Population variations in the grazing turbinid Lunella smaragda (Mollusca: Gastropoda)

The grazing turbinid gastropod Lunella smaragda was sampled regularly over 3.5 y from precise sites of different microtopography and height on the platform shore at Goat Island Beach near Leigh, Northland, New Zealand. Growth is linear for over 3 y, and the year‐classes distinct. The position of the different size‐classes is related to both the shelter afforded by the microtopography, and to the height on the shore. The populations in the mid‐eulittoral turf flats, low eulittoral bare rock areas, and the sublittoral fringe are distinct, and there is a general movement down the shore with age and size. Wave action apparently dislodges the animals from higher areas when they grow to a critical size and transports them to sites lower on the shore, where wave disturbance is less. Field experiments with marked animals and laboratory studies with a wave tank confirm that the wave‐effected distribution is size related. However measurements showed that the ratio of foot attachment area to the shell area presented to the wave does not vary with animal size. The possible benefits of wave dislodgment and wave‐effected distribution are considered.     

Diet and food preference of intertidal Astrostole scabra (Asteroidea: Forcipulata)

Dietary composition in Astrostole scabra was ascertained by regular sampling at four geographically separated locations on the Kaikoura coast between January 1976 and January 1977. A. scabra is a food generalist and scavenger with a diet composed mainly of molluscs and crustaceans belonging to more than 60 genera. The diet was dominated numerically by chitons and trochid molluscs. Several site‐specific differences in dietary composition were apparent. Only Ischnochiton maorianus was a numerically important prey species at all study sites. Dietary diversity and evenness were more or less constant and comparable both seasonally and geographically. The proportion of intertidal seastars feeding fluctuated during the study from a peak of 42% in January to 23.7% in June 1976. Prey species were consumed in proportions independent of their abundance. In the laboratory, A. scabra, free of ingestive conditioning, discriminated between different prey species and preferentially consumed I. maorianus. There were strong prey preferences at the specific, but not at the familial, level.     

Predicting suitability of cockle Austrovenus stutchburyi restoration sites using hydrodynamic models of larval dispersal

An important aspect of shellfish restoration projects is to evaluate whether potential sites are likely to be recolonised naturally once disturbances are removed and habitats are restored. Similarly, if active translocation or reseeding of juveniles or adults is undertaken, it is important to understand whether these introduced populations will be self‐maintaining in future, and whether any seed they produce are likely to be retained within the restored area. We used a combined hydrodynamic and particle tracking model to predict larval dispersion patterns for the common cockle Austrovenus stutchburyi under different hydrodynamic scenarios for seven release locations in Whangarei Harbour, New Zealand. Our results implied that sites varied substantially in their potential for self‐seeding and for exporting seed to other locations. For sites with more restricted dispersal, the model predicted that most larvae originating at these sites would settle inside the release region (68–94% for passive particle simulations), whereas relatively few larvae originating from the other release sites settled at these sites. In contrast, model larvae released from sites exhibiting high connectivity dispersed to all sub‐regions in the harbour, and export outside of the model region was high. Forthcoming field validation of these model predictions will result in better integration of hydrodynamic connectivity in whole estuary restoration programs.     

Observed winds,turbulence, and dispersion in built-up downtown areas of Oklahoma City and Manhattan

