Racemization of amino acids in marine sediments determined by gas chromatography

Ratios of d- to l-amino acids in acid hydrolysates from foraminifera of two deep-sea cores from the Caribbean Sea and Atlantic Ocean increase with depth and consequently with age over a span from 40,000 to 2,000,000 yr. The changing ratios do not seem to follow first-order reversible rate laws. Valine, leucine and glutamic acid apparently racemize (isoleucine epimerizes) at slower rates than do phenylalanine, alanine, aspartic acid and proline. The general relative order for rates of racemization of total (free and bound) amino acids may depend on the electron-withdrawing capacity of the R substituents of the amino acids and on the rates with which the amino acids are naturally hydrolyzed. In contrast to the total amino acids, the free amino acids in these samples are more extensively racemized, probably as a result of various catalytic and hydrolytic reactions.Previous related work based on ion-exchange chromatography has considered only ratios of alloisoleucine to isoleucine. With the gas chromatographic method used here, d/l ratios of all common asymmetric amino acids can be estimated. Measurement of the extent of racemization of amino acids in marine sediments seems to provide the basis for a geochronological tool covering the last few million years.     

Regional scale nutrient modelling: exports to the Great Barrier Reef World Heritage Area

Clearing of native vegetation and replacement with cropping and grazing systems has increased nutrient exports to the Great Barrier Reef (GBR) to a level many times the natural rate. We present a technique for modelling nutrient transport, based on material budgets of river systems, and use it to identify the patterns and sources of nutrients exported. The outputs of the model can then be used to help prioritise catchment areas and land uses for management and assess various management options. Hillslope erosion is the largest source of particulate nutrients because of its dominance as a sediment source and the higher nutrient concentrations on surface soils. Dissolved nutrient fractions contribute 30% of total nitrogen and 15% of total phosphorus inputs. Spatial patterns show the elevated dissolved inorganic nitrogen export in the wetter catchments, and the dominance of particulate N and P from soil erosion in coastal areas. This study has identified catchments with high levels of contribution to exports and targeting these should be a priority.     

Incompletely compacted equilibrated ordinary chondrites

Abstract— We document the size distributions and locations of voids present within five highly porous equilibrated ordinary chondrites using high‐resolution synchrotron X‐ray microtomography (μCT) and helium pycnometry. We found total porosities ranging from ～10 to 20% within these chondrites, and with μCT we show that up to 64% of the void space is located within intergranular voids within the rock. Given the low (S1‐S2) shock stages of the samples and the large voids between mineral grains, we conclude that these samples experienced unusually low amounts of compaction and shock loading throughout their entire post accretionary history. With Fe metal and FeS metal abundances and grain size distributions, we show that these chondrites formed naturally with greater than average porosities prior to parent body metamorphism. These materials were not “fluffed” on their parent body by impact‐related regolith gardening or events caused by seismic vibrations. Samples of all three chemical types of ordinary chondrites (LL, L, H) are represented in this study and we conclude that incomplete compaction is common within the asteroid belt.     

Variability and predictability of Antarctic krill swarm structure

Swarming is a fundamental part of the life of Euphausia superba, yet we still know very little about what drives the considerable variability in swarm shape, size and biomass. We examined swarms across the Scotia Sea in January and February 2003 using a Simrad EK60 (38 and 120 kHz) echosounder, concurrent with net sampling. The acoustic data were analysed through applying a swarm-identification algorithm and then filtering out all non-krill targets. The area, length, height, depth, packing-concentration and inter-swarm distance of 4525 swarms was derived by this method. Hierarchical clustering revealed 2 principal swarm types, which differed in both their dimensions and packing-concentrations. Type 1 swarms were generally small (<50 m long) and were not very tightly packed (<10 ind. m⁻³), whereas type 2 swarms were an order of magnitude larger and had packing concentrations up to 10 times greater. Further sub-divisions of these types identified small and standard swarms within the type 1 group and large and superswarms within the type 2 group. A minor group (swarm type 3) was also found, containing swarms that were isolated (>100 km away from the next swarm). The distribution of swarm types over the survey grid was examined with respect to a number of potential explanatory variables describing both the environment and the internal-state of krill (namely maturity, body length, body condition). Most variables were spatially averaged over scales of 100 km and so mainly had a mesoscale perspective. The exception was the level of light (photosynthetically active radiation (PAR)) for which measurements were specific to each swarm. A binary logistic model was constructed from four variables found to have significant explanatory power (P<0.05): surface fluorescence, PAR, krill maturity and krill body length. Larger (type 2) swarms were more commonly found during nighttime or when it was overcast during the day, when surface fluorescence was low, and when the krill were small and immature. A strong pattern of diel vertical migration was not observed although the larger and denser swarms tended to occur more often at night than during the day. The vast majority of krill were contained within a minor fraction of the total number of swarms. These krill-rich swarms were more common in areas dominated by small and immature krill. We propose that, at the mesoscale level, the structure of swarms switches from being predominantly large and tightly packed to smaller and more diffuse as krill grow and mature. This pattern is further modulated according to feeding conditions and then level of light.     

