The Langeland Fault System unravelled: Quaternary fault reactivation along an elevated basement block between the North German and Norwegian–Danish basins

The reactivation of faults and possible impact on barrier integrity marks a critical aspect for investigations on subsurface usage capabilities. Glacial isostatic adjustments, originating from repeated Quaternary glaciations of northern Europe, cause tectonic stresses on pre-existing fault systems and structural elements of the North German and Norwegian–Danish basins. Notably, our current understanding of the dynamics and scales of glacially induced fault reactivation is rather limited. A high-resolution 2D seismic data set recently acquired offshore northeastern Langeland Island allows the investigation of a fault and graben system termed the Langeland Fault System. Seismo-stratigraphic interpretation of reflection seismic data in combination with diffraction imaging unravels the spatial character of the Langeland Fault System along an elevated basement block of the Ringkøbing–Fyn High. In combination with sediment echosounder data, the data set helps to visualize the continuation of deep-rooted faults up to the sea floor. Initial Mesozoic faulting occurred during the Triassic. Late Cretaceous inversion reactivated a basement fault flanking the southern border of the elevated basement block of the Ringkøbing–Fyn High while inversion is absent in the Langeland Fault System. Here, normal faulting occurred in the Maastrichtian–Danian. We show that a glacial or postglacial fault reactivation occurred within the Langeland Fault System, as evident by the propagation of the faults from the deeper subsurface up to the sea floor, dissecting glacial and postglacial successions. Our findings suggest that the Langeland Fault System was reactivated over a length scale of a minimum of 8.5 km. We discuss the causes for this Quaternary fault reactivations in the context of glacially induced faulting and the present-day stress field. The combination of imaging techniques with different penetration depths and vertical resolution used in this study is rarely realized in the hinterland. It can therefore be speculated that many more inherited, deep-rooted faults were reactivated in Pleistocene glaciated regions.     

Geology,petrology and geochemistry of the “Americano do Brasil” layered intrusion,central Brazil,and its Ni–Cu sulfide deposits

The “Americano do Brasil” Complex (ABC) is part of a cluster of coeval synorogenic mafic–ultramafic intrusions emplaced during the Brasiliano/Pan-African Orogenic Cycle in Brazil. The medium-sized ABC consists of interlayered dunite, peridotite, websterite, and gabbronorite. High Fo values of olivine (up to Fo₈₈) and the crystallization sequence of the ABC (Ol + Chr ≥ Ol + Opx + Chr ≥ Cpx + Opx ≥ Opx + Pl + Cpx ≥ Opx + Pl + Cpx + Ilm + Mag) suggest crystallization from tholeiitic high-MgO parental magmas. Light rare earth element (REE)-enriched mantle-normalized REE profiles and εNd(T) values of +2.4 for cumulate rocks from the ABC suggest a depleted mantle source for the parental magma. The ABC Ni–Cu sulfide deposit (3.1 Mt at 1.12 wt.% Ni and 1.02 wt.% Cu) consists of three distinctively different orebodies (S1, S2, and G2). The S2 orebody, an unusual occurrence of stratiform massive sulfide hosted by dunite and peridotite in the interior of a layered intrusion, results from sulfides accumulated at the transient base of the magma chamber following a new influx of parental magma. The G2 orebody has an irregular and roughly cylindrical shape, consisting mainly of net-textured sulfides. The G2 orebody is hosted by peridotite and pyroxenite and located stratigraphically below the S1 orebody. S2 and G2 orebodies are characterized by low Cu/Cu + Ni ratios (mainly below 0.4). The S1 orebody, hosted by websterite and gabbronorite in the more fractionated sequence of the ABC, is a cluster of several irregular discontinuous orebodies of Ni–Cu disseminated sulfides. The sulfides of the S1 orebody have high Cu/Cu + Ni ratios (mainly between 0.5 and 0.8) and are highly depleted in PGE. The S1 orebody is interpreted to result from a later event of sulfide segregation in the magma chamber, possibly following the event that originated the G2 orebody. The bulk of δ³⁴S values for sulfides of the ABC orebodies and their host rocks fall in the range of 0 ± 2‰. Higher δ³⁴S values (between 3‰ and 5‰) are restricted to pyrite from xenoliths of gneiss located close to the S1 orebody and sulfides from the S1 orebody. Crustal xenoliths and chemical data (lithogeochemistry and sulfur isotope composition) provide evidence of crustal contamination of the igneous rocks hosting the S1 orebody, suggesting that sulfur saturation was induced by contamination with sulfide-bearing crustal rocks. The ABC deposit is an example of Ni–Cu sulfide mineralization hosted by synorogenic mafic–ultramafic intrusions. The S2 orebody is the first documented example of an economic stratiform massive sulfide orebody located within layered intrusions, expanding the opportunities for exploration of Ni–Cu sulfides in orogenic regions worldwide.     

