Pb-Isotope Analyses of USGS Reference Materials

Conventional corrections for thermal ionisation mass spectrometer (TIMS) induced Pb-isotopic fractionation often result in a loss of accuracy because the commonly employed pure Pb reference materials (NIST SRM 981, 982) frequently exhibit markedly different fractionation behaviour to real geological samples. As a result, these SRMs are inappropriate for comparison and/or correction of inter-operator/ laboratory biases. A matrix-matched reference material would be preferable but, as yet, no systematic study has approached this problem. Here we present high quality Pb-isotope ratio determinations, obtained using a double spike procedure, for six USGS reference materials in an attempt to address this deficiency. Our data suggest that most of these rocks could be used as isotopic reference materials comparable, in terms of uncertainty, to the NIST SRMs. However, significant differences in isotopic composition exist between first (e.g. BCR-1) and second (e.g. BCR-2) generation samples. The cause of these differences remains unclear but has significant implications for their use as trace element reference materials.     

Radar Detection of Near-Earth Asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN

We describe Doppler-only radar observations of near-Earth asteroids 2062 Aten, 2101 Adonis, 3103 Eger, 4544 Xanthus, and 1992 QN that were obtained at Arecibo and Goldstone between 1984 and 1996. Estimates of the echo spectral bandwidths, radar cross sections, and circular polarization ratios of these objects constrain their pole-on breadths, radar albedos, surface roughnesses, taxonomic classes, rotation periods, and pole directions. Aten's bandwidth is consistent with its radiometrically determined diameter of 0.9 km. Adonis has a rotation periodP≤ 11 h and an effective diameter (the diameter of a sphere with the same projected area as the asteroid) between 0.3 and 0.8 km. The radar properties of Adonis suggest it is not a member of taxonomic classes C or M. The effective diameter of Xanthus is between 0.4 and 2.2 km with a rotation periodP≤ 20 h. Echoes from 1992 QN constrain the asteroid's pole-on breadth to be ≥0.6 km and probably exclude it from the C and M taxonomic classes. The strongest Eger echoes are asymmetric with bandwidths that set lower bounds of 1.5 and 2.3 km on the minimum and maximum breadths of the asteroid's pole-on silhouette. If Eger is modeled as a 1.5 × 2.3 km biaxial ellipsoid, then its effective diameter for an equatorial view is 1.5 km end-on and 1.9 km broadside or pole-on, implying a geometric albedo smaller than published values but still consistent with a classification as an E-type object. The near-unity circular polarization ratios of Adonis, Eger, and 1992 QN are among the highest values measured for any asteroid or comet and suggest extreme near-surface roughness at centimeter to meter scales.     

Tributary-junction fans as buffers in the sediment cascade: a multi-decadal study

Alluvial fans at tributary junctions modulate sediment flux through river networks, by buffering the mainstem channel from disturbance in the tributaries. Buffering occurs through the storage (and release) of sediment in fans. Here, we use an extensive historic dataset to characterise the ways in which fan buffering can change as sediment supply varies. In New Zealand's East Coast region, sediment supply and fluvial transport are prolific by global standards. We reconstruct how tributary-junction fans in this region have responded to sediment generated by deforestation and extreme storms. The dynamics of five fans along the Tapuaeroa River are examined for the period 1939–2015. In response to major sediment loading, fans aggraded by up to 12 m and prograded by up to 170 m. Net sediment accumulation ranged from near zero to 1.5×10⁶ m³. Fan size, gradient, sediment storage and buffering were influenced by both upstream and downstream controls. Key upstream (tributary) influences were sediment supply and stream power; downstream (mainstem) influences included distal confinement and, importantly, the nature of fan interaction with the mainstem, which aggraded by up to 6 m. The fans' ability to buffer the Tapuaeroa River from change in the tributaries was largely governed by this downstream interaction: as the mainstem aggraded, it increasingly curtailed fan progradation, thus limiting buffering. Previous studies of tributary-junction fans have related fan morphometry to basin characteristics. However, we find that fan slope and area can vary considerably at decadal, annual or even monthly timescales. Consequently, we suggest that such studies could benefit by examining regional histories of disturbance. © 2019 John Wiley & Sons, Ltd.     

Application of Multi-well Subsidence Analysis of the Beryl Embayment,Viking Graben, Northern North Sea

1 Introduction A series of studies have indicated that there were two extensional phases in the North Sea (Fig. 1). An earlier period (Late Permian-Early Triassic) of rifting occurred widely in these areas, with predominant extension direction of W-E (F?rseth, 1996; F?rseth et al., 1997). In contrast to the widely distributed Permo-Triassic extension, Jurassic extension in the North Sea were generally much more localized into the three main rift arms (Fig. 1): the Viking Graben, Moray…     

