Partitioning of dioxins (PCDDs/Fs) in ambient air at urban residential locations

In this work, 17-polychlorinated dibenzo-p-dioxin/furan (PCDD/Fs) isomers were measured in ambient air at four urban sites in Seoul, Korea (from February to June 2009). The concentrations of their summed values (ΣPCDD/Fs) across all four sites ranged from 1,947 (271 WHO₀₅ TEQ) (Jong Ro) to 2,600 (349 WHO₀₅ TEQ) fg/m³ (Yang Jae) with a mean of 2,125 (± 317) fg/m³ (292 WHO₀₅ TEQ fg/m³). The sum values for the two isomer groups of ΣPCDD and ΣPCDF were 527 (30 WHO₀₅ TEQ) and 1,598 (263 WHO₀₅ TEQ) fg/m³, respectively. The concentration profile of individual species was dominated by the 2,3,4,7,8-PeCDF isomer, which contributed approximately 36 % of the ΣPCDD/Fs value. The observed temporal trends in PCDD/F concentrations were characterized by relative enhancement in the winter and spring. The relative contribution of different sources, when assessed by principal component analysis, is explained by the dominance of vehicular emissions along with coal (or gas) burning as the key source of ambient PCDD/Fs in the residential areas studied.     

An assessment of geologic sequestration potential in the panhandle of Florida USA

One alternative to reduce global greenhouse gas emissions is to store the emissions in underground geologic sequestration repositories. The efficacy of this approach has been favorably evaluated by numerous authors over the last 15 years. This paper discusses an assessment of the overall feasibility of storing emissions in three different repositories in the Florida panhandle located in the Southeastern United States. The feasibility assessment evaluates both saline aquifers and oil reservoirs located in the panhandle region. The overall feasibility is driven by the available geologic sequestration capacity, the transportation cost to deliver emissions to a respective repository, and other engineering and regulatory issues. The geologic sequestration capacity is generally controlled by the so-called storage efficiency, a variable dependent on the site-specific geology, reservoir conditions, and the injected fluid characteristics. For this paper, storage efficiency for saline repositories was assessed in more detail using numerical modeling. Based on the work completed, the 3 repositories studied have at least 4.55 gigatonnes of capacity to sequester CO₂.     

A comparison of stream water temperature regimes from open and afforested moorland,Yorkshire Dales,northern England

Despite the known importance of water temperature for river ecosystems, the thermal regime of streams and rivers can be heavily modified by afforestation. Although the nature of the heat budget affecting streams in forested catchments shows high variability in space and time, most of the studies of stream temperature response to afforestation have lacked replication among streams. This study examined the impacts of coniferous forest plantations on stream water temperature at six sites (three forested and three open moorland) in the Yorkshire Dales, northern England. Our aim was to test the hypothesis that afforestation would alter the thermal regime of streams, leading to reduced year‐round thermal variability, and cooler summer/warmer winter water temperatures, relative to streams flowing across open moorland. Data collected from April 2007 to March 2009 showed similar thermal dynamics among all six streams over the study period, although variability in forested streams was markedly lower as expected. Mean and maximum daily water temperatures were significantly higher in open moorland streams for much of the year but while some forested streams were warmer than individual moorland streams during winter months (November to February), there was considerable overlap in water temperature between moorland and forest streams. Most stream temperature records showed evidence of low/no winter flow and freezing. These results contrast with many previous studies that have reported warmer temperatures in forested versus open moorland streams during winter, a finding that most likely reflects site‐specific hydrological, geomorphological and climatological influences on water temperature in addition to afforestation. This study demonstrates the need for replication of hydrological monitoring when examining the effects of basin‐scale management practices and provides further evidence for changes in stream thermal regime following afforestation, a practice that is likely to increase in future due to growing demands for increased forest cover in the UK uplands. Copyright © 2010 John Wiley & Sons, Ltd.     

The Younger Dryas in the English Lake District: reconciling geomorphological evidence with numerical model outputs

