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531.
Antarctic meteorite LAP 031047 is an ordinary chondrite composed of loosely consolidated chondritic fragments. Its petrography, oxygen isotopic composition and geochemical inventory are ambiguous and indicate an intermediate character between H and L chondrites. Petrographic indicators suggest LAP 031047 suffered a shock metamorphic overprint below ∼10 GPa, which did not destroy its unusually high porosity of ∼27 vol%. Metallographic textures in LAP 031047 indicate heating above ∼700 °C and subsequent cooling, which caused massive transformation of taenite to kamacite. The depletion of thermally labile trace elements, the crystallization of chondritic glass to microcrystalline plagioclase of unusual composition, and the occurrence of coarsely crystallized chondrule fragments is further evidence for post-metamorphic heating to ∼700-750 °C. However, this heating event had a transient character because olivine and low-Ca pyroxene did not equilibrate. Nearly complete degassing up to very high temperatures is indicated by the thorough resetting of LAP 031047’s Ar-Ar reservoir ∼100 ± 55 Ma ago. A noble gas cosmic-ray exposure age indicates it was reduced to a meter-size fragment at <0.5 Ma. In light of the fact that shock heating cannot account for the thermal history of LAP 031047 in its entirety, we test the hypothesis that this meteorite belonged to the near-surface of an Aten or Apollo asteroid that underwent heating during orbital passages close to the Sun.  相似文献   
532.
533.
We introduce a novel scheme that enables natural silicic glasses to be projected into the synthetic system Qz-Ab-Or-H2O in order to relate variations in volcanic glass chemistry to changing pressure (P) and temperature (T) conditions in the sub-volcanic magma system. By this means an important distinction can be made between ascent-driven and cooling-driven crystallisation under water-saturated or undersaturated conditions. In samples containing feldspar and a silica phase (quartz or tridymite), quantitative P-T estimates of the conditions of last equilibrium between crystals and melt can be made. Formation of highly silicic melts (i.e. >77 wt% SiO2) is a simple consequence of the contraction of the silica phase volume with decreasing pressure, such that high silica glasses can only form by crystallisation at low pressure. Resorption of quartz crystals appears to be a further diagnostic feature of decompression crystallisation. Groundmass and inclusion glasses in dacites from the 1980-1986 eruption of Mount St Helens volcano (WA) span a wide range in SiO2 (68-80 wt%, anhydrous). The compositions of the least evolved (SiO2-poor) inclusions in amphibole phenocrysts record entrapment of silicic liquids with Е.4 wt% water, corresponding to a water saturation pressure of ~200 MPa at 900 °C. The compositions of more evolved (higher SiO2) plagioclase-hosted inclusions and groundmass glasses are consistent with extensive ascent-driven fractional crystallisation of plagioclase, oxide and orthopyroxene phenocrysts and microlites to low pressures. During this polybaric crystallisation, plagioclase phenocrysts trapped melts with a wide range of dissolved water contents (3.5-5.7 wt%). Magmas erupted during the Plinian phase of the 18 May 1980 eruption were derived from a large reservoir at depths of ̈́ km. Subsequent magmas ascended to varying depths within the sub-volcanic system prior to extraction. From glass chemistry and groundmass texture two arrest levels have been identified, at depths of 0.5-1 and 2-4 km. A single dome sample from February 1983 contains groundmass plagioclase, tridymite and quartz, testifying to temperatures of at least 885 °C at 11 MPa. These shallow storage conditions are comparable to those in the cryptodome formed during spring 1980. The corresponding thermal gradient, А.2 °C MPa-1, is consistent with near-adiabatic magma ascent from ~8 km. We argue that the crystallisation history of Mount St Helens dacite magma was largely a consequence of decompression crystallisation of hot magma beyond the point of water saturation. This challenges the conventional view that phenocryst crystallisation occurred by cooling in a large magma chamber prior to the 1980-1986 eruption. Because the crystallisation process is both polybaric and fractional, it cannot be simulated directly using isobaric equilibrium crystallisation experiments. However, calculation of the phase proportions in water-saturated 910ᆣ °C experiments by Rutherford et al. (1985) over the pressure range 220-125 MPa reproduces the crystallisation sequence and phenocryst modes of Mount St Helens dacites from 18 May 1980. By allowing for the effects of fractional versus equilibrium crystallisation, entrained residual source material, and small temperature differences between nature and experiment, phase compositions can also be matched to the natural samples. We conclude that decompression of water-saturated magma may be the dominant driving force for crystallisation at many other silicic volcanic centres.  相似文献   
534.
