronene units with varying degrees of alkylation. When hydropyrolysis products are collected using a silica trap immersed in liquid nitrogen, the technique enables the solubilisation and retention of compounds with a wide range of volatilities (i.e. benzene to coronene). This report describes the hydropyrolysis method and the information it can provide about meteorite macromolecular material constitution.     

Holocene millennial/centennial‐scale multiproxy cyclicity in temperate eastern Australian estuary sediments

We have undertaken a comparative study of down‐core variation in multiproxy palaeoclimate data (magnetic susceptibility, calcium carbonate content and total organic carbon) from two coastal water bodies (Myall and Tuggerah Lakes) in temperate eastern Australia to identify local, regional and global‐forcing factors within Holocene estuarine sediments. The two lakes lie within the same temperate climate zone adjacent to the Tasman Sea, but are not part of the same catchment and drain different geological provinces. One is essentially a freshwater coastal lake whereas the other is a brackish back‐barrier lagoon. Despite these differences, data from two sites in each of the two lakes have allowed us to investigate and compare cyclicity in otherwise uniform, single facies sediments within the frequency range of 200–2000 years, limited by the sedimentation rate within the lakes and our sample requirements. We have auto‐ and cross‐correlated strong periodicities at ～360 years, ～500–530 years, ～270–290 years, 420–450 years and ～210 years, and subordinate periods of ～650 years, 1200–1400 years and ～1800 years. Our thesis is that climate is the only regionally available mechanism available to control common millennial and centennial scale cyclicity in these sediments, given the geographical and other differences. However, regional climate may not be the dominant effect at any single time and either location. Within the range of frequency spectral peaks we have identified, several fall within known long‐term periodical fluctuations of sun spot activity; however, feedback loops associated with short‐term orbital variation, such as Dansgaard–Oeschger cycles, and the relationship between these and palaeo‐ENSO variation, are also possible contributors. Copyright © 2005 John Wiley & Sons, Ltd.     

Understanding and Reducing False Alarms in Observational Fog Prediction

The reduction in visibility that accompanies fog events presents a hazard to human safety and navigation. However, accurate fog prediction remains elusive, with numerical methods often unable to capture the conditions of fog formation, and observational methods having high false-alarm rates in order to obtain high hit rates of prediction. In this work, 5 years of observations from the Cabauw Experimental Site for Atmospheric Research are used to further investigate how false alarms may be reduced using the statistical method for diagnosing radiation-fog events from observations developed by Menut et al. (Boundary-Layer Meteorol 150:277–297, 2014). The method is assessed for forecast lead times of 1–6 h and implementing four optimization schemes to tune the prediction for different needs, compromising between confidence and risk. Prediction scores improve significantly with decreased lead time, with the possibility of achieving a hit rate of over 90% and a false-alarm rate of just 13%. In total, a further 31 combinations of predictive variables beyond the original combination are explored (including mostly, e.g., variables related to moisture and static stability of the boundary layer). Little change to the prediction scores indicates any appropriate combination of variables that measure saturation, turbulence, and near-surface cooling can be used. The remaining false-alarm periods are manually assessed, identifying the lack of spatio–temporal information (such as the temporal evolution of the local conditions and the advective history of the airmass) as the ultimate limiting factor in the methodology’s predictive capabilities. Future observational studies are recommended that investigate the near-surface evolution of fog and the role of non-local heterogeneity on fog formation.     

The impact of the US retreat from the Paris Agreement: Kyoto revisited?

The United States’ decision to withdraw from the Paris Agreement (pending possible re-engagement under different terms) may have significant ramifications for international climate policy, but the implications of this decision remain contested. This commentary illustrates how comparative analysis of US participation in multilateral environmental agreements can inform predictions and future assessments of the decision. We compare and contrast US non-participation in the Kyoto Protocol and the Paris Agreement, focusing on four key areas that may condition the influence of US treaty decisions on international climate policy: (i) global momentum on climate change mitigation; (ii) the possibility of US non-participation giving rise to alternative forms of international collaboration on climate policy; (iii) the timing and circumstances of the US decision to exit; and (iv) the influence of treaty design on countries’ incentives to participate and comply. We find that differences across the two treaties relating to the first three factors are more likely to reduce the negative ramifications of US withdrawal from the Paris Agreement compared to the Kyoto Protocol. However, the increased urgency of deep decarbonization renders US non-participation a major concern despite its declining share of global emissions. Moreover, key design features of the Paris Agreement suggest that other countries may react to the US decision by scaling back their levels of ambition and compliance, even if they remain in the Agreement.

