Konzepte zur Mobilitätsabschätzung von Schadstoffen in Boden- und Abfallmaterialien

Concepts for the Evaluation of Contaminant Mobility in Soil and Waste Materials Elution tests (S4, pH_stat, and SDS test) are presented, enabling the evaluation of the mobility of hydrophilic/hydrophobic and inorganic/organic contaminants in soil and waste materials. While elution tests for estimation of the mobilization potential of hydrophilic substances are performed following the pH_stat method, for hydrophobic species surfactant-containing eluents are used. The individual parameters of the elution process are selected assuming a "worst-case" scenario. In principle, because of economic reasons, detailed analytical investigations should be preceded by relevant screening tests.     

UV camera measurements of fumarole field degassing (La Fossa crater,Vulcano Island)

The UV camera is becoming an important new tool in the armory of volcano geochemists to derive high time resolution SO₂ flux measurements. Furthermore, the high camera spatial resolution is particularly useful for exploring multiple-source SO₂ gas emissions, for instance the composite fumarolic systems topping most quiescent volcanoes. Here, we report on the first SO₂ flux measurements from individual fumaroles of the fumarolic field of La Fossa crater (Vulcano Island, Aeolian Island), which we performed using a UV camera in two field campaigns: in November 12, 2009 and February 4, 2010. We derived ~ 0.5 Hz SO₂ flux time-series finding fluxes from individual fumaroles, ranging from 2 to 8.7 t d^?1, with a total emission from the entire system of ~ 20 t d^?1 and ~ 13 t d^?1, in November 2009 and February 2010 respectively. These data were augmented with molar H₂S/SO₂, CO₂/SO₂ and H₂O/SO₂ ratios, measured using a portable MultiGAS analyzer, for the individual fumaroles. Using the SO₂ flux data in tandem with the molar ratios, we calculated the flux of volcanic species from individual fumaroles, and the crater as a whole: CO₂ (684 t d^?1 and 293 t d^?1), H₂S (8 t d^?1 and 7.5 t d^?1) and H₂O (580 t d^?1 and 225 t d^?1).     

Petrography and geochemistry of clastic sedimentary rocks as evidences for provenance of the Lower Cambrian Lalun Formation, Posht-e-badam block, Central Iran

Petrography and geochemistry (major, trace and rare earth elements) of clastic rocks from the Lower Cambrian Lalun Formation, in the Posht-e-badam block, Central Iran, have been investigated to understand their provenance. Petrographical analysis suggests that the Lalun conglomerates are dominantly with chert clasts derived from a proximal source, probably chert bearing Precambrian Formations. Similarly, purple sandstones are classified as litharenite (chertarenite) and white sandstones as quartzarenite types. The detrital modes of purple and white sandstones indicate that they were derived from recycled orogen (uplifted shoulders of rift) and stable cratonic source. Most major and trace element contents of purple sandstones are generally similar to upper continental crust (UCC) values. However, white sandstones are depleted in major and trace elements (except SiO₂, Zr and Co) relative to UCC, which is mainly due to the presence of quartz and absence of other Al-bearing minerals. Shale samples have considerably lower content in most of the major and trace elements concentration than purple sandstones, which is possibly due to intense weathering and recycling. Modal composition (e.g., quartz, feldspar, lithic fragments) and geochemical indices (Th/Sc, La/Sc, Co/Th, Cr/Th, Cr/V and V/Ni ratios) of sandstones, and shales (La/Sc and La/Cr ratios) indicate that they were derived from felsic source rocks and deposited in a passive continental margin. The chondrite-normalized rare earth element (REE) patterns of the studied samples are characterized by LREE enrichment, negative Eu anomaly and flat HREE similar to an old upper continental crust composed chiefly of felsic components in the source area. The study of paleoweathering conditions based on modal composition, chemical index of alteration (CIA), plagioclase index of alteration (PIA) and A–CN–K (Al₂O₃ − CaO + Na₂O − K₂O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and white sandstones relative to purple sandstones. The results of this study suggest that the main source for the Lalun Formation was likely located in uplifted shoulders of a rifted basin (probably a pull-apart basin) in its post-rift stage (Pan-African basement of the Posht-e-badam block).     

