Heavy metal contamination of cultivated wetland soils along a typical plateau lake from southwest China

Topsoil (0–20 cm) samples were collected from four cultivated wetlands including Northern and Western Fields (about 30-year tillage), and Southern and Western Fields (about 20-year tillage) along the Yilong Lake of China in October, 2005. Total concentrations of As, Cr, Cu, Pb, and Zn were determined using the inductively coupled plasma atomic absorption spectrometry in order to assess contamination status in four sampling plots. Results showed that the average concentrations of these heavy metals in Northern and Western Fields were significantly (P < 0.01) higher than those in reference soils, while they were generally lower in Southern and Eastern Fields. All the mean concentrations of heavy metals were lower, except that the average concentrations of As and Cr in Northern Field slightly exceeded the soil quality guidelines. The contamination indices showed low-contamination levels for As, Cu, Pb, and Zn in Northern and Western Fields, while no contamination levels could be observed in Southern and Eastern Fields. As for Cr, they showed moderate-contamination levels in Northern Field, but low or no contamination levels in other three Fields. The integrated contamination index values indicated Northern and Western Fields were moderately contaminated, while Southern and Eastern Fields were less contaminated. The same contamination sources of these heavy metals were identified in these fields using factor- and cluster analysis.     

Comparison of numerical models of two debris flows in the Cortina d’ Ampezzo area,Dolomites, Italy

The accurate prediction of runout distances, velocities and the knowledge of flow rheology can reduce the casualties and property damage produced by debris flows, providing a means to delineate hazard areas, to estimate hazard intensities for input into risk studies and to provide parameters for the design of protective measures. The application of most of models that describe the propagation and deposition of debris flow requires detailed topography, rheological and hydrological data that are not always available for the debris-flow hazard delineation and estimation. In the Cortina d’Ampezzo area, Eastern Dolomites, Italy, most of the slope instabilities are represented by debris flows; 325 debris-flow prone watersheds have been mapped in the geomorphological hazard map of this area. We compared the results of simulations of two well-documented debris flows in the Cortina d’Ampezzo area, carried on with two different single-phase, non-Newtonian models, the one-dimensional DAN-W and the two-dimensional FLO-2D, to test the possibility to simulate the dynamic behaviour of a debris flow with a model using a limited range of input parameters. FLO-2D model creates a more accurate representation of the hazard area in terms of flooded area, but the results in terms of runout distances and deposits thickness are similar to DAN-W results. Using DAN-W, the most appropriate rheology to describe the debris-flow behaviour is the Voellmy model. When detailed topographical, rheological and hydrological data are not available, DAN-W, which requires less detailed data, is a valuable tool to predict debris-flow hazard. Parameters obtained through back-analysis with both models can be applied to predict hazard in other areas characterized by similar geology, morphology and climate.     

Extraction of Alteration Mineral Information from Moderate Remote Sensing Images Using MPS Method

Although alteration minerals related to metallogenesis is very important in mineral exploration, information of alteration mineral is weakly expressed in remote sensing imagery, which is often subject to interfering noise and sometimes limited in spectral and spatial resolutions. Because of easy access, moderate images are the main sources of alteration mineral information. Therefore, it is very important to develop alteration mineral information extraction methods from remote sensing images. In this paper, a combined method based on Mask, principal component analysis (PCA) and support vector machine method (SVM) was used to extract alteration mineral information from Enhanced thematic mapper plus remote sensing data with limited spectral and spatial resolutions. First, a mask image of the remote sensing imagery was created to remove interference information such as vegetation, shadow and water. Then, PCA was employed to collect sample data relating to iron, argillic, and carbonatization alteration. Finally, SVM was used to deal with alteration anomaly and build a feature extraction model of high accuracy. The Mask-PCA-SVM model is used to extract alteration mineral information from remote sensing images of Hatu area, Xinjiang Uygur Autonomous Regions, China. The results show that the new methods proposed in this paper can coincide well with known deposits occurrences, rate reached 86.51%. While, the consistent rate with known deposits of the ratio model, PCA model and Spectral angle mapper model were only 3.37, 65.08 and 69.05% respectively. This suggests that the proposed model can find the actual distribution of mineral deposits more effectively by reducing interference to a greater degree.     

Cosmic ray ionization of the Jovian atmosphere

An approximate form of the Boltzmann equation has been used to obtain local ionization rates due to the absorption of galactic cosmic rays in the Jovian atmosphere. It is shown that the muon flux component of the cosmic ray-induced cascade may be especially importannt in ionizing the atmosphere at levels where the total number density exceeds 10¹⁹ cm^?3 (well below the ionospheric layers produced by solar euv). A model containing both positive and negative ion reactions has been employed to compute equilibrium electron and ion number densities. Peak electron number densities on the order of 10³ cm^?3 may be expected even at relatively low magnetic latitudes. The dominant positive ions are NH₄⁺ and C_nH_m⁺ cluster ions, with n ? 2; it is suggested that the absorption of galactic cosmic ray energy at such relatively high pressures in the Jovian atmosphere $\text{(M ? 10}{}^{18}\text{to}\text{10}{}^{20}\text{cm}{}^{\mathrm{?3}}\text{)}$ and the subsequent chemical reactions may be instrumental in the local formation of complex hydrocarbons.     

