Velocity profiles and bed shear stress over various bed configurations in a river bend

Vertical velocity profiles measured over various bed configurations (plane beds, ripples, and dunes) in. the meandering River South Esk, Glen Clova, Scotland are presented on semilogarithmic paper. Local bed shear stress and roughness height are calculated from the lowermost parts of the profiles using the Karman-Prandtl law of the wall; these parameters, and the geometrical properties of the profiles, are related to the various bed configurations. A graphical model is used to identify profiles developed on specific regions of dune geometry, in order to discriminate those profiles that define bed shear effective in transporting sediment over dunes. An assessment is made of the errors involved in estimating local mean velocity from extrapolating the law of the wall to the water surface. A Darcy-Weisbach friction coefficient is related to bed configuration and local stream power.     

Reply to Edward Anders: A discussion of alternative models for explaining the distribution of moderately volatile elements in ordinary chondrites

The high observed abundances of Na and Cu in chondrules indicate that the amount of loss during chondrule formation was minor and possibly negligible, consistent with the view that loss was controlled by diffusion kinetics rather than equilibrium volatility, and that the surface of the chondrule quickly cooled to temperatures at which diffusional transport was negligible. Ordinary chondrite/CI abundance ratios appear to be randomly distributed in the range 0.9-0.1. Very few values are observed in the 0.36–0.70 range, but this is not statistically significant, nor is it predicted by the two-component (chondrule-matrix) model.If CI chondrite abundances are representative of mean solar-system material, the very low chondrule content in CM chondrites (<5% of high-temperature materials) indicates that the observed volatile distribution resulted from incomplete accretion of volatile carriers (perhaps a fine aerosol). At the ordinary chondrite formation location the fraction of an element sited in unaccreted carriers increased with decreasing condensation temperature. At the CM location a similar trend is observed for elements less volatile than S, but the unaccreted fraction of more volatile elements was nearly constant.     

Chlorinated cooling waters in the marine environment: Development of effluent guidelines

The effects of free chlorine and chloramine on stage I lobster larvae and juvenile killifish were investigated in continuous flow bioassay units. In comparing mortality and changes in standard respiration rates during and after exposure to either chlorine form, significant respiratory stress was observed with exposure to sublethal levels. Sublethal responses to free and combined chlorine should be considered when establishing regulations for chlorine residuals in cooling waters.     

Two-feldspar geothermometry in granulite facies metamorphic rocks

A geothermometric technique based on equilibria between coexisting plagioclase and alkali feldspar was applied to quartzo-feldspathic granulites from Salvador, BA, Brazil. The conditions of metamorphism were determined to be in the range 750 ° C–800 ° C, 4–8 Kb, by comparison with experimental data on the stabilities of sapphirine, phlogopite and other minerals occurring in the associated rocks. Selected feldspar data gives temperatures near, but slightly below, this range. Several variants of the Wood and Banno model, as well as an empirical two-pyroxene geothermometer, were also tested and found to give temperatures which were apparently 50 °–100 ° high. The solubility of Al₂O₃ in orthopyroxene indicates temperatures which are about 200 ° to high, suggesting that Fe in the natural assemblages significantly changes relationships observed experimentally in MgO-Al₂O₃-SiO₂ systems.     

Mechanical twinning in diopside Ca(Mg,Fe)Si2O6: Structural mechanism and associated crystal defects

Diopside twins mechanically on two planes, (100) and (001), and the associated macroscopic twinning strains are identical (Raleigh and Talbot, 1967). An analysis based on crystal structural arguments predicts that both twin mechanisms involve shearing of the (100) octahedral layers (containing Ca²⁺, Mg²⁺ and Fe²⁺ ions) by a magnitude of c/2. Small adjustments or shuffles occur in the adjacent layers containing the [SiO₄]^4? tetrahedral chains. While the (100) twins are conventional with shear parallel to the composition plane, this analysis predicts that (001) twins form by a mechanism closely related to kinking. A polycrystalline diopside specimen was compressed 8% at a temperature of 400° C, a pressure of 16 kilobars, and a compressive strain rate of about 10^?4/s. Transmission electron microscopy on this specimen has revealed four basic lamellar features:

1. (100) mechanical twin lamellae;
2. (100) glide bands containing unit dislocations;
3. (001) twin lamellae;
4. (101) lamellar features, not as yet identified.

