Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

A robust algorithm for ellipse-based discrete element modelling of granular materials

With recent research indicating the importance of the rolling mechanism of deformation in granular systems consisting of perfectly round particles, it has become popular to use ellipse-shaped particles in the Discrete Element Method (DEM) numerical model. Inherent in this technique is the need for accurately computing ellipse to ellipse intersection, in order to properly detect contact formation and compute relative contact velocities. However, the commonly used algorithms for computing ellipse-ellipse intersection are generally poorly conditioned and can be inaccurate. An alternate method for computing ellipse-ellipse intersection is developed and presented which results in a well-conditioned, stable and accurate contact detection method. These modification are incorporated into the general DEM algorithm.     

Wrench faults,pull-apart basins,and volcanism in central Oregon: A new tectonic model based on image interpretation

A tectonic study of the Newberry Crater region of central Oregon has been based on the interpretation of Landsat Thematic Mapper imagery. Two major faults, the Brothers-Tumalo and Eugene-Denio Faults, pass NW-SE through the region and step to the right at the eastern margin of the Cascades Range. Dextral wrench faulting on these structures during the Tertiary controlled the formation of the La Pine Basin, a pull-apart structure containing Tertiary and Quaternary sediments and volcanics. Tertiary wrench faulting appears to have been associated with rotations of crustal blocks at a plate margin, but was superseded in the Quaternary by extensional faulting of the Basin and Range province. Newberry Crater and other major bimodal volcanic centres in the NW Cordillera (Crater Lake, Medicine Lake, Mt. St. Helens) seem to have a similar tectonic setting in crustal pull-aparts. A relationship between magma type and fault trend at Newberry and Medicine Lake is suggested.     

Sur quelques concentrations plombo-zinciferes du devonien inferieur du massif schisteux rhenan

Zusammenfassung The Lower Devonian of the Rhine Schist Massif is characterized by a fine detrital sedimentation which reflects a coastal plain environment located between the Old Red Sandstone continent in the N and the marine Bohemian Facies in the SE. Mineralisations are located within these coastal-plain sediments, especially in fractured horizons topped by pelitic and floored by sandy sediments of Sieg Emsian age. The mineralised localities occur in three zones: the districts of Bensberg, Eitorf and Mayen. The Lüderich locality (Bensberg) is the most important having approximately one million tons of Zn and Pb metal. It is localised within a zone having marked sedimentary characteristics since the Siegenian. Mineralisation occurs as penecontemporaneous lenses, fracture fillings etc, formed at abnormal contacts between lithological units having different competance during Siegenian and Lower Emsian deformation. However, locally there is lateral transition between the upper units of the sandy channel series and the lower units of the pelitic swamp facies. Vertical extension of mineralisations is strictly limited to the tectonic contact zone between the Odenspiel Sandstone and the Bensberg pelites. Study of mineralisations at various levels (mapping, morphology, structure, paragenetic and geochemical) leads to the formulation of a genetic model requiring complex fracturation at the contact between contrasting lithologies and preferential drainage through these fractured zones; metals are trapped on the sandstone floor, the pelitic roof trapping the vadose hydrothermal solutions. These basic controls seem to apply throughout the Bensberg, Eitorf and Mayen districts. On a more regional scale the age variations of the gangue sediments reflects a lateral displacement of red/grey facies limits due to coastal evolution. Thus one may demonstrate a type of mineral occurrence whose model may be that of epigenetic reconcentration within fractures affecting syngenetic geochemical anomalies.Zusammenfassung Das Unterdevon des Rheinischen Schiefergebirges wird durch eine feinkörnige detritische Sedimentation gekennzeichnet. Die Verteilung dieser detritischen Sedimente widerspiegelt eine flache Küstenlandschaft zwischen dem Kontinent des Unterrotliegenden im Norden und des Meeres mit der Böhmischen Fazies im Südosten. In diesen Schichten befinden sich gangförmige Vererzungen, die in Bruchzonen auftreten, die ein pelitisches Hangendes und ein sandsteinreiches Liegendes vom Siegen-Ems Alter haben. Die Lagerstätten kommen in drei Bezirken vor: Der Bensberger Bezirk, der Bezirk Eitorf und der Bezirk Mayen. Die Lagerstätte Lüderich (Bensberger Revier) ist die größte (ungefähr eine Million Tonnen Metall Zink+Blei). Sie befindet sich in einer Zone, in der schon in der Siegen-Stufe bemerkenswerte sedimentäre Strukturen auftreten. Die Vererzung tritt als penekonkordante Linsen, Gänge, Stockwerke in tektonischen Kontaktzonen auf. Diese Kontaktzonen befinden sich zwischen 2 verschiedenen sedimentären Einheiten, deren Gesteinseigenschaften sehr verschieden sind. Es handelt sich um Pelite mit Sandstein-Einschaltungen einerseits, die zur unteren Emsstufe gehören sollen und um fluviatile Sandsteine andererseits, die zur oberen Siegenstufe gehören sollen. Lokal ist ein lateraler Übergang durch Faziesänderung von den oberen Sandsteinen in die unteren Pelitschichten jedoch nicht unmöglich. Die Sandsteine vertreten einen fluviatilen Sedimentationsbereich, die Pelite einen sumpfigen Sedimentationsbereich. Die Vererzung (mit einer vertikalen Ausdehnung ungefähr von 300 m) tritt nur im Bereich der Kontaktzone zwischen den Odenspieler Sandsteinen und den Peliten der Unteren Bensberger Schichten auf. Die Resultate der Kartographie, der morphologischen Studie der Erzkörper, der Struktur und der Paragenese führen zu einem genetischen Modell. Dabei spielt die Anwesenheit einer Bruchstruktur an der Grenze zwischen 2 Bereichen mit verschiedenen lithologischen Eigenschaften eine Hauptrolle für die Konzentration der im Hangenden fein verteilten Metalle. Die hydrothermalen Lösungen kommen demnach nicht von der Teufe, sondern aus dem Nebengestein. Im ganzen Bensberger Erzrevier wie in der Gegend von Eitorf und in der Gegend von Mayen finden wir dieselben Leitfäden für die Vererzung in den Lagerstätten und Vorkommen. Beobachtet man die ganze Provinz, dann merkt man, daß die Altersverschiedenheiten in den Nebengesteinen der verschiedenen Lagerstätten eine geographische Wanderung der Faziesgrenze zwischen rot und grau in dieser küstennahen Ebene Widerspiegeln. Die verschiedenen Vorkommen und Lagerstätten treten immer in unmittelbarer Nähe dieser Grenze auf. Die Eigenschaften dieser Lagerstätten weisen auf eine Bildung durch eine epigenetische Umlagerung in eine gangförmige Bruchstruktur hin.     

