Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

A comparison of artificial solar granules with real solar granules

The lifetimes, characteristics of the shapes as well as lengths and perimeters of artificial solar granules (Nordlund, 1982, 1984a) are compared with data from the literature and parameters determined from two different sets of observed granules. No significant differences of the parameters for these sets of granules are detectable.Mitteilungen aus dem Kiepenheuer-Institut Nr. 251.     

Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

A focal plane detector design for a wide-band Laue-lens telescope

The energy range above 60 keV is important for the study of many open problems in high energy astrophysics such as the role of Inverse Compton with respect to synchrotron or thermal processes in GRBs, non thermal mechanisms in SNR, the study of the high energy cut-offs in AGN spectra, and the detection of nuclear and annihilation lines. Recently the development of high energy Laue lenses with broad energy bandpasses from 60 to 600keV have been proposed for a Hard X ray focusing Telescope (HAXTEL) in order to study the X-ray continuum of celestial sources. The required focal plane detector should have high detection efficiency over the entire operative range, a spatial resolution of about 1mm, an energy resolution of a few keV at 500keV and a sensitivity to linear polarization. We describe a possible configuration of the focal plane detector based on several CdTe/CZT pixelated layers stacked together to achieve the required detection efficiency at high energy. Each layer can operate both as a separate position sensitive detector and polarimeter or work with other layers to increase the overall photopeak efficiency. Each layer has a hexagonal shape in order to minimize the detector surface required to cover the lens field of view. The pixels would have the same geometry so as to provide the best coupling with the lens point spread function and to increase the symmetry for polarimetric studies.     

Spectrophotometric Variability of Mira

Data from the Pulkovo spectrophotometric data base on the absolute quasimonochromatic fluxes from oCet in the 320–1080 nm range are used to determine the physical parameters of this star in different phases of its light curve. The continuum emission layer is found to expand between the phases of the cycle corresponding to the rising and falling branches of the light curve. The average expansion velocity is 32 km/s. By the time the star’s brightness has fallen by roughly three magnitudes, its radius has increased by almost a factor of three. Over this same time the temperature of the layer has fallen from 3000 K to 2200 K. For this expansion velocity, the calculated mass rate loss is ⊙ M /year.__________Translated from Astrofizika, Vol. 48, No. 2, pp. 175–189 (May 2005).     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

The determination and analysis of the orbit of NIMBUS 1 ROCKET, 1964-52B: Part 2: Variations in orbital eccentricity

The influence of aerodynamic drag and the geopotential on the motion of the satellite 1964-52B is considered. A model of the atmosphere is adopted that allows for oblateness, and in which the density behaviour approximates to the observed diurnal variation. A differential equation governing the variation of the eccentricity, e, combining the effects of air drag with those of the Earth's gravitational field is given. This is solved numerically using as initial conditions 310 computed orbits of 1964-52B.The observed values of eccentricity are modified by the removal of perturbations due to luni-solar attraction, solid Earth and ocean tides, solar radiation pressure and low-order long-periodic tesseral harmonic perturbations. The method of removal of these effects is given in some detail. The behaviour of the orbital eccentricity predicted by the numerical solution is compared with the modified observed eccentricity to obtain values of atmospheric parameters at heights between 310 and 430 km. The daytime maximum of air density is found to be at 14.5 hours local time. Analysis of the eccentricity near 15th order resonance with the geopotential yielded values of four lumped geopotential harmonics of order 15, namely: $\text{10}{}^9\text{C}{}^{\mathrm{1,0}}{}_{15}\text{= ?78.8 ± 7.0}$, $\text{10}{}^9\text{S}{}^{\mathrm{1,0}}{}_{15}\text{= ?69.4 ± 5.3}$, $\text{10}{}^9\text{C}{}^{\mathrm{?1,2}}{}_{15}\text{= ?41.6 ± 3.5}$$\text{10}{}^9\text{S}{}^{\mathrm{?1,2}}{}_{15}\text{= ?26.1 ± 8.9}$, at inclination 98.68°.