Sediment and particulate phosphorus characteristics in grassed waterways from row crop corn and alfalfa fields collected by manual University of Exeter samplers and automatic sampling

Phosphorus (P) export from agricultural lands above known threshold levels can result in adverse impacts to receiving water quality. Phosphorus loss occurs in dissolved and sediment‐bound, or particulate phosphorous (PP), forms, with the latter often dominating losses from row‐cropped systems. To target practices, land managers need good computer models and model developers need good monitoring data. Sediment monitoring data (e.g. radiometric finger printing and sediment P sorption capacity) can help identify sediment source areas and improve models, but require more sediment mass than is typically obtained by automatic sampling. This study compares a simple suspended sediment sampler developed at the University of Exeter (UE) with automatic sampling in intermittent channels draining corn and alfalfa fields. The corn field had a greater runoff coefficient (27%) than alfalfa (11%). No differences were found in enrichment ratios (sediment constituent/soil constituent) in PP (PP_ER) or percent loss on ignition (LOI_ER) between paired UE samplers on corn. The median LOI_ER for the UE samplers (1·9%) did not differ significantly (p > 0·13) from the automatic sampler (2·0%). The PP_ER from the UE samplers was on average 20% lower than the automatic samplers. A correlation (r² = 0·75) was found between sediment PP and % LOI from automatic samplers and UE samplers for particles < 50 µm, while for > 50 µm PP concentration did not change with changes in % LOI. Sediment ammonium‐oxalate extractable metals were similarly related to LOI, with the strongest correlation for iron (r² = 0·71) and magnesium (r² = 0·70). Copyright © 2011 John Wiley & Sons, Ltd.     

The formation and clay mineral reactions of melanoidins

Sugars and amino acids condense readily to form polymers known as melanoidins that closely resemble natural humic substances. In this study melanoidins are formed by reacting glucose with each of three amino acids: glutamic acid, valine and lysine. The basic amino acid, lysine, reacts with glucose at a much greater rate than either of the other two compounds. The chemical properties of the melanoidins are strongly influenced by the amino acid from which they are formed. The nitrogen contents, acidities and electrophoretic behavior of the polymers all reflect functional group distributions inherited from the amino acids. These chemical differences strongly influence the extent of association of the melanoidins with kaolinite and montmorillonite clay minerals. Laboratory simulations suggest that melanoidin formation may be favored in marine environments where basic amino acids should preferentially condense with sugars to form nitrogen-rich polymers that have a great affinity for clay mineral surfaces.     

Chasing a 'loose and baggy monster': almshouses and the geography of charity

This paper goes some way towards redressing the lack of geographical literature on charity through exploring the geography of the British domestic charitable sector. The size and geography of the third sector is outlined, followed by an analysis of how almshouses can be understood as inherently geographical and deeply embedded in local social networks of inclusion as well as exclusion.     

Effects of oil pollution on breeding Grey Seals

Marine mammals are probably frequently exposed to floating oil but little is known about the effect oil pollution has on them. Oil stranded on the shore in Pembrokeshire, West Wales in September 1974 coincided with the start of the Grey Seal breeding season there. Observations have been made on the effect the oil had on the newborn pups and their mothers.     

Marine algae are ‘taught’ the basics of angular momentum

Advanced modelling studies and high-resolution observations have shown that flows related to instability of the mesoscale (~ 1–10 km scale) may provide both the fertilisation mechanism for nutrient-depleted (oligotrophic) surface waters and a subduction mechanism for the rapid export of phytoplankton biomass to the deep ocean. Here, a detailed multidisciplinary analysis of the data from an example high-resolution observational campaign is presented. The data provide direct observations of the transport of phytoplankton through baroclinic instability. Furthermore, the data confirm that this transport is constrained by the requirement to conserve angular momentum, expressed in a stratified water column as the conservation of potential vorticity. This constraint is clearly seen to produce long thin filaments of phytoplankton populations strained out along isopycnal vorticity annuli associated with mesoscale frontal instabilities.     

Tectonics of complex crater formation as revealed by the Haughton impact structure,Devon Island,Canadian High Arctic

Abstract— The results of a systematic field mapping campaign at the Haughton impact structure have revealed new information about the tectonic evolution of mid‐size complex impact structures. These studies reveal that several structures are generated during the initial compressive outward‐directed growth of the transient cavity during the excavation stage of crater formation: (1) sub‐vertical radial faults and fractures; (2) sub‐horizontal bedding parallel detachment faults; and (3) minor concentric faults and fractures. Uplift of the transient cavity floor toward the end of the excavation stage produces a central uplift. Compressional inward‐directed deformation results in the duplication of strata along thrust faults and folds. It is notable that Haughton lacks a central topographic peak or peak ring. The gravitational collapse of transient cavity walls involves the complex interaction of a series of interconnected radial and concentric faults. While the outermost concentric faults dip in toward the crater center, the majority of the innermost faults at Haughton dip away from the center. Complex interactions between an outward‐directed collapsing central uplift and inward collapsing crater walls during the final stages of crater modification resulted in a structural ring of uplifted, intensely faulted (sub‐) vertical and/or overturned strata at a radial distance from the crater center of ?5.0–6.5 km. Converging flow during the collapse of transient cavity walls was accommodated by the formation of several structures: (1) sub‐vertical radial faults and folds; (2) positive flower structures and chaotically brecciated ridges; (3) rollover anticlines in the hanging‐walls of major listric faults; and (4) antithetic faults and crestal collapse grabens. Oblique strike‐slip (i.e., centripetal) movement along concentric faults also accommodated strain during the final stages of readjustment during the crater modification stage. It is clear that deformation during collapse of the transient cavity walls at Haughton was brittle and localized along discrete fault planes separating kilometer‐size blocks.     

Radiocarbon dating of Danube Delta deposits

The Holocene history of the Danube Delta has been studied using ¹⁴C analyses of faunal material. The principal phases of development include: (1) initial Letea Caroarman spit, 11,700–9800 yr B.P. in its central part, 8800-5500 yr B.P. in its southern part; (2) Sf. Gheorghe I Delta, 8900-7200 yr B.P.; (3) Sulina Delta, 7200-2000 yr B.P., and (4) Sf. Gheorghe II Delta-Chilia Delta 2000 yr B.P.-present. Other smaller-scale features have also been dated, including secondary deltas (Co?na and Sinoe Deltas) and littoral bars. Age determinations carried out on whole samples were erratic and it was found that individual species had to be separated and dated. In all cases, the older dates were of transported material whereas the younger dates gave the true age of the formation.     

Obsidian hydration dating of volcanic events

Obsidian hydration dating of volcanic events had been compared with ages of the same events determined by the ¹⁴C and KAr methods at several localities. The localities, ranging in age from 1200 to over 1 million yr, include Newberry Craters, Oregon; Coso Hot Springs, California; Salton Sea, California; Yellowstone National Park, Wyoming; and Mineral Range, Utah. In most cases the agreement is quite good. A number of factors including volcanic glass composition and exposuretemperature history must be known in order to relate hydration thickness to age. The effect of composition can be determined from chemical analysis or the refractive index of the glass. Exposure-temperature history requires a number of considerations enumerated in this paper.