Intracrystalline lipids within sulfates from the Haughton Impact Structure—Implications for survival of lipids on Mars

Lipids can be present within gypsum as intracrystalline inclusions if they become incorporated within the mineral as is it precipitates. The lipids that comprise these inclusions are protected against alteration or destruction by an external oxidising chemical environment because a protective mineral matrix surrounds them. Sulfate minerals are abundant on the surface of Mars and were present in the samples that were analysed by the Viking landers. The quantities of secondary intracrystalline fossil-lipids that are present in samples of gypsum and gypsum-rich soils from the Haughton Impact Structure, Devon Island, Canadian High Arctic are sufficient to suggest that if a similar concentration of fossil lipids was present in the sulfate-rich samples analysed by the Viking Landers then they could have been detected. Possible reasons why a secondary fossil-lipid signature was not detected include a poor rate of conversion during pyrolysis, exposure of intracrystalline lipids during periods of weathering to oxidative martian diagenesis, a low level of biological productivity or an absence of a source for lipids on the surface of Mars. Polycyclic aromatic hydrocarbons of meteoritic origin, and terpane biomarkers such as hopanes and steranes, are not present in the Haughton gypsum in sufficient quantities to have been readily detected.     

Geochronology of West Indonesia and its implication on plate tectonics

The results of radiometric dating of granitic rocks around Kotanopan near the west coast of Central Sumatra indicate an average age of 45 million years.Granites from the Lassi Mass in the Padang Highlands, Central Sumatra, and the Lampong Mass, South Sumatra, possess radiometric ages of ca. 112 and ca. 88 m.y., respectively. Granites and other rocks from the offshore areas north of Java indicate an average age of 100 m.y.Late Cretaceous granitic rocks are present in the islands of the Sunda Shelf namely Anambas (ca. 86 m.y.), Tembelan (ca. 85 m.y.) and Natuna (ca. 75 m.y.).Late Paleozoic granites possessing ages of ca. 276–298 m.y. are encountered in the basement rocks near Djambi, South Sumatra.The outcome of this radiometric age dating proves to be significant for it permits a fresh analysis of the geological evolution of Indonesia based on the plate-tectonics concept.The Tertiary volcano-plutonic arc exposed along the west coast of Sumatra can be traced to the south coast of Java. The corresponding subduction zone can be found in the islands west of Sumatra and the submarine ridge south of Java.The Late Cretaceous plutonic belt of Sumatra does not continue to Java but passes north of it, running however parallel to the subduction zone of Java. These two zones merge in the Meratus Mountains of Southeast Kalimantan.Sumatra was already a volcano-plutonic arc during Permian time, suggesting that since this Period the margins of at least four lithospheric plates have remained near the side of the active Sumatran arc.The presence of Permian volcanic and granitic rocks in the Malay Peninsula and West Kalimantan, and the results of the radiometric age determination of granitic rocks from the islands situated in the Sunda Shelf area, point to the existence of other Permian and Cretaceous volcano-plutonic arcs east and north of the arcs previously described in Sumatra and Java. Thus a double volcano-plutonic arc with opposing Benioff zones must have existed during Permian and Cretaceous time in this area.The Schwaner Mountains of West Kalimantan are considered to be the place where volcano-plutonic arcs of different ages have merged together. The correlative subduction zones have to be sought in the so-called Danau Formation of West Kalimantan and the northern part of the Kuching zone, the Sibu zone of Serawak situated north of the Schwaner Mountains.The evolution and complex geology of the western part of Indonesia can only be understood by the supposition of the existence of megaplates and sub-plates generated from spreading centers situated in the Indian Ocean and presumably in the area of the South China Sea, respectively.     

Groundwater quality assessment using WQI and GIS techniques, Dindigul district, Tamil Nadu, India

The quality of groundwater was assessed by determining the physicochemical parameters (pH, EC, TDS and TH) and major ions concentration (HCO₃, Cl, FSO₄, Ca, Mg, Na and K) around Dindigul district, Tamil Nadu, India. The groundwater samples were collected from 59 bore wells covering the entire study area and analyzed using standard methods. The GIS mapping technique were adopted to highlight the spatial distribution pattern of physicochemical parameters and major ion concentration in the groundwater. Gibbs diagram reveals that the source of major ions is predominantly derived from rock–water interaction and evaporation dominance process. The salt combinations of the aquifers are dominated by CaHCO₃, mixed CaMgCl, mixed CaMgHCO₃ and CaCl facies type due to leaching and dissolution process of weathered rocks. The Canadian Council of Ministers of Environment Water Quality Index (CCMEWQI) suggests that most of the groundwater quality falls under good to marginal category. The statistical analysis indicates that the presence of major ions and physicochemical parameters are chiefly controlled by rock–water interaction and residence time of the groundwater. However, the major nutrient like nitrite in the groundwater probably comes from anthropogenic process. Based on the groundwater quality standards, majority of the samples are suitable for drinking purposes except few in the study area.     

Review of Lagrangian stochastic models for trajectories in the turbulent atmosphere

We review the theoretical basis for, and the advantages of, random flight models for the trajectories of tracer particles in turbulence. We then survey their application to calculate dispersion in the principal types of atmospheric turbulence (stratified, vertically-inhomogeneous, Gaussian or non-Gaussian turbulence in the surface layer and above), and show that they are especially suitable for some problems (e.g., quantifying ground emissions).     

