Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.     

Lithium isotope systematics of lavas from the Cook–Austral Islands: Constraints on the origin of HIMU mantle

Radiogenic isotope variations in lavas from the Cook–Austral volcanic chain have delineated three distinct mantle sources: a HIMU component, a depleted component (DM), and an enriched component (EM). To better constrain the mantle sources for South Pacific hot spot volcanism, we determined lithium isotopic compositions of lavas from Raivavae, Rapa, Mangaia and Tubuai of the volcanic chain. The study includes whole rock and mineral analyses. In general, δ⁷Li of most olivines resemble bulk rock composition whereas clinopyroxenes are variably lighter. This implies that clinopyroxene is more susceptible to diffusion-induced fractionation, in agreement with previous studies. Olivine δ⁷Li values span a narrower range than whole rock values, and do not extend to the very heavy compositions previously reported in HIMU bulk lavas. This discrepancy likely reflects alteration of bulk lavas, and suggests that Li-isotope analyses of bulk lavas should be interpreted with caution. Olivines from HIMU lavas have heavy δ⁷Li values (up to 6.2‰), and extend beyond the range reported for fresh MORB. Correlations between Li-isotopes and radiogenic isotopes suggest that the heavy δ⁷Li values in HIMU olivines are a source characteristic and not the result of post-magmatic alteration. Although the Li-isotope composition of recycled, dehydrated oceanic crust is currently under debate, our results suggest that HIMU lavas derive from a source containing recycled dehydrated oceanic crust, and that the “heavy” Li-isotope signature of altered oceanic crust is partially preserved during passage through the subduction factory.     

On the relationship of thunderstorm ice hydrometeor characteristics and total lightning measurements

Satellite-borne and ground-based devices for the detection of lightning offer the opportunity to explore relationships–on all significant scales up to global–between lightning frequency, f, and other thundercloud parameters. Calculations predict that f is proportional to the product of the downflux p of solid precipitation and the upward mass flux, I, of ice crystals. This prediction has received support from limited computational studies. The physical reasons for such a relationship are explained in terms of the paramount role of ice in the electrification of thunderstorms. Herein, this prediction is subjected to further, preliminary examination through analysis of lightning and dual-polarimetric radar data collected during the STERAO experiment conducted in Northern Colorado during the summer of 1996. The analysis has yielded some highly provisional support for this flux hypothesis. Computed trends of radar derived hydrometeor fractions of solid precipitation and small ice show correlation to the total lightning frequency and raise the possibility of determining values of p and/or I from lightning measurements.It is shown that the extent to which the observed correlations between f and both solid precipitation and small ice trends are or are not strong can provide an indication as to whether the lightning activity is limited by the available concentrations of precipitating or non-precipitating ice in the upper regions of the charging zone of the thundercloud, where most of the charge transfer occurs. It is demonstrated that the most accurate determinations of precipitation rate p from measurements of lighting frequency f are likely to be for conditions where the field-growth is limited by the availability of graupel pellets. It is shown that the simultaneous time variations of f and solid precipitation trends of the type obtained in the STERAO experiment could enable us to determine the nature of the dominant glaciation process operative in the thunderclouds studied.     

Drivers of Australian dust: a case study of frontal winds and dust dynamics in the lower lake Eyre basin

The roles of pre‐frontal, frontal and post‐frontal winds as the primary wind systems for dust entrainment and transport in Australia are well established. While the relevance of each system has been observed across different wind erosion events in central Australia, the entrainment of dust by all three winds during the passage of an individual front has not been demonstrated until now. Synoptic information, satellite aerosol and imagery, meteorological and dust concentration data are presented for a single case study erosion event in the lower Lake Eyre Basin. This event demonstrates variable dust transport in three different directions from one of the southern Hemisphere's most significant source regions, and the changing nature of the active dust pathways during the passage of a frontal system. While only a single dust event is considered, the findings show the complexity of mineral aerosol emission and transport patterns even within an individual dust outbreak. For the lower Lake Eyre Basin, this appreciation of pathway behaviour is significant for better understanding the role of aeolian inputs from the dominant Australian source to surrounding marine systems. In a wider context, the findings exhibit the detailed insights into major dust source dynamics that can be obtained from high resolution spatial and particularly temporal data, as used in combination. This work highlights the importance of adequately resolved data for the accurate determination of dust entrainment and transport patterns of major dust sources. Copyright © 2015 John Wiley & Sons, Ltd.     

On the dynamic response of an infinite Bernoulli-Euler beam

Summary This paper presents a theory of the transient Bernoulli-Euler beam problem on an elastic foundation which takes into account the effects of axial load and linear damping. An analytical solution of the steady state and the transient components has been obtained due to physically realistic load distributions. With a view to extend its practical applicability, the characteristic features of the solution are explored. Several limiting situations are investigated as special cases. It is shown that the steady state vibration can be achieved as the limit of the solution of the transient problem.     

Cross-shelf transport into nearshore waters due to shoaling internal tides in San Pedro Bay, CA

In the summer of 2001, a coastal ocean measurement program in the southeastern portion of San Pedro Bay, CA, was designed and carried out. One aim of the program was to determine the strength and effectiveness of local cross-shelf transport processes. A particular objective was to assess the ability of semidiurnal internal tidal currents to move suspended material a net distance across the shelf. Hence, a dense array of moorings was deployed across the shelf to monitor the transport patterns associated with fluctuations in currents, temperature and salinity. An associated hydrographic program periodically monitored synoptic changes in the spatial patterns of temperature, salinity, nutrients and bacteria. This set of measurements show that a series of energetic internal tides can, but do not always, transport subthermocline water, dissolved and suspended material from the middle of the shelf into the surfzone. Effective cross-shelf transport occurs only when (1) internal tides at the shelf break are strong and (2) subtidal currents flow strongly downcoast. The subtidal downcoast flow causes isotherms to tilt upward toward the coast, which allows energetic, nonlinear internal tidal currents to carry subthermocline waters into the surfzone. During these events, which may last for several days, the transported water remains in the surfzone until the internal tidal current pulses and/or the downcoast subtidal currents disappear. This nonlinear internal tide cross-shelf transport process was capable of carrying water and the associated suspended or dissolved material from the mid-shelf into the surfzone, but there were no observation of transport from the shelf break into the surfzone. Dissolved nutrients and suspended particulates (such as phytoplankton) transported from the mid-shelf into the nearshore region by nonlinear internal tides may contribute to nearshore algal blooms, including harmful algal blooms that occur off local beaches.