Wind and tracer data from the Oklahoma City Joint Urban 2003 (JU2003) and the Manhattan Madison Square Garden 2005 (MSG05) urban field experiments are being analyzed to aid in understanding air flow and dispersion near street-level in built-up downtown areas. The mean winds are separately calculated for groups of anemometers having similar exposures such as “near street level” and “on building top”. Several general results are found, such as the scalar wind speed at street level is about 1/3 of that at building top. Turbulent standard deviations of wind speed components and temperature, and vertical fluxes of momentum and sensible heat, are calculated from sonic anemometers near street level at 20 locations in JU2003 and five locations in MSG05, and from two rooftop locations in MSG05. The turbulence observations are consistent with observations in the literature at other cities, although the JU2003 and MSG05 data are unique in that many data are available near street level. For example, it is found that the local (i.e., at the measuring height) averages about 1.5 and the local averages about 0.25 in the two cities, where is the standard deviation of vertical velocity fluctuations, is the friction velocity, and u is the wind speed. The ratio of temperature fluctuations to temperature scale, , averages about −3 in both cities, consistent with similarity theory for slightly unstable conditions, where is the standard deviation of temperature fluctuations, and is the temperature scale. The calculated Obukhov length, L, is also consistent with slightly unstable conditions near street level, even at night during JU2003. The SF₆ tracer concentration observations from JU2003 are analyzed. Values of for the continuous releases are calculated for each release and arc distance, where is the 30-min average arc maximum concentration, Q is the continuous source emission rate, and u is the spatial-averaged wind speed in the downtown area. The basic characteristics of the JU2003 plot of averaged agree reasonably well with similar plots for other urban experiments in Salt Lake City and London (i.e., at . A is found to be about 3 during the day and about 10 during the night.     

Shear stress partitioning in large patches of roughness in the atmospheric inertial sublayer

Drag partition measurements were made in the atmospheric inertial sublayer for six roughness configurations made up of solid elements in staggered arrays of different roughness densities. The roughness was in the form of a patch within a large open area and in the shape of an equilateral triangle with 60 m long sides. Measurements were obtained of the total shear stress (τ) acting on the surfaces, the surface shear stress on the ground between the elements (τ_S) and the drag force on the elements for each roughness array. The measurements indicated that τ_S quickly reduced near the leading edge of the roughness compared with τ, and a τ_S minimum occurs at a normalized distance (x/h, where h is element height) of (downwind of the roughness leading edge is negative), then recovers to a relatively stable value. The location of the minimum appears to scale with element height and not roughness density. The force on the elements decreases exponentially with normalized downwind distance and this rate of change scales with the roughness density, with the rate of change increasing as roughness density increases. Average τ_S : τ values for the six roughness surfaces scale predictably as a function of roughness density and in accordance with a shear stress partitioning model. The shear stress partitioning model performed very well in predicting the amount of surface shear stress, given knowledge of the stated input parameters for these patches of roughness. As the shear stress partitioning relationship within the roughness appears to come into equilibrium faster for smaller roughness element sizes it would also appear the shear stress partitioning model can be applied with confidence for smaller patches of smaller roughness elements than those used in this experiment.     

Persistent organic pollutants and stable isotopes in biopsy samples (2004/2006) from Southern Resident killer whales

“Southern Resident” killer whales include three “pods” (J, K and L) that reside primarily in Puget Sound/Georgia Basin during the spring, summer and fall. This population was listed as “endangered” in the US and Canada following a 20% decline between 1996 and 2001. The current study, using blubber/epidermis biopsy samples, contributes contemporary information about potential factors (i.e., levels of pollutants or changes in diet) that could adversely affect Southern Residents. Carbon and nitrogen stable isotopes indicated J- and L-pod consumed prey from similar trophic levels in 2004/2006 and also showed no evidence for a large shift in the trophic level of prey consumed by L-pod between 1996 and 2004/2006. ∑PCBs decreased for Southern Residents biopsied in 2004/2006 compared to 1993–1995. Surprisingly, however, a three-year-old male whale (J39) had the highest concentrations of ∑PBDEs, ∑HCHs and HCB. POP ratio differences between J- and L-pod suggested that they occupy different ranges in winter.     

Using UCODE_2005 and PHREEQC to determine thermodynamic constants from experimental data

This article presents a method for estimating chemical thermodynamic constants from experimental data using the two computer programs UCODE_2005 and PHREEQC. As an example, the conditional stability constant for lead (Pb) complexation by a remediation agent (carboxymethyl-beta-cyclodextrin) is estimated, but the method can be applied to estimate other thermodynamic parameters such as sorption constants and degradation rate constants. Advantages of this technique include estimation of uncertainties associated with estimated parameters, evaluation of information content of observations, statistical evaluation of the appropriateness of the conceptual model, and statistical-based comparison of different models.     

