Strontium, Neodymium and Lead Isotope Analyses of NIST Glass Certified Reference Materials: SRM 610, 612, 614

The NIST glass certified reference materials, SRM 610-617, have been widely adopted by the geological community as calibration samples for a variety of in situ trace element analytical techniques. There is now an urgent requirement for similar reference materials for in situ isotopic analytical techniques. We have analysed SRM 610, 612 and 614 for their Pb, Sr and Nd isotopic compositions using thermal ionisation mass spectrometry. Large differences in isotopic composition were observed between each CRM, suggesting a significant trace element content in the initial starting material (base glass). As a result, isotopic compositions for one CRM cannot be extrapolated to another, and each must be calibrated for use independently. We present the first compilation of working values for these glasses.     

Pavement Deformation Monitoring in a Rolling Load Facility

This paper describes work undertaken to measure deformation of a pavement within the Newcastle University Rolling Load Facility (NUROLF). Precise three dimensional measurements of the pavement have been produced from stereo-imagery taken with diVerent cameras, using both analytical and digital photogrammetric instrumentation. The photogrammetric measurements, and those from the existing system consisting of an array of linear voltage displacement transducers, have been compared with measurements produced using a digital level. Encouraging results have been achieved and photogrammetry has been shown to be capable of producing a similar accuracy to the existing system. There are many advantages associated with a photogrammetric survey but attempts to establish a permanent, automated photogrammetric system for the rolling load facility at a reasonable cost have so far been unsuccessful. It is anticipated that, with the falling cost of high resolution digital sensors, such a system will soon be possible.     

Quantifying the erosional impact of the Fennoscandian ice sheet in the Torneträsk–Narvik corridor, northern Sweden, based on cosmogenic radionuclide data

Despite spectacular landform evidence of a dominant role for glacial action in shaping landscapes under former northern hemisphere ice sheets, there is little quantitative evidence for rates and patterns of erosion associated with specific glaciations. Here we use cosmogenic nuclide data to assess rates of subglacial erosion underneath the Fennoscandian ice sheet. By testing whether there are remnant nuclide concentrations in samples taken from sites that include both relict areas and features and landscapes typically associated with vigorous glacial erosion, we can constrain the level and pattern of modification that resulted from the last glaciation. Cosmogenic ¹⁰Be and ³⁶Cl data from the Torneträsk region confirm the temporal and spatial variability of glacial erosion suggested by geomorphological mapping. At some sites, glacial erosion estimates in what appear to be heavily scoured areas indicate erosion of only c. 2 ± 0.4 m of bedrock, based on cosmogenic nuclide inheritance. This implies that the generation of severely scoured terrain in this study area required multiple glaciations. The overall modification produced by ice sheets along glacial corridors may be more restricted than previously thought, or may have occurred preferentially during earlier Quaternary glacial periods.     

Glacial mass balance of Austre Brøggerbreen (Spitsbergen), 1971–1999, modelled with a precipitation-run-off model

An energy balance based HBV model was calibrated to the run-off from Bayelva catchment in western Spitsbergen, Svalbard. The model simulated the glacier mass balance, and the results were compared to observations at Austre Brøggerbreen for the period 1971-1997. Even though the model was optimized to observed run-off from a catchment in which the glaciers constitute 50% of the area, and not to the observation of glacier mass balance, the model was able to reconstruct the trends and values of the mass balance found through observations. On average the simulation gave a negative net balance of 696 mm. The observed average is 442 mm. The simulated winter accumulation was in average for the same period 9% lower and the summer ablation 17% higher than the observed. The years 1994-96 show deviations between simulated and observed winter accumulation up to 160%. This can probably be accounted for by extreme rainfall during the winter, leading to thick ice layers which make accurate observations difficult. The higher simulated summer ablation might indicate that the glaciers in the catchment as a whole have a larger negative mass balance than Austre Brøggerbreen. The simulations showed that the glacier mass-balance would be in equilibrium with a summer temperature 1.2°C lower than the average over the last decades or with a 100% increase in the winter (snow) precipitation. These are higher values than former estimates. A combined change of temperature and precipitation showed a synergic effect and thereby less extreme values.     

