Evolution of the Kivu Rift,East Africa: interplay among tectonics,sedimentation and magmatism

The seismically and volcanically active Kivu Rift, in the western branch of the East African Rift System, is a type locale for studies of high‐elevation, humid‐climate rift basins, as well as magmatic basin development. Interpretations of offshore multi‐channel seismic (MCS) reflection data, terrestrial radar topography, lake bathymetry and seismicity data recorded on a temporary array provide new insights into the structure, stratigraphy and evolution of the Kivu rift. The Kivu rift is an asymmetric graben controlled on its west side by a ca. 110 km‐long, N‐S striking border fault. The southern basins of the lake and the upper Rusizi river basin are an accommodation zone effectively linking 1470 m‐high Lake Kivu to 770 m‐high Lake Tanganyika. MCS data in the eastern Kivu lake basin reveal a west‐dipping half graben with at least 1.5 km of sedimentary section; most of the ca. 2 km of extension in this sub‐basin is accommodated by the east‐dipping Iwawa normal fault, which bounds an intrabasinal horst. Lake Kivu experienced at least three periods of near desiccation. The two most recent of these approximately correlate to the African Megadrought and Last Glacial Maximum. There was a rapid lake level transgression of at least 400 m in the early Holocene. The line load of the Virunga volcanic chain enhances the fault‐controlled basin subsidence; simple elastic plate models suggest that the line load of the Virunga volcanic chain depresses the basin by more than 1 km, reduces flank uplift locally and broadens the depocentre. Not only do the voluminous magmatism and degassing to the lake pose a hazard to the riparian population, but our studies demonstrate that magmatism has important implications for short‐term processes such as lake levels, inflow and outlets, as well as long term modification of classic half‐graben basin morphology.     

Radiometric characteristics of heavy mineral deposits along the west coast of South Africa

During the last decade, exploration and mining of modern-Tertiary heavy mineral beach and raised beach sands along the west coast of South Africa has developed into a major industry. High resolution radiometric techniques have demonstrated their use as a quantitative indicator of total heavy mineral concentration (THM) and also have the ability to discriminate between sediments derived from different provenance terrains. Results indicate that it is possible to calculate the total heavy mineral concentration from high resolution radiometric measurements, but the ability to quantify the concentration of individual mineral fractions, such as ilmenite, requires further refinement of the method. Radiometric characteristics of the light mineral fraction made it possible to distinguish between sediments from mixed marine-aeolian palaeoplacers and active present beach placers. The effects of in situ alteration of the ilmenite fraction in the palaeoplacers were also reflected by subtle contrasts in the radiometric character of the deposits. Furthermore, the uniform radiometric character of the sample population indicates a common provenance for the heavy mineral suite and supports previous results which indicate the metamorphites of the mid-Proterozoic Namaqua Province as the primary source terrain. The high resolution radiometric techniques discussed offer a broad spectrum of applications in sedimentology and have the potential to aid heavy mineral exploration. With further refinement it can possibly be used quantitatively in grade control during mining and beneficiation of heavy mineral deposits. Received: 19 July 1996 / Accepted: 7 January 1997     

U-Pb isotopic dating of zircons (SHRIMP-II) from granulites of the Ol’khon region of Western Baikal area

Doklady Earth Sciences -     

Sulphur-containing compounds in sulphur-rich crude oils from hypersaline lake sediments and their geochemical implications

Three sulphur-rich commercial crude oils have been studied, which contain sulphur as high as up to 4–12%. These samples were collected from Tertiary hypersaline lake sediments of the Jianghan Basin, Hubei Province at different depths, but above the oil generation threshold (2200m). FPD-GC and GC-MS data show that aromatic fractions of the crude oils are composed of different homologues of sulphur-containing compounds, including long-chain normal alkyl-thiophenes and-thiolanes, long-chain isoprenoid-thiophenes and -thiolanes, and benzothiophenes. It is worth noting that the distribution patterns of long-chain alkyl-thiophenes and -thiolanes from two shallow-seated crude oils are quite similar to those of normal alkanes showing marked even-odd predominance. It seems that the even-odd predominance of sulphur-containing compounds decreases with increasing burial depth of the crude oils. The major component of aliphatic fraction is phytane, and similarly the major peaks of aromatic fractions also represent C₂₀ isoprenoid thiophenes. Some preliminary conclusions have been drawn from the above discussion: (1) Abundant sulphur-containing compounds may be used as an indicator of low mature or immature crude oils produced from hypersaline lake sediments; (2) Sulphur-containing compounds are considered to be early diagenetic products of reactions between elemental sulphur or sulfides and alkanes or their precursors (phytols, fatty acids, alcohols, etc.), or of bacterial activities, but not direct inputs of organisms.     

First data on late vendian granitoid magmatism of the Northwestern Sayan–Yenisei accretionary belt

Late Vendian (540–550 Ma) U–Pb age was established for zircon from postcollisional granites of the Osinovsky Massif located among island-arc complexes of the Isakovka terrane in the northwestern Sayan–Yenisei accretionary belt. The granites were formed 150 Ma after the formation of the host island-arc complexes and 50–60 Ma after the beginning of their accretion to the Siberian Craton. These events mark the final stage of the Neoproterozoic history of the Yenisei Ridge related to the end of accretion of oceanic fragments and the beginning of the Caledonian Orogeny. The granites are subalkaline leucoractic Na–K rocks enriched in Rb, U, and Th. The petrogeochemical and Sm–Nd isotope data (T_Nd(DM)-2st = 1490–1650 Ma and ε_Nd(T) from–2.5 to–4.4) indicate that their source was highly differentiated continental crust of the SW margin of the Siberian Craton. Therefore, the host Late Riphean island-arc complexes were thrust over the craton margin for distance significantly exceeding the size of the Osinovsky Massif.     