This paper tracks changes in relative centralisation and relative concentration of poverty for the 25 largest British cities, analysing change for poor and non-poor groups separately, and examining parallel changes in spatial segregation. The paper confirms that poverty is suburbanising, at least in the larger cities, although poverty remains over-represented in inner locations. Suburbanisation is occurring through both the reduction in low income populations in inner locations and the growth non-poor groups in these places, consistent with a process of displacement. Relative centralisation of poverty has fallen more stronglythan relative concentration of poverty, as the outward shift of poorer groups leaves them still living in denser neighbourhoods on average. The paper also shows that spatial segregation (unevenness) declined at the same time although it remains to be seen whether this indicates a long-term shift to less segregated urban forms or a transitional outcome before new forms of segregation emerge around suburban poverty concentrations.  相似文献   
535.
This study examines the projections of hydroclimatic regimes and extremes over Andean basins in central Chile (~ 30–40° S) under a low and high emission scenarios (RCP2.6 and RCP8.5, respectively). A gridded daily precipitation and temperature dataset based on observations is used to drive and validate the VIC macro-scale hydrological model in the region of interest. Historical and future simulations from 19 climate models participating in CMIP5 have been adjusted with the observational dataset and then used to make hydrological projections. By the end of the century, there is a large difference between the scenarios, with projected warming of ~ + 1.2 °C (RCP2.6), ~ +?3.5 °C (RCP8.5) and drying of ~ ? 3% (RCP2.6), ~ ? 30% (RCP8.5). Following the strong drying and warming projected in this region under the RCP8.5 scenario, the VIC model simulates decreases in annual runoff of about 40% by the end of the century. Such strong regional effect of climate change may have large implications for the water resources of this region. Even under the low emission scenario, the Andes snowpack is projected to decrease by 35–45% by mid-century. In more snowmelt-dominated areas, the projected hydrological changes under RCP8.5 go together with more loss in the snowpack (75–85%) and a temporal shift in the center timing of runoff to earlier dates (up to 5 weeks by the end of the century). The severity and frequency of extreme hydroclimatic events are also projected to increase in the future. The occurrence of extended droughts, such as the recently experienced mega-drought (2010–2015), increases from one to up to five events per 100 years under RCP8.5. Concurrently, probability density function of 3-day peak runoff indicates an increase in the frequency of flood events. The estimated return periods of 3-day peak runoff events depict more drastic changes and increase in the flood risk as higher recurrence intervals are considered by mid-century under RCP2.6 and RCP8.5, and by the end of the century under RCP8.5.  相似文献   
536.
ABSTRACT

Maps are explicitly positioned within the realms of power, representation, and epistemology; this article sets out to explore how these ideas are manifest in the academic Geographic Information Science (GIScience) literature. We analyze 10 years of literature (2005–2014) from top tier GIScience journals specific to the geoweb and geographic crowdsourcing. We then broaden our search to include three additional journals outside the technical GIScience journals and contrast them to the initial findings. We use this comparison to discuss the apparent technical and social divide present within the literature. Our findings demonstrate little explicit engagement with topics of social justice, marginalization, and empowerment within our subset of almost 1200 GIScience papers. The social, environmental, and political nature of participation, mapmaking, and maps necessitates greater reflection on the creation, design, and implementation of the geoweb and geographic crowdsourcing. We argue that the merging of the technical and social has already occurred in practice, and for GIScience to remain relevant for contributors and users of crowdsourced maps, researchers and practitioners must heed two decades of calls for substantial and critical engagement with the geoweb and crowdsourcing as social, environmental, and political processes.  相似文献   
537.
538.
