Influence of Temporal Variations in River Discharge, pH, Alkalinity and Ca on the Speciation and Concentration of Heavy Metals in Some Mining Polluted Rivers

Dissolved (dialysis in situ) and total concentrations ofCu, Zn, Cd and Al in eight mining polluted rivers in the Røros area, central Norway, were determinedby atomic absorption spectrometry (flame and graphite furnace) and compared to pH, Caconcentration and alkalinity through seasonal variations in river discharge. Totalconcentrations of the metals were highest during early spring flood and during summer andautumn rain episodes. Dissolved concentrations also increased as the spring floodproceeded, but small discharge peaks within this 2 month period as well as a considerableautumn flood episode appeared to lower rather than to raise the dissolved metal concentrations.Consequently the dissolved fractions of Zn, Cd and Al showed a significant negative correlationwith river discharge, and were low at the discharge peaks. Possibly high sediment concentrationsoccurring at high flood conditions more than counteracted desorption induced by pHdecrease, and led to decreased dissolved fractions through adsorption. Cu speciationon the other hand seemed to be more closely linked to pH. Alkalinity and Ca concentration,both assumed to protect aquatic life from metal pollution, were significantly lowerduring episodes with high Cu and Al total concentrations.     

An integrated approach to investigate saline water intrusion and to identify the salinity sources in the Central Godavari delta, Andhra Pradesh, India

The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO ₄ ^?2 /Cl^?and Na⁺²/Cl^?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.     

Large-scale vertical hydroacoustic structure of the North Atlantic and its seasonal variability

A classification based on the number and types of large-scale acoustic waveguides is proposed for the mean seasonal profiles of sound speed propagation. A scheme for North Atlantic zoning, using typical curves of the sound speed vertical distribution, is given. The channel axis's position is shown not to depend on the water mass haline properties, being controlled by the temperature field vertical stratification.Translated by Vladimir A. Puchkin.     

Site response studies in Agartala Urban agglomeration

A systematic investigation using digital microearthquake recorders with short period SS-1 seismometers, covering 76 sites in and around Agartala city, has been carried out for site response (SR) studies in the area. In the northern part of the area, SR varies from 1.15 to 1.85 corresponding to peak frequency 0.76 to 0.93 Hz where soil is mostly semi-consolidated and stiffer than recent Quaternary deposits (Haora River formation). In the southern part of the area, SR varies from 1.12 to 2.42 corresponding to peak frequency from 0.71 to 0.85 Hz within the Dupitila formation (early Quaternary). It is observed that estimated SR from H/V increases from edges to middle of the Haora River valley and impedance contrast fallows the similar trend. This reflects that site response by H/V is influenced by impedance contrast, whereas computed amplification from 1-D model shows opposite trend. The maximum amplification at fundamental frequency of resonance, 1.04 Hz estimated from H/V by near to BH-7, is 2.5 times greater than the impedance contrast/ratio derived from 1-D model for same location. Relationship between resonance frequency and depth was obtained by applying quarter wavelength and Bard (2000) methodologies, which shows linearity, whereas H/V shows its nonlinearity characteristic in soil across the valley part of Haora River. Shear wave velocities, and subsequently, SPT index and factor of safety (by cyclic stress approach) were estimated from geotechnical parameters. Vs30 and site response data were used in this study for getting a first hand information about soil stiffness condition in the area. The estimation of SPT index and factor of safety could be a useful tool for delineating liquefied and none liquefied zones at various depth levels, especially where water table exists at a very shallow level. The expected liquefiable zone was observed at depths varying from 6–25 m beneath the soil bearing zones where percentage of fines is estimated to be more than 35% for the area. This knowledge about subsurface soil characteristics will be useful for the civil engineers/city planners, which can be taken into account at the time of constructing earthquake-resistant structures in the area.     

Persisting challenges for performance-based building assessment

Intense research and refinement of the tools used in performance-based seismic engineering have been made, but the maturity and accuracy of these methods have not been adequately confirmed with actual data from the field. The gap between the assumed characteristics of actual building systems and their idealized counterparts used for analysis is wide. When the randomly distributed flaws in buildings as they exist in urban areas and the extreme variability of ground motion patterns combine, the conventional procedures used for pushover or dynamic response history analyses seem to fall short of reconciling the differences between calculated and observed damage. For emergency planning and loss modeling purposes, such discrepancies are factors that must be borne in mind. Two relevant examples are provided herein. These examples demonstrate that consensus-based analytical guidelines also require well-idealized building models that do not lend themselves to reasonably manageable representations from field data. As a corollary, loss modeling techniques, e.g., used for insurance purposes, must undergo further development and improvement.     

Evaluation of stratospheric ozone,temperature, and aerosol profiles from the LOANA lidar in Antarctica

We present an evaluation of observations from the Lidar Ozone and Aerosol for NDACC in Antarctica (LOANA) at the Dumont d’Urville station, Antarctica. This instrument is part of the Network for the Detection of Atmospheric Composition Change (NDACC), and ensures continuity with lidar measurements made since 1989 with the previous instrument at this site. This study is based on the dataset from 2008 to 2009, and comparisons are made with observations from balloon soundings, and from three satellite experiments: Aura/MLS, TIMED/SABER, and CALIOP/CALIPSO. The lidar ozone data are in very good agreement with the balloon sounding data (ECC sensor), revealing a bias of less than 3% between 17 and 34 km. For temperature, the lidar shows a low bias of ?3 K at 20 km when compared with Aura/MLS. Between 30 and 50 km, the bias is less than 2 K. We also present our initial results showing diurnal variations in temperature. The amplitude of these diurnal cycles is on the order of 1 K and is unlikely to account for the temperature biases between LOANA and the reference instruments. Comparisons of total attenuated backscatter reveal good qualitative agreement between LOANA and CALIOP, with differences of less than 30% in the derived optical depth.     

Current trends of ice coverage changes in the Franz Josef Land Archipelago area

Doklady Earth Sciences - The data on the ice distribution in the Franz Josef Land Archipelago area during the 2010/2011 and 2014/2015 ice seasons depending on climate oscillations are presented...