Key policy insights

• Increasing global momentum on mitigation since 1997 means that US withdrawal from the Paris Agreement is potentially less damaging than its non-participation in the Kyoto Protocol

• Despite the declining US share of global emissions, greater urgency of deep decarbonization means that the non-participation of a major player, such as the US, remains problematic for global cooperation and achieving the Paris Agreement’s goals

• Differences in the design of the Kyoto Protocol and Paris Agreement suggest that US non-participation is more likely to prompt reluctant countries to stay within the Paris framework but reduce levels of ambition and compliance, rather than exit the Agreement altogether

     

Speleothem stable isotope records interpreted within a multi-proxy framework and implications for New Zealand palaeoclimate reconstruction

A primary step in the interpretation of speleothem stable isotope records (¹⁸O/¹⁶O and ¹³C/¹²C) is to conduct a comparison with other local palaeoclimate proxies. Here, two new master speleothem δ¹⁸O and δ¹³C records (one from eastern North Island, and the other from western/southern South Island, New Zealand) are evaluated against independent precipitation and temperature proxy information to assess their palaeoclimate reconstruction potential. This comparison also resulted in a serendipitous opportunity to reconstruct past circulation using climate regime classification [Lorrey, A.M., Fowler, A.M., Salinger, J., 2007a. Regional climate regime classification as a qualitative tool for interpreting multi-proxy palaeoclimate data spatial patterns: a New Zealand case study. Palaeo-3, in press], specifically because these two regional climate districts are hyper-sensitive to westerly circulation changes, and in many cases, exhibit contrasting climate character in response to circulation anomalies.For both the western South Island and the eastern North Island master speleothem δ¹³C records, variations tracked changes in relative regional precipitation. The δ¹⁸O master speleothem record for both regions varied with temperature change. Both records contain strong regional climate signals that suggest they have good value for palaeoclimate reconstruction. The ensuing attempt at a multi-proxy reconstruction of regional climate regimes from the compiled proxies indicates past circulation in the New Zealand sector has varied considerably during the past four millennia. Centennial-scale circulation changes for the past 4000 years are evident, and are analogous to modern Blocking, Zonal and Trough regime types [Kidson J. W., 2000. An analysis of New Zealand synoptic types and their use in defining weather regimes. International Journal of Climatology 20, 299–316] that characterise changes in present-day (prevailing) westerly circulation. This palaeoclimate reconstruction indicates modern regional climate regime classification can be extended at least as far back as the temporal coverage of the records presented here, and it can likely be improved on with better dating control and the addition of new records with higher resolution. It is also anticipated that future work will expand to include more proxy data from across New Zealand to improve the clarity of past climate regime occurrence for the Late Holocene.     

Drinking water quality in Nepal’s Kathmandu Valley: a survey and assessment of selected controlling site characteristics

Water was sampled from over 100 sources in Nepal’s Kathmandu Valley, including municipal taps, dug wells, shallow-aquifer tube wells, deep-aquifer tube wells, and dhunge dharas (or stone spouts, public water sources that capture groundwater or surface water). Information was gathered on user preference and site and well characteristics, and water was examined for indicators of contamination from sewage, agriculture, or industry. Most problematic were total coliform and Escherichia coli bacteria, which were present in 94 and 72% of all the water samples, respectively. Contamination by nitrate, ammonia and heavy metals was more limited; nitrate and ammonia exceeded Nepali guidelines in 11 and 45% of the samples, respectively. Arsenic and mercury exceeded WHO guidelines in 7 and 10% of the samples, respectively, but arsenic never exceeded the less strict Nepali guideline. Significant differences existed in contamination levels between types of sources; dug wells and dhunge dharas, being the shallowest, were the most contaminated by bacteria and nitrate; deep-aquifer tube wells were the most contaminated by arsenic. Whereas E. coli concentrations decreased with depth, iron and ammonia concentrations increased with depth. These relationships account for people choosing to drink water with higher levels of bacterial contamination based on its superior (non-metallic) taste and appearance.     