High-resolution historical records from Pettaquamscutt River basin sediments: 1. Pb and varve chronologies validate record of Cs released by the Chernobyl accident

Cesium-137 derived from the explosion of the Chernobyl reactor in 1986 was preserved in anoxic sediments from a coastal environment in southern Rhode Island. Although the radioactive plume was detected in surface air samples at several locations in the United States, this is the first known record of a Chernobyl ¹³⁷Cs peak in sediments from North America. The inventory of Chernobyl ¹³⁷Cs that was preserved in the Pettaquamscutt River is small compared to European counterparts and should only be detectable for the next 15-20 yr. However, the presence of two ¹³⁷Cs peaks (1963 and 1987) identifies a well-dated segment of the sediment column that could be exploited in understanding the decomposition and preservation of terrestrial and aquatic organic matter. Different methods for calculating the ²¹⁰Pb chronology were also evaluated in this study and checked against independent varve counting. The end result is a detailed chronology of a site well suited for reconstruction of historical records of environmental change.     

Electronic structures of sulfide minerals — Theory and experiment

The sulfide minerals exhibit a rich diversity in sturctural chemistry and in electrical, magnetic and other physical properties. Models based on molecular orbital theory and incorporating some elements of band theory can be developed to describe the diverse valence electron behavior in these minerals. Qualitative models can be proposed on the basis of observed properties, and the models can be tested and refined using experimental data from X-ray emission and X-ray photoelectron spectroscopy and quantum mechanical calculations performed on cluster units which form the basic building blocks of the crystals. This approach to chemical bonding in sulfide minerals is illustrated for binary non-transition metal sulfides (ZnS, CdS, HgS, PbS), binary transition metal sulfides (FeS₂, CoS₂, NiS₂, CuS₂ ZnS₂) and more complex sulfides (CuFeS₂, Cu₂S, Ag₂S, CuS, Co₃S₄, CuCo₂S₄, Fe₃S₄). The relationship between qualitative and quantitative theories is reviewed with reference to the pyrite-marcasite-arsenopyrite-loellingite series of minerals. Application of the models to understanding structure-determining principles, relative stabilities, solid solution limits and properties such as color, reflectance and hardness are discussed.     

Petrography and geochemistry of clastic sedimentary rocks as evidences for provenance of the Lower Cambrian Lalun Formation, Posht-e-badam block, Central Iran

Petrography and geochemistry (major, trace and rare earth elements) of clastic rocks from the Lower Cambrian Lalun Formation, in the Posht-e-badam block, Central Iran, have been investigated to understand their provenance. Petrographical analysis suggests that the Lalun conglomerates are dominantly with chert clasts derived from a proximal source, probably chert bearing Precambrian Formations. Similarly, purple sandstones are classified as litharenite (chertarenite) and white sandstones as quartzarenite types. The detrital modes of purple and white sandstones indicate that they were derived from recycled orogen (uplifted shoulders of rift) and stable cratonic source. Most major and trace element contents of purple sandstones are generally similar to upper continental crust (UCC) values. However, white sandstones are depleted in major and trace elements (except SiO₂, Zr and Co) relative to UCC, which is mainly due to the presence of quartz and absence of other Al-bearing minerals. Shale samples have considerably lower content in most of the major and trace elements concentration than purple sandstones, which is possibly due to intense weathering and recycling. Modal composition (e.g., quartz, feldspar, lithic fragments) and geochemical indices (Th/Sc, La/Sc, Co/Th, Cr/Th, Cr/V and V/Ni ratios) of sandstones, and shales (La/Sc and La/Cr ratios) indicate that they were derived from felsic source rocks and deposited in a passive continental margin. The chondrite-normalized rare earth element (REE) patterns of the studied samples are characterized by LREE enrichment, negative Eu anomaly and flat HREE similar to an old upper continental crust composed chiefly of felsic components in the source area. The study of paleoweathering conditions based on modal composition, chemical index of alteration (CIA), plagioclase index of alteration (PIA) and A–CN–K (Al₂O₃ − CaO + Na₂O − K₂O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and white sandstones relative to purple sandstones. The results of this study suggest that the main source for the Lalun Formation was likely located in uplifted shoulders of a rifted basin (probably a pull-apart basin) in its post-rift stage (Pan-African basement of the Posht-e-badam block).     

A study of the depth of weathering and its relationship to the mechanical properties of near-surface rocks in the Mojave Desert

Weathered granite extends 70 m deep at Hi Vista in the arid central Mojave Desert of southern California. The low strength of this granite is due to the alteration of biotite and chlorite montmorillonite. Deep weathering probably occurs in most granites, although we cannot rule out some anomalous mechanisms at Hi Vista. Geophysical instruments set in these slightly altered rocks are limited by the unstable behavior of the rocks. Thus, tectonic signals from instruments placed in shallow boreholes give vague results. Geophysical measurements of these weathered rocks resemble measurements of granitic rocks near major faults. The rheology of the rocks in which instruments are placed limits the useful sensitivity of the instruments.     

Evolution of cold shock-bounded slabs

The stability and evolution of cold, shock-bounded slabs is studied using numerical hydrodynamic simulations. We confirm the analysis of Vishniac (1994) [ApJ, 428, 186], who showed that such slabs are unstable if they are perturbed by a displacement larger than their width. The growth rate of this nonlinear thin shell instability (NTSI) is found to increase with decreasing wavelength, in qualitative agreement with Vishniac's analysis. The NTSI saturates when the bending angle becomes large and the growth in the width of the slab pinches off the perturbation. After saturation, the slab remains greatly extended with an average density much less than the original slab density, supported primarily by supersonic turbulence within the slab. Linear perturbations are also found to be unstable in that they can lead to turbulent flow within the slab, although this response to linear perturbations is distinct from, and much less violent than the NTSI.Richard McCray