Anthropogenic heat in the city of S?o Paulo, Brazil

The main goal of this work is to describe the anthropogenic energy flux (Q _F) in the city of S?o Paulo, Brazil. The hourly, monthly, and annual values of the anthropogenic energy flux are estimated using the inventory method, and the contributions of vehicular, stationary, and human metabolism sources from 2004 to 2007 are considered. The vehicular and stationary sources are evaluated using the primary consumption of energy based on fossil fuel, bio fuel, and electricity usage by the population. The diurnal evolution of the anthropogenic energy flux shows three relative maxima, with the largest maxima occurring early in the morning (??19.9 Wm^?2) and in the late afternoon (??20.3 Wm^?2). The relative maximum that occurs around noontime (??19.6 Wm^?2) reflects the diurnal pattern of vehicle traffic that seems to be specific to S?o Paulo. With respect to diurnal evolution, the energy flux released by vehicular sources (Q _FV) contributes approximately 50% of the total anthropogenic energy flux. Stationary sources (Q _FS) and human metabolism (Q _FM) represent about 41% and 9% of the anthropogenic energy flux, respectively. For 2007, the monthly values of Q _FV, Q _FS, Q _FM, and Q _F are, respectively, 16.8?±?0.25, 14.3?±?0.16, 3.5?±?0.03, and 34.6?±?0.41?MJ?m^?2?month^?1. The seasonal evolution monthly values of Q _FV, Q _FS, Q _FM, and Q _F show a relative minimum during the summer and winter vacations and a systematic and progressive increase associated with the seasonal evolution of the economic activity in S?o Paulo. The annual evolution of Q _F indicates that the city of S?o Paulo released 355.2?MJ?m^?2?year^?1 in 2004 and 415.5?MJ?m^?2?year^?1 in 2007 in association with an annual rate of increase of 19.6?MJ?m^?2?year^?1 (from 2004 to 2006) and 30.5?MJ?m^?2?year^?1 (from 2006 to 2007). The anthropogenic energy flux corresponds to about 9% of the net radiation at the surface in the summer and 15% in the winter. The amplitude of seasonal variation of the maximum hourly value of the diurnal variation increases exponentially with latitude.     