Water and salt balance modelling to predict the effects of land-use changes in forested catchments. 1. Small catchment water balance model

A long-term water balance model has been developed to predict the hydrological effects of land-use change (especially forest clearing) in small experimental catchments in the south-west of Western Australia. This small catchment model has been used as the building block for the development of a large catchment-scale model, and has also formed the basis for a coupled water and salt balance model, developed to predict the changes in stream salinity resulting from land-use and climate change. The application of the coupled salt and water balance model to predict stream salinities in two small experimental catchments, and the application of the large catchment-scale model to predict changes in water yield in a medium-sized catchment that is being mined for bauxite, are presented in Parts 2 and 3, respectively, of this series of papers. The small catchment model has been designed as a simple, robust, conceptually based model of the basic daily water balance fluxes in forested catchments. The responses of the catchment to rainfall and pan evaporation are conceptualized in terms of three interdependent subsurface stores A, B and F. Store A depicts a near-stream perched aquifer system; B represents a deeper, permanent groundwater system; and F is an intermediate, unsaturated infiltration store. The responses of these stores are characterized by a set of constitutive relations which involves a number of conceptual parameters. These parameters are estimated by calibration by comparing observed and predicted runoff. The model has performed very well in simulations carried out on Salmon and Wights, two small experimental catchments in the Collie River basin in south-west Western Australia. The results from the application of the model to these small catchments are presented in this paper.     

Meridional Motion and Reynolds Stress from Debrecen Photoheliographic Data

The Debrecen Photoheliographic Data catalogue is a continuation of the Greenwich Photoheliographic Results providing daily positions of sunspots and sunspot groups. We analyse the data for sunspot groups focussing on meridional motions and transfer of angular momentum towards the solar equator. Velocities are calculated with a daily shift method including an automatic iterative process of removing the outliers. Apart from the standard differential rotation profile, we find meridional motion directed towards the zone of solar activity. The difference in measured meridional flow in comparison to Doppler measurements and some other tracer measurements is interpreted as a consequence of different flow patterns inside and outside of active regions. We also find a statistically significant dependence of meridional motion on rotation velocity residuals confirming the transfer of angular momentum towards the equator. Analysis of horizontal Reynolds stress reveals that the transfer of angular momentum is stronger with increasing latitude up to about \(40^{\circ}\), where there is a possible maximum in absolute value.     

Recent increase of river–floodplain suspended sediment exchange in a reach of the lower Amazon River

We analyzed variation of channel–floodplain suspended sediment exchange along a 140 km reach of the lower Amazon River for two decades (1995–2014). Daily sediment fluxes were determined by combining measured and estimated surface sediment concentrations with river–floodplain water exchanges computed with a two‐dimensional hydraulic model. The average annual inflow to the floodplain was 4088 ± 2017 Gg yr^?1 and the outflow was 2251 ± 471 Gg yr^?1, respectively. Prediction of average sediment accretion rate was twice the estimate from a previous study of this same reach and more than an order of magnitude lower than an estimate from an earlier regional scale study. The amount of water routed through the floodplain, which is sensitive to levee topography and increases exponentially with river discharge, was the main factor controlling the variation in total annual sediment inflow. Besides floodplain routing, the total annual sediment export depended on the increase in sediment concentration in lakes during floodplain drainage. The recent increasing amplitude of the Amazon River annual flood over two decades has caused a substantial shift in water and sediment river–floodplain exchanges. In the second decade (2005–2014), as the frequency of extreme floods increased, annual sediment inflow increased by 81% and net storage increased by 317% in relation to the previous decade (1995–2004). Copyright © 2017 John Wiley & Sons, Ltd.     

Growth of large sulfide structures on the endeavour segment of the Juan de Fuca ridge