The (001) twins often contain remnant (100) lamellae of untwinned host. Twinning dislocations occur in these (100) lamellae and in the (001) twin boundaries with very high densities. Diffraction contrast experiments indicate that the twinning dislocations associated with both twin laws glide on (100) with Burgers vector b=X [001] where X is probably equal to 1/2 on the basis of the structural analysis. Parallels are drawn between mechanical twinning in clinopyroxenes and clinoamphiboles. The exclusive natural occurrence of basal twins in shock-loaded clinopyroxenes and of analogous ( \(\bar 1\) 01) twins in clinoamphiboles is given a simple explanation in terms of the relative difficulty of the “kinking” mechanism as compared to direct glide parallel to the composition plane.     

Moon—An albite depleted giant Skaergaard?

The chemical composition of 2188 terrestrial igneous rocks ranging from ultrabasic to granitic composition was analyzed statistically using the method of factor analysis (principal components). The resultant first and second factors were: $$\begin{gathered} {\text{ }}F_1 = 0.933{\text{ Na}}_{\text{2}} {\text{O + 0}}{\text{.143 SiO}}_{\text{2}} + 0.206{\text{ K}}_{\text{2}} {\text{O}} - 0.346{\text{ CaO}} - 0.263{\text{ MgO}} - \hfill \\ .203{\text{ FeO}} \pm \cdot \cdot \cdot \hfill \\ {\text{ }}F_2 = 0.979{\text{ Al}}_{\text{2}} {\text{O}}_{\text{3}} - 0.269{\text{ MgO}} - 0.151{\text{ SiO}}_{\text{2}} - 0.112{\text{ FeO}} \pm \cdot \cdot \cdot \hfill \\ \end{gathered} $$ where oxides are in weight percent. A plot of the first factor against the second results in a useful igneous variation diagram. When the compositions of the 2188 terrestrial rocks and 604 lunar rocks are plotted on this diagram, the two groups of rocks are clearly separated within an albite-anorthite-forsterite-fayalite-quartz polygon. None of the terrestrial differentiation trends are significant for lunar rocks. The major difference in the chemistry of lunar and terrestrial rocks lies in the former being albite poor. Removal of most of the albite from the compositions of terrestrial layered intrusives such as the Skaergaard results in an excellent match between the compositions of the two groups of rocks. Albite subtracted compositions of Skaergaard rocks in particular cover the entire range of chemical variation in the lunar rocks. The statistical results prompt us to speculate further on the similarity of the moon and Skaergaard. We note that the average composition of the moon (Wanke et al., 1974) is similar to the albite subtracted composition of the Skaergaard magma. The lunar crust and a significant part of the lunar interior may match the albite subtracted and somewhat Mg enriched Skaergaard magma.     

Fatty acids and Pb-210 geochronology of a sediment core from Buzzards Bay,Massachusetts

Four sections of a Pb-210 dated core of 62 cm length from Buzzards Bay, Massachusetts, were analyzed for fatty acids. A comparison of fatty acids extracted by Soxhlet extraction (unbound fatty acids) with fatty acids extracted by subsequent saponification extraction of the same sample (bound fatty acids) showed the former did not undergo diagenetic loss any faster than the latter. However, compositional differences between bound and unbound fatty acids were apparent in the top section of 1–2 cm and were less apparent in the 54–58 cm section. At least 14% of the bound fatty acids are esterified to non-solvent extractable material. The net conversion of fatty acids to other compounds is 32 μ/g dry weight sediment over the first 30 yr after deposition.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.     

Agpaitic magmatism at Norra Kärr? RbSr isotopic evidence

RbSr isotopic analyses of 10'whole-rock samples from the controversial peralkaline Norra Kärr complex of southern Sweden suggest an age (1580±62 m.y.) considerably older than had previously been anticipated, and indicate an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7072±0.0035 (errors at 2σ). The isotopic data are consistent with a primary magmatic origin for the Norra Kärr agpaites, but data from 8 mineral separates show that they have experienced at least one period of metamorphic disturbance since the original intrusion; the last episode of isotopic readjustment must have occurred after 1250 m.y. before present, and is attributed to the Sveconorwegian (Grenville) metamorphism.