Teleconnections in a warmer climate: the pliocene perspective

Migrations toward altered sea surface temperature (SST) patterns in the Indo-Pacific region are present in the recent observational record and in future global warming projections. These SSTs are in the form of ??permanent?? El Ni?o-like (herein termed ??El Padre??) and Indian Ocean Dipole (IOD)-like patterns. The Early Pliocene Warm Period, which bears similarity to future warming projections, may have also exhibited these Indo-Pacific SST patterns, as suggested by regional terrestrial paleo-climatic data and general circulation model studies. The ability to corroborate this assessment with paleo-data reconstructions is an advantage of the warm Pliocene period that is not afforded by future warming scenarios. Thus, the Pliocene period provides us with a warm-climate perspective and test bed for understanding potential changes to future atmospheric interactions given these altered SST states. This study specifically assesses how atmospheric teleconnections from El Padre/IOD SST patterns are generated and propagate to create the regional climate signals of the Pliocene period, as these signals may be representative of future regional climatic changes as well. To do this, we construct a holistic diagnostic rubric that allows us to examine atmospheric teleconnections, both energetically and dynamically, as produced by a general circulation model. We incorporate KE??, a diagnostic adapted from the eddy kinetic energy generation field, to assess the available energy transferred to these teleconnections. Using this methodology, we found that relative to our Modern Control experiments, weaker atmospheric teleconnections prevail under warm Pliocene conditions, although pathways of propagation still appear directed toward the southwestern United States from our tropical Pacific sector forcing. Propagation directly emanating from the Indian Ocean forcing sector appears to be largely blocked, although indirect teleconnective pathways appear traversing the Asian continent toward the North Pacific. The changes in the atmospheric circulation of Indian Ocean region in response to the underlying specified SST forcing (and indicated by Pliocene paleo-data) may have a host of implications for energy transfer out of and into the region, including interactions with the Asian jet stream and changes to the seasonal monsoon cycle. These interactions warrant further study in both past and future warm climate scenarios.     

Traffic-related immissions and their impact on historic buildings: implications from a pilot study at two German cities

Besides the enormous improvement of air quality in Germany due to the reduction of sulphur dioxide emissions in the last decades, high immissions of nitrogen oxides and fine particulate matter are frequently observed at traffic-rich urban sites. The changed chemical composition of air pollution requires a new investigation of its impact on historic buildings constructed of natural stone. In a pilot study a multi-disciplinary approach was chosen to obtain information on the actual pollution situation of historic buildings and monuments at traffic hotspots in Germany. The study concentrated on the two German cities of Munich and Mainz of different size, traffic volume and stone inventory. Dose–response functions were calculated to demonstrate the change of impact of different pollutants over the last three decades, and for comparison of traffic hotspots and housing areas of both cities. Numeric modelling on a city-scale was used to identify the historic buildings and monuments affected by elevated traffic immissions. Because a relevant part of these pollutants is dominated by short-range transport, the differences of wind speed and deposition rates were calculated using a street-scale 3D flow and dispersion model regarding traffic volume, wind regime and adjacent buildings. Finally, particulate matter was sampled at different positions of two buildings heavily exposed to traffic emissions. Individual particles were investigated by environmental scanning electron microscopy. After classification of the particles into different chemical groups, the fraction of traffic-induced particulate matter was quantified. Summarizing the results, it must be stated that soiling by traffic-related particulate matter, deposition of nitrates deriving from exhaust emission and other diffusely emitted components bear a severe damage potential for natural building stone at least locally at traffic-rich urban sites.     

Carbonate diagenesis and feldspar alteration in fracture-related bleaching zones (Buntsandstein,central Germany): possible link to CO<Subscript>2</Subscript>-influenced fluid–mineral reactions

Fracture-related bleaching of Lower Triassic Buntsandstein red beds of central Germany was related to significant carbonate diagenesis and feldspar alteration caused by CO₂-rich fluids. Using cathodoluminescence microscopy and spectroscopy combined with electron microprobe analysis and stable carbon isotope study, two major fluid–mineral interactions were detected: (1) zoned, joint-filling calcites and zoned pore-filling calcite cements, the latter replacing an earlier dolomite, were formed during bleaching. During the calcite formation and dolomite–calcite transformation, iron was incorporated into the calcite cement crystal cores due to Fe availability from the coeval bleaching. The dedolomitisation was ultimately associated with a volume increase. The related permeability decrease implies a certain degree of sealing and increasing retention of CO₂, and the volume increase offers a minor CO₂ sink. Carbonate-rich sandstone, therefore, can provide advantages for underground CO₂ storage especially when situated in the fringes of the reservoir. (2) Alkali-feldspar alteration due to the bleaching fluids is reflected in cathodoluminescence spectra predominantly by the modulation of a brown luminescence emission peak (~620 nm). This peak represents a newly discovered effect related to alkali-feldspar alteration not solely associated with bleaching. Its modulation by the bleaching is interpreted to be due to Na depletion or a lattice defect in the Si–O bonds of the SiO₄-tetrahedron. Alteration reflected by this luminescence feature has a destructive effect on the feldspars implying the possibility of diminished rock integrity due to bleaching and, hence, CO₂-rich fluids. Two further CL spectral changes related to bleaching occur, (a) decreased intensity between around 570 nm assigned to Mn-depletion, and (b) increased amplitude and wavelength shift of the red (~680 nm) band. Converging evidence from carbonate and feldspar diagenesis, stable carbon isotope data and analysis of fracture directions suggests that CO₂ fluids contributed to a significant extent to the bleaching phenomena and alteration in the studied Buntsandstein strata.     

