The role of precursory structures on Tertiary deformation in the Black Forest—Hegau region

International Journal of Earth Sciences - Structural inheritance of preexisting crustal discontinuities is widely accepted to have played a crucial role during the Cenozoic tectonic evolution of...     

Using a One-and-a-Half Order Closure Model of the Atmospheric Boundary Layer for Surface Flux Footprint Estimation

A knowledge of the distribution of the contribution of upwind sources to measurements of vertical scalar flux densities is important for the correct interpretation of eddy covariance data. Several approaches have been developed to estimate this so-called footprint function. Here a new approach based on the ensemble-averaged Navier—Stokes equations is presented. Comparisons of numerical results using this approach with results from other studies under a range of environmental conditions show that the model predictions are robust. Moreover, the approach outlined here has the advantage of a potential wide applicability, due to an ability to take into account the heterogeneous nature of underlying surfaces. For example, the model showed that any variations in surface drag, such as must occur in real life heterogeneous canopies, can exert a marked influence of the shape and extent of flux footprints. Indeed, it seems likely that under such circumstances, estimates of surface fluxes will be weighted towards areas of highest foliage density (and therefore quite likely higher photosynthetic rates) close to the measurement sensor. Three-dimensional footprints during the day and night were also determined for a mixed coniferous forest in european Russia. A marked asymmetry of the footprint in the crosswind direction was observed, this being especially pronounced for non-uniform plant distributions involving vegetation types with different morphological and physiological properties. The model also found that, other things being equal, the footprint peak for forest soil respiration is typically over twice the distance from the above canopy measurement sensor compared to that for canopy photosynthesis. This result has important consequences for the interpretation of annual ecosystem carbon balances by the eddy covariance method.     

Projected hydroclimate changes over Andean basins in central Chile from downscaled CMIP5 models under the low and high emission scenarios

This study examines the projections of hydroclimatic regimes and extremes over Andean basins in central Chile (～ 30–40° S) under a low and high emission scenarios (RCP2.6 and RCP8.5, respectively). A gridded daily precipitation and temperature dataset based on observations is used to drive and validate the VIC macro-scale hydrological model in the region of interest. Historical and future simulations from 19 climate models participating in CMIP5 have been adjusted with the observational dataset and then used to make hydrological projections. By the end of the century, there is a large difference between the scenarios, with projected warming of ～ + 1.2 °C (RCP2.6), ～ +?3.5 °C (RCP8.5) and drying of ～ ? 3% (RCP2.6), ～ ? 30% (RCP8.5). Following the strong drying and warming projected in this region under the RCP8.5 scenario, the VIC model simulates decreases in annual runoff of about 40% by the end of the century. Such strong regional effect of climate change may have large implications for the water resources of this region. Even under the low emission scenario, the Andes snowpack is projected to decrease by 35–45% by mid-century. In more snowmelt-dominated areas, the projected hydrological changes under RCP8.5 go together with more loss in the snowpack (75–85%) and a temporal shift in the center timing of runoff to earlier dates (up to 5 weeks by the end of the century). The severity and frequency of extreme hydroclimatic events are also projected to increase in the future. The occurrence of extended droughts, such as the recently experienced mega-drought (2010–2015), increases from one to up to five events per 100 years under RCP8.5. Concurrently, probability density function of 3-day peak runoff indicates an increase in the frequency of flood events. The estimated return periods of 3-day peak runoff events depict more drastic changes and increase in the flood risk as higher recurrence intervals are considered by mid-century under RCP2.6 and RCP8.5, and by the end of the century under RCP8.5.     