Sample-size implications of the trace-element variability of ostracod shells

The magnesium and strontium contents of fossil ostracod-shell calcite have been used extensively in the reconstruction of water composition and temperature in lakes and, to a lesser degree, in marginal-marine waters and in the deep ocean. Current instrumentation may allow single shells of these calcite microfossils to be analysed and most studies have taken advantage of this capability. However, there is now good evidence for large intra-sample variability in the trace-element content of ostracod shells, both in living populations and in fossil assemblages, and this has implications for any attempt to distinguish the low-frequency (∼decadal or longer) trends in water temperature and composition that are often the goals of palaeoenvironmental studies, from higher-frequency (seasonal or interannual) ‘noise’. In this study, the Mg and Sr contents of living and fossil populations of six species of marine, marginal-marine and shallow-marine ostracods from 11 sites are used to investigate sources of variability and to estimate critical sample sizes for stratigraphic studies. Results confirm that variability amongst individual samples is generally wide and cannot be attributed to instrumental error or sample handling alone. In some instances, variability can be explained by fluctuations in water composition and/or temperature, although this has to be evaluated in each case. Some evidence points to non-environmental control on variability in shell composition, perhaps connected to genetically-controlled differences in physiology that affected calcification, early diagenetic alteration, or the role of environmental factors other than temperature or water composition. However, further work is needed to verify this. In some stratigraphic studies, large numbers (>20) of individual shells would need to be analysed in order to detect low-frequency environmental changes with any degree of confidence, although fewer shells may often suffice. The critical sample size depends on the variability at each study site, which should ideally be evaluated using pilot studies.     

Enclosure experiments on survival and growth of black drum eggs and larvae in lower Chesapeake Bay

Experiments in 2.2 m³, in situ mesocosm enclosures indicate that black drum, Pogonias cromis, eggs and larvae potentially can survive in the lower Chesapeake Bay at ambient microzooplankton prey levels (≈200 prey 1^?1) in the absence of predators. In growth experiments, larva mean growth rates to 10 d posthatch were similar (0.17 mm d^?1 and 0.18 mm d^?1) when fed at prey levels of 50 prey 1^?1 and 200 prey 1^?1. Individual growth rates, however, were more variable at 50 prey 1^?1. Mortality rates also were comparable in 50 (27% d^?1) and 200 (23% d^?1) prey 1^?1 enclosures. In a second experiment, the predation potentials of the hydromedusa Nemopsis bachei and the lobate ctenophore Mnemiopsis leidyi were estimated in relation to initial black drum egg prey density, presence of alternative <1 mm zooplankton prey, and estimated daily abundance of the jellyfish on the black drum spawning grounds. Mortality rates per medusa and ctenophore were similar (0.02–0.03 d^?1), were not affected by presence of alternative prey, and were directly related to initial egg density. Results suggest that the gelatinous predators, especially the hydromedusa, could have cleared a high (≈38%) but variable fraction of the water column daily of fish eggs and yolk-sac larvae during the black drum spawning season. We hypothesize that the poor or episodic recruitment success of black drum in Chesapeake Bay results from a short spawning season that often coincides with abundance peaks of gelatinous predators and that predation on eggs and yolk-sac larvae may control recruitment.     

Depositional features in tourist beaches of Chennai Metropolis,SE coast of India: Inferences from grain size studies

The present study was undertaken to examine the depositional and transportation pattern in the tourist beaches of Chennai in SE coast of India. Twenty four samples were analyzed for textural parameters, Linear discriminate function (LDF), C-M plots and heavy/light minerals from beach, berm and dune regions. Results of textural parameters indicate that they are coarse grained in the three regions. Majority of the samples indicate that they are moderately well sorted, symmetrically skewed and leptokurtic. The LDF analysis allowed in identifying areas that are characterized by: (1) beach, (2) shallow agitated environment and (3) fluvial deposits. C-M plots indicate that the sediments in the beaches were deposited from the near shore environment. Heavy mineral analysis suggests that the heavy and light minerals were in the range of 0.5 to 16.9% and 82.08 to 98.14% and the light/dark layers are controlled by the prevailing tidal conditions in the coastal region. It is observed that sand is accumulating from the shallow agitated environment, while the transportation and deposition of sediments is mainly due to the interaction of tidal activities at the same time. C-M plots suggest that the sediments fall in the graded suspension and the saltation activities in the region also facilitate to understand the hydrodynamics of the region suggesting that they are deposited by high-energy activities.