Quantifying the erosional impact of the Fennoscandian ice sheet in the Torneträsk–Narvik corridor, northern Sweden, based on cosmogenic radionuclide data

Despite spectacular landform evidence of a dominant role for glacial action in shaping landscapes under former northern hemisphere ice sheets, there is little quantitative evidence for rates and patterns of erosion associated with specific glaciations. Here we use cosmogenic nuclide data to assess rates of subglacial erosion underneath the Fennoscandian ice sheet. By testing whether there are remnant nuclide concentrations in samples taken from sites that include both relict areas and features and landscapes typically associated with vigorous glacial erosion, we can constrain the level and pattern of modification that resulted from the last glaciation. Cosmogenic ¹⁰Be and ³⁶Cl data from the Torneträsk region confirm the temporal and spatial variability of glacial erosion suggested by geomorphological mapping. At some sites, glacial erosion estimates in what appear to be heavily scoured areas indicate erosion of only c. 2 ± 0.4 m of bedrock, based on cosmogenic nuclide inheritance. This implies that the generation of severely scoured terrain in this study area required multiple glaciations. The overall modification produced by ice sheets along glacial corridors may be more restricted than previously thought, or may have occurred preferentially during earlier Quaternary glacial periods.     

Effects of decreased pH on marine organisms

Sea water scrubbing of flue gas may result in a significant pH decrease in the waters of coastal areas with restricted dilution capacity. A review of the literature on pH tolerance of marine organisms indicates that there is little evidence of harm caused by decrease of 0.5–1.0 pH units. However, few long term or life cycle studies have been conducted. As pH may influence seawater chemistry in several important ways, notably the carbonic acid equilibrium, chemical form of metals, and the characteristics of dissolved substances, it is concluded that pH tolerance deserves more interest from marine biologists than it has received hitherto.     

Fossil pigments as a guide to the paleolimnology of Browns Lake, Ohio

Some aspects of the paleolimnology of Browns Lake, Ohio, have been ascertained by a study of preserved sedimentary plant pigments and conductivity of interstitial water. Temporal changes in the sedimentary environment, especially redox conditions, along with changes in the flora of the lake and the development of peat in the basin have brought about differential sedimentation and preservation of pigments. Measurement of changes in total and relative concentration and diversity of chlorophyll derivatives and carotenoids has provided important clues to late-glacial and postglacial evolution of the lake. Laminated sediments, rich in fossil remains, near the base of the core indicate eutrophic conditions and meromixis for several thousand years beginning shortly after lake inception. As meromixis broke down, the lake evolved gradually to holomictic conditions when sapropel was deposited. An advancing complex of reed swamp and fen forest began during midpostglacial time, providing ever-increasing amounts of highly organic, peaty sediments and continues to the present. The pond is now dystrophic, and increasing deposition of inorganic sediment is apparent at the top of the core, concomitant with land clearance and agriculture. In the same interval, an increase of water conductivity reflects recent agricultural practices and industrialization in the region.     

Thermal effects of thrust faulting

Calculations based on simple models of overthrust sheets in crystalline basement rocks show that significant thermal effects may result from their movements. If rates are sufficiently high (e.g. plate tectonic rates), the thrust sheets sufficiently thick (5, 10 and 15 km are modelled here), the distances moved sufficiently large, and for reasonable values of the coefficient of friction along the thrust plane overthrusting can cause metamorphic mineral zonations and heat flow anomalies observable in the field. Regions where large-scale overthrusting has occurred should be characterized by a decrease with depth of grade of metamorphic mineral assemblages and anomalously low heat flow. The theoretical effects are presented as a series of maximum temperature vs. depth and heat flow vs. time plots.