Proper motion surveys in the infrared

Current and future wide field surveys in infrared passbands present opportunities for ultra low‐mass stellar sample selection via proper motions, as well as or instead of purely photometric techniques. Furthermore, proper motion measurements yield additional clues as to candidate membership of cluster or field (kinematic) populations. In this paper we review some recent results and speculate as to the possibilities afforded by the next generation of wide‐field infrared surveys. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Heavy rare gases from Rabbit Lake (Canada) and the Oklo mine (Gabon): natural spontaneous chain reactions in old uranium deposits

Xenon isotopic studies confirm natural spontaneous chain reactions at the Oklo mine site (Republic of Gabon) with an integrated neutron flux of approximately 4 × 10²⁰n/cm² and a duration between 14,000 and 70,000 years. Similar studies for the Rabbit Lake deposit (Saskatchewan), a slightly younger site with some evidence of continued geologic activity, shows no evidence of self-supporting reactions.     

Early Holocene brackish closed basin conditions in Georgian Bay, Ontario, Canada: microfossil (thecamoebian and pollen) evidence

Microfossils have been critical in unravelling the complex postglacial history of Georgian Bay. Thecamoebians (testate amoebae/rhizopods) record paleolimnological conditions, and pollen stratigraphy allows correlation across the basin, where sedimentation has been spatially and temporally discontinuous. Because parts of Georgian Bay have been non-depositional or erosional since the end of the Nipissing transgression (~5,000 (5,800 cal) BP), early Holocene features are exposed on the lakebed. Among these are shoreline features, such as submerged beaches and relict channels, associated with low-level Lake Hough that was driven far below the level of basin overflow. Cores taken throughout Georgian Bay record the existence of closed basin conditions that persisted several centuries around 7,500 (8,300 cal) BP, corresponding to the late Lake Hough lowstand. Evidence for hydrologic closure includes a low-diversity centropyxid-dominated thecamoebian fauna around the boundary between pollen subzones 2a and 2b in the Flowerpot Beach core, Flowerpot and Killarney basins, and in Severn Sound. This low-diversity centropyxid-dominated fauna is interpreted as recording the development of slightly brackish conditions as a result of a hydrologic deficit associated with relatively arid conditions in the Great Lakes basin during the early Holocene pine zone (~8,800–7,200 (9,900–8,050 cal) BP). The rest of the Holocene record in Georgian Bay (where it is preserved) is more diverse and dominated by difflugiid thecamoebians: predominantly Difflugia oblonga prior to human settlement, and Cucurbitella tricuspis since high-density human occupation and agriculture (and resulting eutrophication) began with the Wendat First Nations people around Severn Sound about 750 years ago. The implication that water budget fluctuations leading to discernible variations in lake level and water chemistry occurred in the relatively recent geologic past is significant to studies of global climate change and resource management in the Great Lakes, one of the world’s largest freshwater resources.     

Validation of an annual cycle simulation with a T42-L20 GCM

An annual cycle of an atmospheric general circulation model (AGCM) is presented. The winter and summer zonal averages of the atmospheric fields are compared with an observed climatology. The main features of the observed seasonal means are well reproduced by the model. One of the main discrepancies is that the simulated atmosphere is too cold, particularly in its upper part. Some other discrepancies might be explained by the interannual variability. The AGCM surface fluxes are directly compared to climatological estimates. On the other hand, the calculation of meridional heat transport by the ocean, inferred from the simulated energy budget, can be compared to transport induced from climatologies. The main result of this double comparison is that AGCM fluxes generally are within the range of climatological estimates. The main deficiency of the model is poor partitioning between solar and non-solar heat fluxes in the tropical belt. The meridional heat transport also reveals a significant energy-loss by the Northern Hemisphere ocean north of 45° N. The possible implications of model surface flux deficiencies on coupling with an oceanic model are discussed.This paper was presented at the International Conference on Modelling of Global Climate Change and Variability, held in Hamburg 11–15 September 1989 under the auspices of the Meteorological Institute of the University of Hamburg and the Max Planck Institute for Meteorology. Guest Editor for these papers is Dr. L. Dümenil