Structure of the larvikite-lardalite complex,Oslo-region,Norway, and its evolution

Structures not previously described from the southern part of the Permian rift-system in the Oslo-district, Norway, are presented. These indicate that the larvikite massif is a ring complex consisting of numerous individual sections which are roughly circular and repeatedly cut each other in a manner that suggests sequential shifting of centres of igneous activity towards the west. The compositions of these sections vary from quartzbearing varieties in the earliest parts through intermediate types to larvikite and lardalite with excess nepheline in the youngest parts.As this complex covers almost the total width of the Oslo rift-system, it forms an important profile across the graben structure. It suggests unilateral westward migration of centres of igneous activity in this region, viewed either as magma injection or cauldron subsidence and therefore provides additional information regarding the origin and evolution of the Oslo paleo-rift system.

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Zusammenfassung Die Arbeit behandelt bisher nicht beschriebene Strukturen im südlichen Teil des permischen Bruchsenkungsgebietes im Oslogebiet in Norwegen. Sie zeigen, daß das Larvikit-Massiv einen ringförmigen Komplex bildet aus zahlreichen, ungefähr zirkulären und untereinander diskordanten Teilbereichen. Die Lage der Diskordanzen erlaubt die Annahme, einer westlich gerichteten sukzessiven Verlagerung der Zentren magmatischer Aktivität. Mit abnehmendem Alter dieser Teilbereiche verändert sich deren Mineralbestand von quartzführend über intermediär hin zur larvikitischen und lardalitischen Zusammensetzung mit Nephelinüberschuß.Da dieser Komplex fast den gesamten Bereich des Osloer Bruchsenkungsgebietes deckt, stellt er ein wichtiges Profil durch die Grabenstruktur dar. Dieses läßt plausibel erscheinen, daß die Zentren der magmatischen Vorgänge der Gegend einem einheitlich westgerichteten Trend gefolgt sind gleichviel, ob man in ihnen großräumige Vorgänge ringförmiger Magmen-intrusion sieht oder zylindrische Kesselbrüche (Cauldrons). Die in der Arbeit dargelegten Ergebnisse sind somit geeignet, die Frage des Ursprungs und der Entwicklung des Osloer Bruchsenkungsgebietes weiter zu erhellen.

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Résumé Une nouvelle analyse structurale de massif de larvikite au sud du rift permien d'Oslo, Norvège, montre que ce massif forme un complexe annulaire comprenant de nombreuses composantes à peu pres circulaires et discordantes entre elles. Les segments se recoupent successivement indiquant un déplacement des centres d'activité magmatique vers l'ouest. Les larvikites passent de types à composition acide avec quartz dans les premiers segments, à des types intermédiaires puis a des compositions sousatourée avec néphéline en excess dans les segments les plus jeunes.Comme le massif occupe presque toute la largeur du rift d'Oslo il constitue une coupe importante de cette fosse paléozoique. Sa structure suggère une migration continue vers l'ouest des centres d'activité volcanique pour autant qu'on y voie des intrusions annulaires de magma, ou des effondrements successifs de la caldeira. Ce résultat apporte une information nouvelle sur l'origine et l'évolution du rift permien d'Oslo au sud de la Norvège.

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Using a One-and-a-Half Order Closure Model of the Atmospheric Boundary Layer for Surface Flux Footprint Estimation

A knowledge of the distribution of the contribution of upwind sources to measurements of vertical scalar flux densities is important for the correct interpretation of eddy covariance data. Several approaches have been developed to estimate this so-called footprint function. Here a new approach based on the ensemble-averaged Navier—Stokes equations is presented. Comparisons of numerical results using this approach with results from other studies under a range of environmental conditions show that the model predictions are robust. Moreover, the approach outlined here has the advantage of a potential wide applicability, due to an ability to take into account the heterogeneous nature of underlying surfaces. For example, the model showed that any variations in surface drag, such as must occur in real life heterogeneous canopies, can exert a marked influence of the shape and extent of flux footprints. Indeed, it seems likely that under such circumstances, estimates of surface fluxes will be weighted towards areas of highest foliage density (and therefore quite likely higher photosynthetic rates) close to the measurement sensor. Three-dimensional footprints during the day and night were also determined for a mixed coniferous forest in european Russia. A marked asymmetry of the footprint in the crosswind direction was observed, this being especially pronounced for non-uniform plant distributions involving vegetation types with different morphological and physiological properties. The model also found that, other things being equal, the footprint peak for forest soil respiration is typically over twice the distance from the above canopy measurement sensor compared to that for canopy photosynthesis. This result has important consequences for the interpretation of annual ecosystem carbon balances by the eddy covariance method.     