Nannofossil age constraints for the northern KwaZulu-Natal shelf-edge wedge: Implications for continental margin dynamics, South Africa, SW Indian Ocean

Samples collected from the shelf-edge wedge using surface grab samples and the Jago submersible constrain the KwaZulu-Natal shelf-edge wedge to a late Pliocene age on the basis of the absence of Gephyrocapsa oceanica s.l. and Discoaster brouweri, and the presence of Calcidiscus macintyrei. This correlates with proposed Tertiary sea-level curves for southern Africa and indicates relative sea-level fall during the late Pliocene coupled with hinterland uplift. Exposed failure scarps in the upper portions of submarine canyons yield sediment samples of early Pleistocene ages, indicating the uppermost age of deposition of clinoform topsets exposed in the scarp walls. Partially consolidated, interbedded silty and sandy deposits of similar age outcrop in the thalweg of Leven canyon at a depth of 150 m. These sediments provide an upper age limit of the shelf-edge wedge of early Pleistocene, giving a sedimentation rate of this wedge of 162–309 m/Ma. The distribution of widespread basal-most Pleistocene sediments on the upper slope indicates that these sediments escaped major reworking during sea-level falls associated with Pleistocene glaciations and remain as relict upper slope veneers. The absence of more recent sediments suggests that this area has been a zone of sediment bypass or starvation since the early Pleistocene. Areas where younger sediments mantle deposits of early Pleistocene ages represent areas of offshore bedload parting, re-distributing younger Holocene sediment offshore and downslope.     

The timing of ultrahigh-temperature metamorphism in Southern India: U–Th–Pb electron microprobe ages from zircon and monazite in sapphirine-bearing granulites

We report here U–Pb electron microprobe ages from zircon and monazite associated with corundum- and sapphirine-bearing granulite facies rocks of Lachmanapatti, Sengal, Sakkarakkottai and Mettanganam in the Palghat–Cauvery shear zone system and Ganguvarpatti in the northern Madurai Block of southern India. Mineral assemblages and petrologic characteristics of granulite facies assemblages in all these localities indicate extreme crustal metamorphism under ultrahigh-temperature (UHT) conditions. Zircon cores from Lachmanapatti range from 3200 to 2300 Ma with a peak at 2420 Ma, while those from Mettanganam show 2300 Ma peak. Younger zircons with peak ages of 2100 and 830 Ma are displayed by the UHT granulites of Sengal and Ganguvarpatti, although detrital grains with 2000 Ma ages are also present. The Late Archaean-aged cores are mantled by variable rims of Palaeo- to Mesoproterozoic ages in most cases. Zircon cores from Ganguvarpatti range from 2279 to 749 Ma and are interpreted to reflect multiple age sources. The oldest cores are surrounded by Palaeoproterozoic and Mesoproterozoic rims, and finally mantled by Neoproterozoic overgrowths. In contrast, monazites from these localities define peak ages of between 550 and 520 Ma, with an exception of a peak at 590 Ma for the Lachmanapatti rocks. The outermost rims of monazite grains show spot ages in the range of 510–450 Ma.While the zircon populations in these rocks suggest multiple sources of Archaean and Palaeoproterozoic age, the monazite data are interpreted to date the timing of ultrahigh-temperature metamorphism in southern India as latest Neoproterozoic to Cambrian in both the Palghat–Cauvery shear zone system and the northern Madurai Block. The data illustrate the extent of Neoproterozoic/Cambrian metamorphism as India joined the Gondwana amalgam at the dawn of the Cambrian.     

Sulphur saturation in the lower and critical zones of the Eastern Bushveld Complex

A suite of ultramafic and mafic rocks from the lower, critical and lower portion of the main zones of the Bushveld Complex has been analysed for Th, Cs, Zr, Ni, Cr and Au by INAA and XRF spectrometry. The incompatible elements Th, Cs, and Zr correlate positively, and show a gradual upward increase in abundance. Assuming constant average proportion of intercumulus material, this upward increase implies that the zones of the Complex studied represent crystallization of a single magma type some 3600 m thick. Pyroxenites dominate the lower portion of the section studied and their Ni content shows an initial rapid decrease from 850 ppm in the lowermost rocks, to around 500 ppm, with considerable scatter. This distribution is most likely to have resulted from bottom crystallization with superimposed convective overturn near the transient floor of the chamber. Gold abundances are generally higher in chromitites, and correlate positively with Ni, indicating the presence of significant amounts of cumulus immiscible sulphide. In the silicate rocks, Au does not correlate with any of the analysed elements, and it is concluded that Au was trapped in small quantities of immiscible sulphide which precipitated continuously during crystallization. There is an upward increase in the amount of cumulus immiscible sulphide, indicating a progressive increase in sulphur solubility in the magma.