Mapping and sampling with DSRV “Alvin” has established that sulfide blocks 0.5 m across, dredged from the axial valley of the Endeavour Segment at 47°57′N, are samples of unusually large sulfide structures. The steep-sided structures, up to 30 m in length, 20 m in height, and 10–15 m across, are localized by venting along normal faults at the base of the western axial valley wall, and are distributed for about 200 m along strike paralleling the 020 trend of the ridge crest. High-temperature fluids (350 to more than 400°C) pass through the massive sulfide structures and enter seawater through small, concentric “nozzle-like” features projecting from the top or the sides of the larger vent structures. Diffuse, low-temperature flow is pervasive in the vicinity of the active sulfide structures, exiting from basalt and sulfide surfaces alike. Evidence of recent volcanic activity is sparse.The two largest samples taken with the dredge would not have been recoverable using the submersible. These samples represent massive, complex portions of the sulfide structures which were not closely associated with rapid high-temperature fluid flow at the time of sampling; they contain textural evidence of sealed hydrothermal fluid exit channels. Mineralogy is dominated by Fe sulfides nnd amorphous silica. Pyrite, marcasite, wurtzite, chalcopyrite, and iss are the most common sulfide phases. Pyrrhotite, galena, and sphalerite are present in trace amounts. Barite, amorphous silica, and chalcedony are the only non-sulfide phases; anhydrite is not observed in any of the dredge samples, although it is common in the chimney-like samples recovered by “Alvin”.Specific mineralogical-textural zones within the dredge samples are anaoogous to individual layers in East Pacific Rise at 21°N and southern Juan de Fuca Ridge samples, with two exceptions: a coarse-grained, highly porous Fe sulfide-rich interior containing sulfidized tubeworm casts, and a 2–5 cm thick zone near the outer margin of the samples dominated by late stage amorphous silica. The porous interior may have formed by dendritic crystal growth from a slowly circulating fluid within a large enclosed chamber. The amorphous silica deposited from a seawater/hydrothermal fluid mixture percolating slowly through the walls of the enclosed chamber; conductive cooling of the fluid as it traversed the walls allowed amorphous silica to precipitate. These silica-rich zones are the densest, most durable portions of the structures and may be responsible for the lasting stability of the large sulfide features.Observations in these samples are consistent with two distinct phases of development. Phase 1 is analogous to chimney growth and construction at 21°N and ends when flow channels become sealed to rapid flow of through-going fluid. The flow is evidently redirected within the structure. Phase 2 includes dissolution of anhydrite and precipitation of amorphous silica during conductive cooling of sluggishly circulating hydrothermal fluid or seawater/hydrothermal fluid mixtures. Evolution of vent structures through phase 2 allows lateral and vertical growth of unusually large structures.     

Land surface coupling in regional climate simulations of the West African monsoon

Coupling of the Community Land Model (CLM3) to the ICTP Regional Climate Model (RegCM3) substantially improves the simulation of mean climate over West Africa relative to an older version of RegCM3 coupled to the Biosphere Atmosphere Transfer Scheme (BATS). Two 10-year simulations (1992–2001) show that the seasonal timing and magnitude of mean monsoon precipitation more closely match observations when the new land surface scheme is implemented. Specifically, RegCM3–CLM3 improves the timing of the monsoon advance and retreat across the Guinean Coast, and reduces a positive precipitation bias in the Sahel and Northern Africa. As a result, simulated temperatures are higher, thereby reducing the negative temperature bias found in the Guinean Coast and Sahel in RegCM3–BATS. In the RegCM3–BATS simulation, warmer temperatures in northern latitudes and wetter soils near the coast create excessively strong temperature and moist static energy gradients, which shifts the African Easterly Jet further north than observed. In the RegCM3–CLM3 simulation, the migration and position of the African Easterly Jet more closely match reanalysis winds. This improvement is triggered by drier soil conditions in the RegCM3–CLM3 simulation and an increase in evapotranspiration per unit precipitation. These results indicate that atmosphere–land surface coupling has the ability to impact regional-scale circulation and precipitation in regions exhibiting strong hydroclimatic gradients.     

Altitudinal trends in δ<Superscript>13</Superscript>C value,stomatal density and nitrogen content of <Emphasis Type="Italic">Pinus tabuliformis</Emphasis> needles on the southern slope of the middle Qinling Mountains,China

In this study, a coniferous tree species (Pinus tabuliformis Carr.) was investigated at a moderate-altitude mountainous terrain on the southern slope of the middle Qinling Mountains (QLM) to detect the trends in carbon isotope ratio (δ¹³C), leaf nitrogen content (LNC) and stomatal density (SD) with altitude variation in north-subtropical humid mountain climate zone of China. The results showed that LNC and SD both significantly increased linearly along the altitudinal gradient ranging from 1000 to 2200 m, whereas leaf δ¹³C exhibited a significantly negative correlation with the altitude. Such a correlation pattern differs obviously from that obtained in offshore low-altitude humid environment or inland high-altitude semi-arid environment, suggesting that the pattern of increasing δ¹³C with the altitude cannot be generalized. The negative correlation between δ¹³C and altitude might be attributed mainly to the strengthening of carbon isotope fractionation in plants caused by increasing precipitation with altitude. Furthermore, there was a remarkable negative correlation between leaf δ¹³C and LNC. One possible reason was that increasing precipitation that operates to increase isotopic discrimination with altitude overtook the LNC in determining the sign of leaf δ¹³C. The significant negative correlation between leaf δ¹³C and SD over altitudes was also found in the present study, indicating that increases in SD with altitude would reduce, rather than enhance plant δ¹³C values.