Small volume andesite magmas and melt–mush interactions at Ruapehu, New Zealand: evidence from melt inclusions

Historical eruptions from Mt. Ruapehu (New Zealand) have been small (<0.001 km³ of juvenile magma) and have often occurred without significant warning. Developing better modelling tools requires an improved understanding of the magma storage and transport system beneath the volcano. Towards that end, we have analysed the volatile content and major element chemistry of groundmass glass and phenocryst-hosted melt inclusions in erupted samples from 1945 to 1996. We find that during this time period, magma has been stored at depths of ~2–9 km, consistent with inferences from geophysical data. Our data also show that Ruapehu magmas are relatively H₂O-poor (<2 wt%) and CO₂-rich (≤1,000 ppm) compared to typical arc andesites. Surprisingly, we find that melt inclusions are often more evolved than their transporting melt (as inferred from groundmass glass compositions). Furthermore, even eruptions that are separated by less than 2 years exhibit distinct major element chemistry, which suggests that each eruption involved magma with a unique ascent history. From these data, we infer that individual melt batches rise through, and interact with, crystal mush zones formed by antecedent magmas. From this perspective, we envision the magmatic system at Ruapehu as frequently recharged by small magma inputs that, in turn, cool and crystallise to varying degrees. Melts that are able to erupt through this network of crystal mush entrain (to a greater or lesser extent) exotic crystals. In the extreme case (such as the 1996 eruption), the resulting scoria contain melt inclusion-bearing crystals that are exotic to the transporting magma. Finally, we suggest that complex interactions between recharge and antecedent magmas are probably common, but that the small volumes and short time scales of recharge at Ruapehu provide a unique window into these processes.     

Evolution of granitoids in the Catalina metamorphic core complex, southeastern Arizona: U–Pb, Nd, and Hf isotopic constraints

The Santa Catalina Mountains, SE Arizona, was one of the first metamorphic core complexes to be described. Despite its status as a type example, relatively little is known about precise ages and origins of the intrusive rocks that make up most of the crystalline core. U–Pb and Hf isotopic data by laser ablation–inductively coupled plasma–mass spectrometry from zircons and Nd isotopic results from whole rocks were obtained for 12 granitoids ranging from 1,440 to 26 Ma. Results confirm that the 1.44-Ga Oracle Granite extends through the Catalina Range as variably mylonitic granite and banded gneiss. Laramide intrusions (67–73 Ma) display initial ε_Nd values ?5 to ?8 and ε_Hf from ?7.5 to ?9. Magmatic ages for the prominent white granite sills of the Wilderness suite are 46–57 Ma, in agreement with Terrien (2012), and these granites have initial ε_Nd values ?8 to ?10 and ε_Hf from ?7 to ?14. Lastly, the undeformed Catalina Granite has an age of 26 Ma, with an initial ε_Nd and ε_Hf of ?6 and ?8, respectively. Our Nd results agree with limited results from Farmer and DePaolo (89:10141–10160, 1984). Although the Catalina Granite seems to have a significant juvenile component based on Nd and Hf, most of the Laramide and Wilderness intrusions contain Nd and Hf compositions lying close to the evolution of 1.44-Ga Oracle Granites, a fact that is confirmed by the U–Pb data, which show both 1.7- and 1.4-Ga zircon cores in these samples, with 1.4 Ga as the dominant core age. In order to become the dominant source of most of the 72–45-Ma magmas, the Oracle pluton must not only extend across the whole Catalina region, but also have abundant deep-seated equivalents to provide magma sources.     

Climate change,migration and adaptation in Funafuti,Tuvalu

This paper shows the extent to which people in Funafuti – the main island of Tuvalu – are intending to migrate in response to climate change. It presents evidence collected from Funafuti to challenge the widely held assumption that climate change is, will, or should result in large-scale migration from Tuvalu. It shows that for most people climate change is not a reason for concern, let alone a reason to migrate, and that would-be migrants do not cite climate change as a reason to leave. People in Funafuti wish to remain living in Funafuti for reasons of lifestyle, culture and identity. Concerns about the impacts of climate change are not currently a significant driver of migration from Funafuti, and do not appear to be a significant influence on those who intend to migrate in the future.