Changes in lead and zinc lability during weathering-induced acidification of desert mine tailings: Coupling chemical and micro-scale analyses

Desert mine tailings may accumulate toxic metals in the near surface centimeters because of low water through-flux rates. Along with other constraints, metal toxicity precludes natural plant colonization even over decadal time scales. Since unconsolidated particles can be subjected to transport by wind and water erosion, potentially resulting in direct human and ecosystem exposure, there is a need to know how the lability and form of metals change in the tailings weathering environment. A combination of chemical extractions, X-ray diffraction, micro-X-ray fluorescence spectroscopy, and micro-Raman spectroscopy were employed to study Pb and Zn contamination in surficial arid mine tailings from the Arizona Klondyke State Superfund Site. Initial site characterization indicated a wide range in pH (2.5–8.0) in the surficial tailings pile. Ligand-promoted (DTPA) extractions, used to assess plant-available metal pools, showed decreasing available Zn and Mn with progressive tailings acidification. Aluminum shows the inverse trend, and Pb and Fe show more complex pH dependence. Since the tailings derive from a common source and parent mineralogy, it is presumed that variations in pH and “bio-available” metal concentrations result from associated variation in particle–scale geochemistry. Four sub-samples, ranging in pH from 2.6 to 5.4, were subjected to further characterization to elucidate micro-scale controls on metal mobility. With acidification, total Pb (ranging from 5 to 13 g kg⁻¹) was increasingly associated with Fe and S in plumbojarosite aggregates. For Zn, both total (0.4–6 g kg⁻¹) and labile fractions decreased with decreasing pH. Zinc was found to be primarily associated with the secondary Mn phases manjiroite and chalcophanite. The results suggest that progressive tailings acidification diminishes the overall lability of the total Pb and Zn pools.     

Comparison of stress-dependent geophysical,hydraulic and mechanical properties of synthetic and natural sandstones for reservoir characterization and monitoring studies

Synthetic rock samples can offer advantages over natural rock samples when used for laboratory rock physical properties studies, provided their success as natural analogues is well understood. The ability of synthetic rocks to mimic the natural stress dependency of elastic wave, electrical and fluid transport properties is of primary interest. Hence, we compare a consistent set of laboratory multi-physics measurements obtained on four quartz sandstone samples (porosity range 20–25%) comprising two synthetic and two natural (Berea and Corvio) samples, the latter used extensively as standards in rock physics research. We measured simultaneously ultrasonic (P- and S-wave) velocity and attenuation, electrical resistivity, permeability and axial and radial strains over a wide range of differential pressure (confining stress 15–50 MPa; pore pressure 5–10 MPa) on the four brine saturated samples. Despite some obvious physical discrepancies caused by the synthetic manufacturing process, such as silica cementation and anisotropy, the results show only small differences in stress dependency between the synthetic and natural sandstones for all measured parameters. Stress dependency analysis of the dry samples using an isotropic effective medium model of spheroidal pores and penny-shaped cracks, together with a granular cohesion model, provide evidence of crack closure mechanisms in the natural sandstones, seen to a much lesser extent in the synthetic sandstones. The smaller grain size, greater cement content, and cementation under oedometric conditions particularly affect the fluid transport properties of the synthetic sandstones, resulting in lower permeability and higher electrical resistivity for a similar porosity. The effective stress coefficients, determined for each parameter, are in agreement with data reported in the literature. Our results for the particular synthetic materials that were tested suggest that synthetic sandstones can serve as good proxies for natural sandstones for studies of elastic and mechanical properties, but should be used with care for transport properties studies.     

Local and regional constraints on relative sea-level changes in southern Isle of Skye,Scotland, since the Last Glacial Maximum

New relative sea-level (RSL) data constrain the timing and magnitude of RSL changes in the southern Isle of Skye following the Last Glacial Maximum (LGM). We identify a marine limit at ~23 m OD, indicating RSL ~20 m above present c. 15.1 ka. Isolation basin data, supported by terrestrial and marine limiting dates, record an RSL fall to 11.59 m above present by c. 14.2 ka. This RSL fall occurs across the time of global Meltwater Pulse 1A, supporting recent research on the sources of ice melting. Our new data also help to resolve some of the chronological issues within the existing Isle of Skye RSL record and provide details of the sub-Arctic marine environment associated with the transition into Devensian Lateglacial climate at c. 14.5 k cal a bp , and the timing of changes in response to the Loch Lomond Stadial climate. Glacio-isostatic adjustment (GIA) model predictions of RSL deviate from the RSL constraints and reflect uncertainties in local and global ice models used within the GIA models. An empirical RSL curve provides a target for future research.