Petrochemistry of Jurassic and Cretaceous tholeiites from Kong Karls Land, Svalbard, and their relation to Mesozoic magmatism in the Arctic

A study of the whole-rock geochemistry and mineral chemistry of high-TiO₂ Upper Jurassic and medium-TiO₂ Lower Cretaceous basalts from Kong Karls Land, Svalbard, is presented. Geochemical criteria indicate that the basalts are initial rifting tholeiites with weak signs of crustal contamination. The Upper Jurassic basalts appear to be associated with the Olga Rift, part of a trans-Barents rift system which failed to link the proto-Atlantic and proto-Arctic basins. The Lower Cretaceous basalts may be more closely related to initial rifting tholeiites on Franz Josef Land and Spitsbergen generated during the rifting stage of opening of the Canada Basin. During break-up of the Barents Shelf, the sequence of magma types corresponds to the pre-, syn- and post-rifting stages established in other areas of continental break-up. Evidence for a possible hot-spot or plume trail, extending from Siberia to the Yermak Plateau over 250 Ma, is assembled.     

Multifractal analysis of the spatial distribution of earthquakes in southern Italy

We evaluate the complete spectrum of the generalized fractal dimension of the spatial pattern of microearthquakes in Southern Italy, revealing a multifractal distribution structure. Our analysis is focused on the dependence of the multifractal distribution on the size of the selected area and the kind of seismicity in the area. As the size of the window varies, we observe that the capacity, information and correlation dimensions vary significantly, while both d _∞ and d _−infin; remain unchanged within their errors limits. We interpret this result in terms of the observation that our data are mainly clustered around a linear fault (the Sisifo fault). When we restrict the selected windows around the fault, clustering around a line (the fault) is highlighted. The capacity dimension changes from about 1.8 to about 1.4 and the correlation dimension decreases because we observe in detail the clustering of the seismicity along the fault, which approximates the maximum intense clustering of the whole data set. Although our results are strongly influenced by the fact that the data are dominated by the epicentres located on the fault, we can conclude that multifractal analysis can be a very useful tool to discriminate the seismicity linked to a particular fault in a given area.     

Responses of interrill runoff and erosion rates to vegetation change in southern Arizona

Vegetation change, fi-om grassland to shrubland, has occurred over much of the Sonoran and Chihuahuan Deserts during the past century. The effect of this vegetation change on interrill runoff and erosion was examined by conducting rainfall-simulation experiments on large runoff plots on contemporary grassland and shrubland hillslopes. These experiments show that, compared to the grassland, the interrill portions of shrubland hillslopes (1) have higher runoff rates, (2) experience equilibrium runoff conditions much more frequently, (3) exhibit higher overland flow velocities, and (4) are subject to greater rates of erosion. The environmental change that has led to the vegetation change has been relatively minor, but its geomorphic impact has been substantial.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.     

A modern vision: Eric Lindsay at Armagh

Eric Mervyn Lindsay masterminded the development of Armagh Observatory in the middle of the 20th century, building it into the centre for research and education that it is today. John McFarland recounts Lindsay's story, of how one man's drive and ambition forged international collaborations that presaged today's world of shared research facilities     

Isotopic order, biogeochemical processes, and earth history: Goldschmidt lecture, Davos, Switzerland, August 2002

The impetus to interpret carbon isotopic signals comes from an understanding of isotopic fractionations imposed by living organisms. That understanding rests in turn on studies of enzymatic isotope effects, on fruitful concepts of isotopic order, and on studies of the distribution of ¹³C both between and within biosynthetic products. In sum, these studies have shown that the isotopic compositions of biological products are governed by reaction kinetics and by pathways of carbon flow.Isotopic compositions of individual compounds can indicate specific processes or environments. Examples include biomarkers which record the isotopic compositions of primary products in aquatic communities, which indicate that certain bacteria have used methane as a carbon source, and which show that some portions of marine photic zones have been anaerobic. In such studies, the combination of structural and isotopic lines of evidence reveals relationships between compounds and leads to process-related thinking. These are large steps. Reconstruction of the sources and histories of molecular fossils redeems much of the early promise of organic geochemistry by resolving and clarifying paleoenviron-mental signals. In turn, contemplation of this new information is driving geochemists to study microbial ecology and evolution, oceanography, and sedimentology.