桑沟湾和胶州湾沉积物耗氧率研究

为评价浅海海域底层在碳元素生物地化循环中的作用,采用现场取样培养法测定了黄海桑沟湾和胶州湾的沉积物耗氧率。桑沟湾5月和8月的沉积物耗氧率分别为15和24 mmol.m-2.d-1;胶州湾8月的沉积物耗氧率为18 mmol.m-2.d-1。回归分析表明,2个湾的沉积物耗氧率分别与沉积物表层的有机碳和总氮含量正相关。取呼吸商为0.8,得到桑沟湾底层对有机碳的矿化率占水层初级生产力的102%(5月)和67%(8月),胶州湾底层对有机碳的矿化率占水层初级生产力的28%(8月)。取桑沟湾颗粒有机碳的生物沉积速率为236 mg.m-2.d-1,得到底层对有机碳的埋置效率为40%(5月)和3%(8月),埋置的有机碳占水层初级生产力的69%(5月)和2%(8月);胶州湾颗粒有机碳的自然沉积速率为251 mg.m-2.d-1,底层对有机碳的埋置效率为32%(8月),埋置的有机碳占水层初级生产力的13%(8月)。     

Topographic correlations with soil and regolith thickness from shallow‐seismic refraction constraints across upland hillslopes in the Valles Caldera,New Mexico

How rock is weathered physically and chemically into transportable material is a fundamental question in critical‐zone science. In addition, the distribution of weathered material (soil and intact regolith) across upland landscapes exerts a first‐order control on the hydrology of watersheds. In this paper we present the results of six shallow seismic‐refraction surveys in the Redondo Mountain region of the Valles Caldera, New Mexico. The P‐wave velocities corresponding to soil (≤ 0.6 km s^?1) were inferred from a seventh seismic survey where soil‐thickness data were determined by pit excavation. Using multivariable regression, we quantified the relationships among slope gradient, aspect, and topographic wetness index (TWI) on soil and regolith (soil plus intact regolith) thicknesses. Our results show that both soil and regolith thicknesses vary inversely with TWI in all six survey areas while varying directly with slope aspect (i.e. thicker beneath north‐facing slopes) and inversely with slope gradient (i.e. thinner beneath steep slopes) in the majority of the survey areas. An empirical model based on power‐law relationships between regolith thickness and its correlative variables can fit our inferred thicknesses with R² ‐values up to 0.880 for soil and 0.831 for regolith in areas with significant topographic variations. These results further demonstrate the efficacy of shallow seismic refraction for mapping and determining how soil and regolith variations correlate with topography across upland landscapes. Copyright © 2016 John Wiley & Sons, Ltd.     

Controls on carbon and nitrogen export in an eroding catchment of south‐eastern Queensland,Australia

Effects of gully and channel erosion on the export of sediments are in general well understood, but the effects on carbon (C) and nitrogen (N) export remain an open question. We examined these effects and the role of flow magnitude, total wet season rainfall, catchment size and the C and N content and solubility of most probable sediment sources in a subtropical catchment. We sampled the baseflow and the rising stage of high‐flow events for one wet season and analysed 5 years of water quality data from event sampling stations. Total suspended sediment was the main variable explaining N export followed by rainfall, flow and catchment size. N was exported mainly in particulate organic form and C in dissolved form. The quality of most probable sediment source fractions explains these results and points to fractionation during transport into C and N richer and C and N poorer fractions, with travel distance ultimately determining the average quality of transported sediment for different flow magnitudes. Erosion would have caused a lower C and N concentration in sediments, a lower proportion of mineralized N, a larger proportion of dissolved organic C and a larger C : N ratios of the soluble fraction as compared with unincised grassed valleys. This would alter the rates of nutrient cycling and energy flow within and across ecosystem compartments in streams receiving this export. Copyright © 2014 John Wiley & Sons, Ltd.     

The tephrochronology of Iceland and the North Atlantic region during the Middle and Late Quaternary: a review

The tephrochronology of Iceland and the North Atlantic region is reviewed in order to construct a unified framework for the last 400 kyr BP. Nearly all of the tephra layers described are also characterised geochemically. A number of new tephra layers are analysed for the first time for their geochemical signature and a number of pre‐Holocene tephra layers have been given an informal denotation. The tephrostratigraphy of Ash Zone II is highlighted. Where possible the rhyolitic tephra layers found outside Iceland have been correlated to known Icelandic tephra layers or to the volcanic source area. The application of tephra fallout in various depositional environments is described and discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Saalian to Weichselian stratigraphy and sedimentation along the Lågjæren – Høgjæren escarpment,southwest Norway

Quaternary sediments along a profile crossing the southern part of the Jæren escarpment, southwestern Norway, have been investigated with regard to their glacial history and sea-level variations. Deposits from at least three glaciations and two ice-free periods between Oxygen Isotope Stage 6 and the Late Weichselian have been identified. Subglacial till directly overlain by a glaciomarine regressional succession indicates a deglaciation, and amino acid ratios in Elphidium excavatum between 0.083 and 0.118 date this event to Oxygen Isotope Stage 6. Sea-level dropped from 130 to below 110 m a.s.l. Subsequently, a short-lived ice advance deposited a marginal moraine and a sandur locally on the escarpment. Stratigraphical position and luminescence dates around 148 ka BP suggest deposition during the final stage 6 deglaciation. A Late Weichselian till covers most of the surface of Jæren. In addition to a well documented westerly ice flow, glaciotectonic indications of ice flow towards the north have been found. Ice flow directions and a hiatus between Oxygen Isotope Stage 6 and the Weichselian indicate enhanced erosion along the escarpment and the influence of a Norwegian Channel ice-stream. Copyright © 1999 John Wiley & Sons, Ltd.