Relation between the monthly sums of sunshine and global radiation

Summary The statistical treatment of the dependence of monthly sums of global radiation on the monthly sums of sunshine at the stations of Hradec Králové, Bratislava — Koliba and Hurbanovo is presented. The parameters of linear and quadratic regression are derived for the said stations and for the individual months of the year. Drawing on the statistical analysis of the initial data sets, the accuracy and reliability of the mentioned regression relations are critically evaluated.     

Electron microprobe study of a ‘mysterite’-bearing inclusion from the Krymka LL-chondrite

The black inclusion from the Krymka LL3 chondrite previously found to contain ‘mysterite’ by Lewiset al. (1979) belongs to a hitherto unknown class of carbonaceous chondrites. Its olivine and pyroxene compositions. Fo 97–99 and En 96, respectively, are characteristic of carbonaceous chondrites and its plagioclase composition. An 100, is characteristic of C3's. It contains a peculiar group of Co-, Cr-rich metal grains whose compositions are similar, but not identical, to those in C2 chondrites and which also bear some similarities to those in Renazzo. Its weight ratios of total $\text{Fe}\text{SiO}{}_2$ and $\text{solSiO}{}_2\text{MgO}$ are 0.74 and 1.43, respectively, and its atomic ratio of $\text{Si}\text{Al}$ is 10.7, exactly the same as in carbonaceous chondrites. Its bulk chemical composition is very close to that of the Murchison C2 chondrite. The association of mysterite with a special type of carbonaceous chondrite material suggests that mysterite formed by low-temperature condensation in a different region of the nebula from other carbonaceous chondrites.     

Specimen-apparatus interaction during stick-slip in a tri axial compression machine: A decoupled two-degree-of-freedom model

The stick-slip of frictional sliding depends not only on material properties but also on the elastic and inertial properties of the loading system. To compare data from different testing machines or to apply them to the problem of natural seismogenic faulting, one must account for the differences in stiffness and mass. We develop a simple mechanical model to describe the stick-slip oscillation during frictional sliding in a triaxial-compression machine. The experimental system, the loading frame and rock specimen with precut sliding surface, is divided into two subsystems across this surface. The model is based upon two key assumptions: the kinetic friction is constant regardless of the relative motion of the subsystems, and the elastic restoring force is uniform throughout each subsystem. The first assumption leads to the decoupling of the subsystems, and the behavior of each becomes mathematically analogous to that of a simple spring/mass/slider-block model, owing to the second assumption. The theory agrees well with the experimental data from the dynamic measurements of stick-slip. The displacement-time function is of cosine form, the rise time of stick-slip is constant, and the relation between force drop and average displacement rate is linear. From this model we argue that the differences in the frictional behavior of experimental fault-gouges may indeed be ascribed to differences in the material properties of their specimens because the elastic and inertial properties of a particular testing machine are little influenced by the specimen itself, so long as all specimens are of about the same size. However, interlaboratory correlations may well be invalid unless machine effects are properly accounted for.     

Sedimentary processes and trace metal contaminants in the buccaneer oil/gas field,northwestern gulf of Mexico

Sediments are the ultimate sink for contaminants in the marine environment, and physical processes of sedimentation influence the distribution and accumulation of these contaminants. Evaluation of contaminant levels in sediments is one approach to assessing environmental impact; data interpretation depends on consideration of sediment texture and mineralogy, however, which profoundly influence chemical composition. In this study, comparison of potentially contaminated sediments from the production field with control populations was done only within the context of similar (as to texture and organic carbon and carbonate content) sample groups as determined by cluster analysis. Ba, Cd, and Sr are identified as contaminants. Supported by the identification of a well-crystallized expandable clay—possibly bentonite—drilling fluids are a potential source of Ba. Ba and Sr may be unnaturally high because of their abundance in discharged produced formation waters, but may also be naturally controlled by the unique faunal assemblage associated with the structures. Cd is probably derived from corrosion of the structures and assorted debris on the seafloor. In general, contamination is limited to an area within 100 m of the platforms. Furthermore, substantial erosion around platforms has probably effectively removed and dispersed the bulk of the contaminants introduced into the marine environment by the offshore exploration/production operations.     

Paleomagnetism of a Paleozoic anorthosite from the Appalachian Piedmont,northern Delaware: possible tectonic implications

Two components of magnetization have been observed in fourty-four samples (five sites) of the anorthosites in the Arden Pluton. One component, withD = 325°,I = ?75°,k = 32, α₉₅ = 13.6°, was isolated in many samples by progressive alternating field demagnetization and in the remainder of the collection by the use of intersecting great circles of remagnetization. The corresponding pole is located at 16°N, 303°E,dp = 22.7°,dm = 24.9°. Assuming the age of the last metamorphism (Taconic, ca. 440 Ma) of the Cambrian Arden Pluton to be the age of the magnetization, this pole deviates significantly from coeval poles thus far obtained from the North American craton. The preferred explanation for this deviation is that the Arden Pluton and the surrounding Piedmont rocks belonged to a different Early Paleozoic plate on the south or east side of the Iapetus Ocean, most likely the African (Gondwana) plate, and that it was transferred to the North American plate during a subsequent continental collision.     

Josephinite: Crystal structures and phase relations of the metals

Josephinite, a complex, metal-bearing rock from the region of the Josephine Peridotite in southwest Oregon, contains FeNiCo metal alloy phases having exsolution textures. Scanning and transmission electron microscopy have revealed Widmanstaetten patterns in which the lamellae are polysynthetically twinned, ordered, face-centered-cubic FeNi₃ surrounded by untwinned, ordered, face-centered-cubic FeNi₃ and body-centered-cubic FeCo. These exsolution textures require a temperature in excess of 500°C for their formation. This is consistent with a mantle derivation of josephinite prior to obduction of the peridotite in one of the Klamath ophiolites.     

Rare earth element distribution in some hydrothermal minerals: evidence for crystallographic control

Rare earth element (REE) abundances were measured by neutron activation analysis in anhydrite (CaSO₄), barite (BaSO₄), siderite (FeCO₃) and galena (PbS). A simple crystal-chemical model qualitatively describes the relative affinities for REE substitution in anhydrite, barite, and siderite. When normalized to ‘crustal’ abundances (as an approximation to the hydrothermal fluid REE pattern), log REE abundance is a surprisingly linear function of (ionic radius of major cation—ionic radius of REE)² for the three hydrothermal minerals, individually and collectively. An important exception, however, is Eu, which is anomalously enriched in barite and depleted in siderite relative to REE of neighboring atomic number and trivalent ionic radius. In principle, REE analyses of suitable pairs of co-existing hydrothermal minerals, combined with appropriate experimental data, could yield both the REE content and the temperature of the parental hydrothermal fluid.The REE have only very weak chalcophilic tendencies, and this is reflected by the very low abundances in galena—La, 0.6 ppb; Sm, 0.06 ppb; the remainder are below detection limits.