“Lessons for marine conservation planning: A comparison of three marine protected area planning processes”

Various approaches have been used to establish marine protected areas (MPAs) in different countries. In this paper we compare and review three processes to establish MPAs within the United States and Australia. These two countries share many similarities in their cultures, but their approaches to managing marine resources differ considerably. Each of these efforts to establish or review MPAs was motivated by concern about declines of targeted marine species or habitats. However, the government actions varied because of differences in governance, planning process including public input, and the role of science. Comparing these processes highlights effective approaches for protecting marine ecosystems and gaining public support.     

Isotopic and trace-element profiles across the New Britain island arc,Papua New Guinea

New Pb-, Sr-, and Nd-isotopic data have been obtained for the rocks of volcanoes overlying a wide range of depths (100–580 km) to the Wadati-Benioff Zone (WBZ) in the New Britain island arc, Papua New Guinea. Well-defined trends consistent with two-component mixing are observed in combined Pb-isotope/trace-element plots. One of the components is believed to represent a slab contribution whose isotopic signature, unlike those noted for several other arcs, appears to be dominated by subducted, altered, oceanic crust rather than by sediment. This conclusion is consistent with the results of a recent Be–B study of New Britain rocks. The influence of the slab component is considered to decrease as depth to the WBZ increases. Higher abundances of high-field-strength elements correlate with increasing depths to the WBZ, and may be indicative of smaller degrees of partial melting of the mantle wedge as WBZ depths increase. Abundances of other incompatible elements appear to reflect a complex interplay between the slab-derived flux and melting process.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.     

OCCURRENCE OF VOLATILE ORGANIC CHEMICALS IN NEBRASKA GROUND WATER

Abstract. This report summarizes results of monitoring programs for volatile synthetic organic chemicals (VOCs) in Nebraska's private and public water-supply wells conducted by two State agencies. Of 97 community water-supply systems sampled as of June 1984, 16.5 percent (16 systems) showed quantifiable levels of at least one VOC. Detectable amounts of one or more VOCs were measured in samples from 15.9 percent (10) of 63 private wells sampled in 1982. These percentages are consistent with results of other State and national surveys.     

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.     

Organochlorine residues in whales landed at Durban,South Africa

The levels of DDT and its metabolites found in the blubber of 29 minke, 6 fin and 1 sei whale landed at the Durban whaling station in 1974 were on average much lower than those found in baleen whales from the North Atlantic, but of the same order as those measured from the Antarctic and North Pacific. In 12 sperm whales examined at Durban the levels of DDT and its metabolites in the blubber were substantially lower than in any other locality so far examined, including the Antarctic, but this may partly reflect the comparative youth of the animals sampled. Low levels of Dieldrin were found in some minke whales only. No PCB could be detected in any of the whales examined.     

Progress in Carrier Phase Time Transfer

The progress of the joint Pilot Project for time transfer, formed by the International GPS Service (IGS) and the Bureal International des Poids et Mesures (BIPM), was recently reviewed. Three notable milestones were set. (1) The IGS will implement, at least in a test mode, an internally realized time scale based on an integration of combined frequency standards within the IGS network. This will eventually become the reference time scale for all IGS clock products (instead of the current GPS broadcast time). (2) A new procedure for combined receiver and satellite clock products will be implemented officially in November 2000. Receiver clocks are an entirely new product of the IGS. (3) The BIPM will coordinate an effort to calibrate all Ashtech Z12-T (and possibly other) receivers suitable for time transfer applications, either differentially or absolutely. Progress reports will be presented publicly in the spring 2001. ? 2001 John Wiley & Sons, Inc.     

The volcanic and magmatic evolution of Volcán Ollagüe, a high-K, late quaternary stratovolcano in the Andean Central Volcanic Zone

Volcán Ollagüe is a high-K, calc-alkaline composite volcano constructed upon extremely thick crust in the Andean Central Volcanic Zone. Volcanic activity commenced with the construction of an andesitic to dacitic composite cone composed of numerous lava flows and pyroclastic deposits of the Vinta Loma series and an overlying coalescing dome and coulée sequence of the Chasca Orkho series. Following cone construction, the upper western flank of Ollagüe collapsed toward the west leaving a collapse-amphitheater about 3.5 km in diameter and a debris avalanche deposit on the lower western flank of the volcano. The deposit is similar to the debris avalanche deposit produced during the May 18, 1980 eruption of Mount St. Helens, U.S.A., and was probably formed in a similar manner. It presently covers an area of 100 km² and extends 16 km from the summit. Subsequent to the collapse event, the upper western flank was reformed via eruption of several small andesitic lava flows from vents located near the western summit and growth of an andesitic dome within the collapse-amphitheater. Additional post-collapse activity included construction of a dacitic dome and coulée of the La Celosa series on the northwest flank. Field relations indicate that vents for the Vinta Loma and post-collapse series were located at or near the summit of the cone. The Vinta Loma series is characterized by an anhydrous, two-pyroxene assemblage. Vents for the La Celosa and Chasca Orkho series are located on the flanks and strike N55 W, radial to the volcano. The pattern of flank eruptions coincides with the distribution in the abundance of amphibole and biotite as the main mafic phenocryst phases in the rocks. A possible explanation for this coincidence is that an unexposed fracture or fault beneath the volcano served as a conduit for both magma ascent and groundwater circulation. In addition to the lava flows at Ollagüe, magmas are also present as blobs of vesiculated basaltic andesite and mafic andesite that occur as inclusions in nearly all of the lavas. All eruptive activity at Ollagüe predates the last glacial episode ( 11.000 a B.P.), because post-collapse lava flows are overlain by moraine and are incised by glacial valleys. Present activity is restricted to emission of a persistent, 100-m-high fumarolic steam plume from a vent located within the summit andesite dome.Sr and Nd isotope ratios for the basaltic andesite and mafic andesite inclusions and lavas suggest that they have assimilated large amounts of crust during crystal fractionation. In contrast, narrow ranges in ¹⁴³Nd/¹⁴⁴Nd and ⁸⁷Sr/⁸⁶Sr in the andesitic and dacitic lavas are enigmatic with respect to crustal contamination.