The Haraa Gol terrane in the western Hentiyn Mountains (northern Mongolia): geochemistry,geochronology, and geodynamics

According to geological, petrological, geochemical, and geochronological studies, the Haraa Gol terrane in the western Hentiyn Mts. is dominated by two rock assemblages of different ages, associated with the initiation and development of the island arcs and marginal spreading seas of the Mongol–Okhotsk Ocean. The Late Cambrian, Early Ordovician, and Middle Ordovician were marked by the effusion of basalt and basaltic andesite and the formation of gabbro and gabbro-dolerite in back-arc spreading basins. In the Late Silurian–Devonian, after a short pause, tectonomagmatic processes were activated, with the formation of differentiated island-arc volcanics, gabbro, and granitoids. Their absolute ⁴⁰Ar–³⁹Ar age is given in the paper. The model age of the T_Nd(DM) protolith of the Haraa Gol igneous rocks corresponds to the composition of the Mesoproterozoic juvenile crust.     

Proton acceleration in flares and magnetohydrodynamic solar activity

The possibility of accelerated protons in solar flares having a sharp change in their spectral index is discussed. The analysis is based on the Tsytovich (1982, 1984, 1987a, b, c) acceleration model by MHD turbulence, which is shown to have different resonant conditions for non-relativistic and relativistic particles. The different resonant condition is shown to result in a sharp change in the accelerated proton spectral index, even in the absence of any peculiarity in the spectra of the MHD turbulence. Time scales for accelerated protons to relativistic energies are also derived, and shown to be consistent with observations. We also show that the threshold energy for electron acceleration by low frequency MHD turbulence is much greater than for proton acceleration. The turbulence therefore preferentially accelerates protons.     

The thermophob experiment: Direct investigations of the thermophysical properties of the regolith of phobos

The methodology and the main features of the Thermophob experiment developed for the direct analysis of the thermophysical properties of the surface of the Martian satellite Phobos from the Phobos-Grunt lander are considered. The methodical and engineering aspects of the measurements are discussed, and the design of the instrument and the potential of the interpretation of the measurement results with accounting for the theoretical estimates and the data of the laboratory tests are discussed.     

Estimating the dark halo mass from the relative thickness of stellar disks

We analyze the relationship between the mass of a spherical component and the minimum possible thickness of stable stellar disks. This relationship for real galaxies allows the lower limit on the dark halo mass to be estimated (the thinner the stable stellar disk is, the more massive the dark halo must be). In our analysis, we use both theoretical relations and numerical N-body simulations of the dynamical evolution of thin disks in the presence of spherical components with different density profiles and different masses. We conclude that the theoretical relationship between the thickness of disk galaxies and the mass of their spherical components is a lower envelope for the model data points. We recommend using this theoretical relationship to estimate the lower limit for the dark halo mass in galaxies. The estimate obtained turns out to be weak. Even for the thinnest galaxies, the dark halo mass within four exponential disk scale lengths must be more than one stellar disk mass.     

Spectral analysis of water vapour in cool stars

M-star spectra, at wavelengths beyond 1.35 μm, are dominated by water vapour, yet terrestrial water vapour makes it notoriously difficult to obtain accurate measurement from ground-based observations. We have used the short-wavelength spectrometer on the Infrared Space Observatory at four wavelength settings to cover the  2.5–3.0 μm  region for a range of M stars. The observations show a good match with previous ground-based observations and with synthetic spectra based on the Partridge & Schwenke line list, although not with the SCAN line list. We have used a least-squared minimization technique to systematically find best-fitting parameters for the sample of stars. The temperatures that we find indicate a relatively hot temperature scale for M dwarfs. We consider that this could be a consequence of problems with the Partridge & Schwenke line list which leads to synthetic spectra predicting water bands that are too strong for a given temperature. Such problems need to be solved in the next generation of water vapour line lists, which will extend the calculation of water vapour to higher energy levels with the good convergence necessary for reliable modelling of hot water vapour. Then water bands can assume their natural role as the primary tool for the spectroscopic analysis of M stars.