Generation of multi-resolution maps from run-length-encoded data

Abstract

One motivation for the need of maps to be organized hierarchically in different resolutions is the fact that in most applications low-resolution maps require less heavy computations than maps represented at higher resolutions. Spatial data structures that permit generation of lower levels or resolution in a hierarchical fashion already exist, e.g., quad-trees and resolution pyramids. Many other spatial data structures that are non-hierarchical, and therefore do not permit the generation of resolution hierarchies, also exist. One such structure is the run-length-code (RLC), which has many powerful advantages that make the structure feasible in geographical information systems. In this article an approach to the problem of generating a resolution hierarchy from RLC is described and discussed.     

Reproduction of temporal scaling by a rectangular pulses rainfall model

The presence of scaling statistical properties in temporal rainfall has been well established in many empirical investigations during the latest decade. These properties have more and more come to be regarded as a fundamental feature of the rainfall process. How to best use the scaling properties for applied modelling remains to be assessed, however, particularly in the case of continuous rainfall time‐series. One therefore is forced to use conventional time‐series modelling, e.g. based on point process theory, which does not explicitly take scaling into account. In light of this, there is a need to investigate the degree to which point‐process models are able to ‘unintentionally’ reproduce the empirical scaling properties. In the present study, four 25‐year series of 20‐min rainfall intensities observed in Arno River basin, Italy, were investigated. A Neyman–Scott rectangular pulses (NSRP) model was fitted to these series, so enabling the generation of synthetic time‐series suitable for investigation. A multifractal scaling behaviour was found to characterize the raw data within a range of time‐scales between approximately 20 min and 1 week. The main features of this behaviour were surprisingly well reproduced in the simulated data, although some differences were observed, particularly at small scales below the typical duration of a rain cell. This suggests the possibility of a combined use of the NSRP model and a scaling approach, in order to extend the NSRP range of applicability for simulation purposes. Copyright © 2002 John Wiley & Sons, Ltd.     

Uncertainty quantification in numerical simulation of particle-laden flows

Numerical models can help to push forward the knowledge about complex dynamic physical systems. Modern approaches employ detailed mathematical models, taking into consideration inherent uncertainties on input parameters (phenomenological parameters or boundary and initial conditions, among others). Particle-laden flows are complex physical systems found in nature, generated due to the (possible small) spatial variation on the fluid density promoted by the carried particles. They are one of the main mechanisms responsible for the deposition of sediments on the seabed. A detailed understanding of particle-laden flows, often referred to as turbidity currents, helps geologists to understand the mechanisms that give rise to reservoirs, strategic in oil exploration. Uncertainty quantification (UQ) provides a rational framework to assist in this task, by combining sophisticated computational models with a probabilistic perspective in order to deepen the knowledge about the physics of the problem and to access the reliability of the results obtained with numerical simulations. This work presents a stochastic analysis of sediment deposition resulting from a turbidity current considering uncertainties on the initial sediment concentrations and particles settling velocities. The statistical moments of the deposition mapping, like other important features of the currents, are approximated by a Sparse Grid Stochastic Collocation method that employ a parallel flow solver for the solution of the deterministic problems associated to the grid points. The whole procedure is supported and steered by a scientific workflow management engine designed for high performance computer applications.