The geomorphology of the south‐western and central Lake District, England is used to reconstruct the mountain palaeoglaciology pertaining to the Lateglacial and Younger Dryas. Limitations to previous ice‐mass reconstructions and consequent palaeoclimatic inferences include: (i) the use of static (steady‐state) glacier reconstructions, (ii) the assumption of a single‐stage Younger Dryas advance, (iii) greatly varying ice‐volume estimates, (iv) inexplicable spatial variations in ELA (Equilibrium Line Altitude), and (v) a lack of robust extent chronology. Here we present geomorphological mapping based on aerial photography and the NextMap Britain Digital Elevation Model, checked by ground survey. Former glacier extents were inferred and ELAs were calculated using the Balance Ratio method of Osmaston. Independently, a time‐dependant 2‐D ice‐flow model was forced by a regional ELA history that was scaled to the GRIP record. This provided a dynamic reconstruction of a mountain ice field that allowed for non‐steady‐state glacier evolution. Fluctuations in climate during the Younger Dryas resulted in multiple glacial advance positions that show agreement with the location of mapped moraines, and may further explain some of the ELA variations found in previous local and static reconstructions. Modelling based on the GRIP record predicts three phases: an initial maximum extent, a middle minor advance or stillstand, and a pronounced but less extensive final advance. The comparisons find that the reconstructions derived from geomorphological evidence are effective representations of steady‐state glacier geometries, but we do propose different extents for some glaciers and, in particular, a large former glacier in Upper Eskdale.     

Midfrequency "Through-the-Sensor" scattering measurements: a new approach

In this paper, a new paradigm for "through-the-sensor" remote sensing of the seafloor is presented. The methodology has been tailored for use with the AN/SQS-53C sonar found on many U.S. Navy destroyers. Sonar beamformer outputs are processed, and a point georeferenced database of signal attributes is constructed. Corresponding sonar settings and ship navigation information are also included for each database point. Database entries are then fused with environmental characteristics, such as bathymetry and sound speed information. These data may be derived from historical databases, on-site measurements, or a combination of the two. The database is then completed by ambiguity resolution and matching of modeled eigenray paths with database entries in order to associate signal attributes with specific propagation paths. Model inputs are derived from a customized version of the Comprehensive Acoustic System Simulation/Gaussian Ray Bundle eigenray propagation model (CASS/GRAB), which performs propagation estimates over incremental range/depth steps. Illustrations of how the point database may be filtered/constrained, gridded, and displayed are presented. An example of how bottom scattering strength can be derived from the database is presented, followed by an example of a technique for monostatic bottom loss estimation. Results indicate that the approach presented in this paper represents a viable method for conducting "through-the-sensor" measurements of seafloor scattering properties.     

Chromospheric Height and Density Measurements in a Solar Flare Observed with RHESSI – II. Data Analysis

We present an analysis of hard X-ray imaging observations from one of the first solar flares observed with the Reuven Ramaty High-Energy Solar Spectroscopic Imager (RHESSI) spacecraft, launched on 5 February 2002. The data were obtained from the 22 February 2002, 11:06 UT flare, which occurred close to the northwest limb. Thanks to the high energy resolution of the germanium-cooled hard X-ray detectors on RHESSI we can measure the flare source positions with a high accuracy as a function of energy. Using a forward-fitting algorithm for image reconstruction, we find a systematic decrease in the altitudes of the source centroids z(ε) as a function of increasing hard X-ray energy ε, as expected in the thick-target bremsstrahlung model of Brown. The altitude of hard X-ray emission as a function of photon energy ε can be characterized by a power-law function in the ε=15–50 keV energy range, viz., z(ε)≈2.3(ε/20 keV)^−1.3 Mm. Based on a purely collisional 1-D thick-target model, this height dependence can be inverted into a chromospheric density model n(z), as derived in Paper I, which follows the power-law function n _e(z)=1.25×10¹³(z/1 Mm)^−2.5 cm⁻³. This density is comparable with models based on optical/UV spectrometry in the chromospheric height range of h≲1000 km, suggesting that the collisional thick-target model is a reasonable first approximation to hard X-ray footpoint sources. At h≈1000–2500 km, the hard X-ray based density model, however, is more consistent with the `spicular extended-chromosphere model' inferred from radio sub-mm observations, than with standard models based on hydrostatic equilibrium. At coronal heights, h≈2.5–12.4 Mm, the average flare loop density inferred from RHESSI is comparable with values from hydrodynamic simulations of flare chromospheric evaporation, soft X-ray, and radio-based measurements, but below the upper limits set by filling-factor insensitive iron line pairs.     

The supernova fragmentation model of solar system formation

We have further developed Brown's model of solar system formation. In this model, each fragment of an ejected supernova shell evolves into a separate solar system. Specifically, we have formulated the reverse-flow hypothesis that may be responsible for the inner, earthlike planets. We have written a computer program with which it is possible to calculate mass distributions within a solar nebula. We have found mass distributions similar to our solar system over a wide range of the model parameters.Los Alamos National Laboratory is operated by the University of California for the U.S. Dept. of Energy under contract W-7405-ENG-36.