Microscale Simultaneous Measurement of Carbon and Nitrogen Isotopes on Natural Diamond

Simultaneous analysis of carbon and nitrogen isotope ratios by SIMS was applied for the first-time to a natural diamond from the Kelsey Lake kimberlite, State Line Distinct, Colorado (UWD-1). This in situ procedure is faster, reduces sample size for analysis, and measures both isotope ratios from a single ~ 10 μm diameter pit, a critical advantage for zoned diamonds. The carbon isotope ratio (expressed as δ¹³C_VPDB) of the bulk UWD-1 crystal, determined by the conventional combustion method in the present study, is -5.9‰ ± 0.2‰ (VPDB, 2s). Nitrogen mass fraction ([N]) and isotope ratio (expressed as δ¹⁵N_Air) were determined by stepwise combustion and gas-source mass-spectrometry, resulting in 553 ± 64 μg g^-1 and -6.7‰ ± 1.1‰ (Air, 2s), respectively. Secondary ions of ¹²C₂^-, ¹²C¹³C^-, ¹²C¹⁴N^-, and ¹²C¹⁵N^- were simultaneously measured by SIMS using three Faraday cups and one electron multiplier. The spot-to-spot reproducibility of δ¹³C and δ¹⁵N values for the UWD-1 (178 spots on sixteen chips, 10 μm spots), were 0.3‰ and 1.6‰, respectively (2s). While ¹²C¹⁴N^-/¹²C₂^- ratios, which are an indicator for [N], varied up to 12% among these sixteen chips, such variation did not correlate with either δ¹³C or δ¹⁵N values. We propose that UWD-1 is a suitable reference sample for microscale in situ analysis of δ¹³C and δ¹⁵N values in diamond samples.     

Improving the valuation of groundwater

Hydrogeology Journal - An overview of groundwater economics is presented, highlighting the factors contributing to serious resource undervaluation, which is an aspect of resource management that...     

Consolidation properties and structural alteration of Old Alluvium

Acta Geotechnica - We present experimental observations and a conceptual model for understanding the compression and swelling characteristics of Old Alluvium (OA) from San Juan, Puerto Rico. Prior...     

Correction: Guidelines and pitfalls of refraction microtremor surveys

Journal of Seismology -     

Guidelines and pitfalls of refraction microtremor surveys

Journal of Seismology - The geotechnical industry has widely adopted the refraction microtremor shear-wave velocity measurement technique, which is accepted by building authorities for evaluation...     

The impact of land use and land cover changes on soil erosion in western Iran

Natural Hazards - Analysis of long-term land use and land cover (LULC) changes requires up-to-date remotely sensed data to assess their effects on erosion. This is a particularly important...     

A visibility-based assessment of tsunami evacuation signs in Seaside,Oregon

Tsunami risk mitigation programs often include iconic evacuation signage to direct locals and visitors to safety during a tsunami event. This paper examines sign placement in Seaside, Oregon, from a visibility perspective. It leverages existing visibility analysis methodologies characterize the visibility of the community’s evacuation signage and reveals patterns in the viewable landscape. Additionally, we develop a topologically 3D approach to visibility analysis using raw LiDAR datasets. This applied work situates a discussion on existing patterns of visibility, how to improve existing signage placement, 2D and 3D representation of landscape, and the importance of visibility analysis. This work aims to stimulate discussion and development of hazard research that incorporates a visibility perspective.