Latin hypercube approach to estimate uncertainty in ground water vulnerability

A methodology is proposed to quantify prediction uncertainty associated with ground water vulnerability models that were developed through an approach that coupled multivariate logistic regression with a geographic information system (GIS). This method uses Latin hypercube sampling (LHS) to illustrate the propagation of input error and estimate uncertainty associated with the logistic regression predictions of ground water vulnerability. Central to the proposed method is the assumption that prediction uncertainty in ground water vulnerability models is a function of input error propagation from uncertainty in the estimated logistic regression model coefficients (model error) and the values of explanatory variables represented in the GIS (data error). Input probability distributions that represent both model and data error sources of uncertainty were simultaneously sampled using a Latin hypercube approach with logistic regression calculations of probability of elevated nonpoint source contaminants in ground water. The resulting probability distribution represents the prediction intervals and associated uncertainty of the ground water vulnerability predictions. The method is illustrated through a ground water vulnerability assessment of the High Plains regional aquifer. Results of the LHS simulations reveal significant prediction uncertainties that vary spatially across the regional aquifer. Additionally, the proposed method enables a spatial deconstruction of the prediction uncertainty that can lead to improved prediction of ground water vulnerability.     

Effects of anthropogenic seawater acidification on acid-base balance in the sea urchin Psammechinus miliaris

The purple-tipped sea urchin, Psammechinus miliaris, was exposed to artificially acidified seawater treatments (pH(w) 6.16, 6.63 or 7.44) over a period of 8 days. Urchin mortality of 100% was observed at pH(w) 6.16 after 7 days and coincided with a pronounced hypercapnia in the coelomic fluid producing an irrecoverable acidosis. Coelomic fluid acid-base measures showed that an accumulation of CO(2) and a significant reduction in pH occurred in all treatments compared with controls. Bicarbonate buffering was employed in each case, reducing the resultant acidosis, but compensation was incomplete even under moderate environmental hypercapnia. Significant test dissolution was inferred from observable increases in the Mg(2+) concentration of the coelomic fluid under all pH treatments. We show that a chronic reduction of surface water pH to below 7.5 would be severely detrimental to the acid-base balance of this predominantly intertidal species; despite its ability to tolerate fluctuations in pCO(2) and pH in the rock pool environment. The absence of respiratory pigment (or any substantial protein in the coelomic fluid), a poor capacity for ionic regulation and dependency on a magnesium calcite test, make echinoids particularly vulnerable to anthropogenic acidification. Geological sequestration leaks may result in dramatic localised pH reductions, e.g. pH 5.8. P. miliaris is intolerant of pH 6.16 seawater and significant mortality is seen at pH 6.63.     

Reconstruction of contaminant trends in a salt wedge estuary with sediment cores dated using a multiple proxy approach

The Taunton River is a partially mixed tidal estuary in southeastern Massachusetts (USA) which has received significant contaminant inputs, yet little information exists on the history of discharge and the subsequent fate of these contaminants. Three sediment cores taken along a transect were analyzed, reconstructing the spatial and temporal trends of pollution in the estuary. A combination of radiometric dating, contaminant markers, and storm layers from major hurricanes were used to establish age models and sedimentation rates. Age estimates obtained from the different dating methods compared well, establishing an accurate history of contaminant release to the estuary. Polycyclic aromatic hydrocarbons (PAHs) were present in one core at depths corresponding to the early 1860s, earlier than previously established dates of introduction. Temporal and spatial trends of Cr, Cu, Hg and Pb indicated multiple sources of varying input to the river. Polychlorinated biphenyls (PCBs) were present in each of the cores from the 1930s onward, with elevated levels still present in surficial sediments at several sites. A unique organic compound, Topanol, which was produced locally was used as a tracer to track contaminant transport in the river. Tracer data indicates that contaminants are still being transported and deposited to surficial sediments at high concentrations well after their discharge. This reconstruction demonstrates the utility of using multiple dating proxies where often the sole use of radiometric dating techniques is not an option and provides insights into the fate of contaminants discharged decades ago but continue to represent environmental risks.