The Santa Catalina Mountains, SE Arizona, was one of the first metamorphic core complexes to be described. Despite its status as a type example, relatively little is known about precise ages and origins of the intrusive rocks that make up most of the crystalline core. U–Pb and Hf isotopic data by laser ablation–inductively coupled plasma–mass spectrometry from zircons and Nd isotopic results from whole rocks were obtained for 12 granitoids ranging from 1,440 to 26 Ma. Results confirm that the 1.44-Ga Oracle Granite extends through the Catalina Range as variably mylonitic granite and banded gneiss. Laramide intrusions (67–73 Ma) display initial εNd values ?5 to ?8 and εHf from ?7.5 to ?9. Magmatic ages for the prominent white granite sills of the Wilderness suite are 46–57 Ma, in agreement with Terrien (2012), and these granites have initial εNd values ?8 to ?10 and εHf from ?7 to ?14. Lastly, the undeformed Catalina Granite has an age of 26 Ma, with an initial εNd and εHf of ?6 and ?8, respectively. Our Nd results agree with limited results from Farmer and DePaolo (89:10141–10160, 1984). Although the Catalina Granite seems to have a significant juvenile component based on Nd and Hf, most of the Laramide and Wilderness intrusions contain Nd and Hf compositions lying close to the evolution of 1.44-Ga Oracle Granites, a fact that is confirmed by the U–Pb data, which show both 1.7- and 1.4-Ga zircon cores in these samples, with 1.4 Ga as the dominant core age. In order to become the dominant source of most of the 72–45-Ma magmas, the Oracle pluton must not only extend across the whole Catalina region, but also have abundant deep-seated equivalents to provide magma sources.  相似文献   
539.
Historical eruptions from Mt. Ruapehu (New Zealand) have been small (<0.001 km3 of juvenile magma) and have often occurred without significant warning. Developing better modelling tools requires an improved understanding of the magma storage and transport system beneath the volcano. Towards that end, we have analysed the volatile content and major element chemistry of groundmass glass and phenocryst-hosted melt inclusions in erupted samples from 1945 to 1996. We find that during this time period, magma has been stored at depths of ~2–9 km, consistent with inferences from geophysical data. Our data also show that Ruapehu magmas are relatively H2O-poor (<2 wt%) and CO2-rich (≤1,000 ppm) compared to typical arc andesites. Surprisingly, we find that melt inclusions are often more evolved than their transporting melt (as inferred from groundmass glass compositions). Furthermore, even eruptions that are separated by less than 2 years exhibit distinct major element chemistry, which suggests that each eruption involved magma with a unique ascent history. From these data, we infer that individual melt batches rise through, and interact with, crystal mush zones formed by antecedent magmas. From this perspective, we envision the magmatic system at Ruapehu as frequently recharged by small magma inputs that, in turn, cool and crystallise to varying degrees. Melts that are able to erupt through this network of crystal mush entrain (to a greater or lesser extent) exotic crystals. In the extreme case (such as the 1996 eruption), the resulting scoria contain melt inclusion-bearing crystals that are exotic to the transporting magma. Finally, we suggest that complex interactions between recharge and antecedent magmas are probably common, but that the small volumes and short time scales of recharge at Ruapehu provide a unique window into these processes.  相似文献   
540.
Plio-Pleistocene deposits of the Lower Colorado River (LCR) and tributary alluvial fans emanating from the Black Mountains near Golden Shores, Arizona record six cycles of Late Cenozoic aggradation and incision of the LCR and its adjacent alluvial fans. Cosmogenic 3He (3Hec) ages of basalt boulders on fan terraces yield age ranges of: 3.3–2.2 Ma, 2.2–1.1 Ma, 1.1 Ma to 110 ka, < 350 ka, < 150 ka, and < 63 ka. T1 and Q1 fans are especially significant, because they overlie Bullhead Alluvium, i.e. the first alluvial deposit of the LCR since its inception ca. 4.2 Ma. 3Hec data suggest that the LCR began downcutting into the Bullhead Alluvium as early as 3.3 Ma and as late as 2.2 Ma. Younger Q2a to Q4 fans very broadly correlate in number and age with alluvial terraces elsewhere in the southwestern USA. Large uncertainties in 3Hec ages preclude a temporal link between the genesis of the Black Mountain fans and specific climate transitions. Fan-terrace morphology and the absence of significant Plio-Quaternary faulting in the area, however, indicate regional, episodic increases in sediment supply, and that climate change has possibly played a role in Late Cenozoic piedmont and valley-floor aggradation in the LCR valley.  相似文献   
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