Stable Isotope Investigations on the Granulite Facies Terrains of Brazil: A Review

Stable isotope data from three areas in the granulite facies terrains of Brazil are assembled and discussed. All the three areas (Jequié, Guaxupé and São José do Rio Pardo) are from the São Francisco Craton. The carbon isotope composition of the fluid inclusion CO₂ in the Archean granulite terrain of Jequié indicate the participation of two distinct sources, an upper mantle source and an internal source of Archean organic matter. The isotope data may be interpreted in terms of the granulite genesis due to the intrusion of magma in the lower crust. The singularly uniform carbon isotope data for CO₂ fluid inclusion of plutonic granulites is a clear indication of the magmatic addition of CO₂-rich volatiles from deeper crustal sources. In the São José do Rio Pardo area sulfur and carbon isotope data of scapolites from the granulites imply the derivation of volatiles from internal sources. The whole rock oxygen isotope data of the amphibolite and granulite facies gneisses from Guaxupé indicate a small scale variation of d¹⁸O values, compatible with the chemical data, suggesting the preservation of pre-metamorphic oxygen isotope composition. The isotope data of the granulites from São Francisco Craton indicate non-pervasive fluid flow during metamorphism.     

Ammonium,nitrate and phytoplankton interactions in a freshwater tidal estuarine zone: potential effects of cultural eutrophication

Nitrate and ammonium are the most important nitrogen sources for phytoplankton growth. Differential utilization of inorganic nitrogenous compounds by phytoplankton has been observed and may have significant impacts on primary productivity at local scales. We used enrichment experiments with natural phytoplankton populations from the freshwater tidal zone of the Guadiana estuary, a coastal ecosystem increasingly subjected to anthropogenic influences, to study the effects of nitrate and ammonium on N-consumption and phytoplankton growth. In addition, we used combined additions of nitrate and ammonium to understand the inhibitory effect of ammonium over nitrate uptake. Ammonium concentrations in the freshwater tidal reaches of the Guadiana estuary throughout the sampling period were too low to exert an inhibitory effect on nitrate uptake or a toxic effect on phytoplankton growth. Nitrate was clearly the main nitrogen source for phytoplankton at the study site. Overall, nitrate seemed to become limiting at concentrations lower than 20 μM and N-limitation was particularly significant during summer. A trend of decreasing nitrate uptake with increasing ammonium concentrations and uptake suggested an overall preference for ammonium. However, preference for ammonium was group-specific, and it was observed mainly in green algae and cyanobacteria. In fact, cyanobacteria relied only on ammonium as their N-source. On the contrary, diatoms preferred nitrate, and did not respond to ammonium additions. The increasing eutrophication in the Guadiana estuary and particularly increased inputs of nitrogen as ammonium due to urban waste effluents may result in a shift in phytoplankton community composition, towards a dominance of cyanobacteria and green algae.     

An Environmental Threshold of Soil Test P and Degree of P Saturation of Brazilian Oxisols

To develop P management guidelines for poultry litter application in Oxisols of Brazil, the relationship between water soluble P (WSP), soil test P (STP), and degree of P saturation (DPS) needs to be established. The study examined this relationship in Oxisols of Brazil receiving poultry litter. Soils were analyzed for Mehlich‐1 P (M1‐P), WSP, P fractions, P sorption index (PSI), and P saturation based on Mehlich‐1 extractable P, Al, Fe (DPS_M1), and PSI (DPS_PSI). Surface water bodies in the catchment area were examined for inorganic and total P. All the surface water bodies in the catchment area of the sampled plots were highly enriched in inorganic and organic P. Enrichment of soil P fractions following poultry litter application followed the order HCl‐bound > NaOH‐bound > NaHCO₃‐bound fraction. M1‐P was correlated to labile (NaHCO₃‐P_i), and stable P pools (NaOH‐P and HCl‐P) and reflected the cumulative P accumulation in these soils. P saturation indices increased with cumulative P addition and increasing M1‐P. WSP increased with increasing DPS and a change point was noticed at 23% DPS_PSI (equivalent to DPS_M1 of 16.5%) corresponding to M1‐P of 44.5 mg P kg^?1, which could be regarded as threshold for P loss in these soils.     

Site evaluation and RFI spectrum measurements in Portugal at the frequency range 0.408–10 GHz for a GEM polarized galactic radio emission experiment

We probed for radio frequency interference (RFI) at three potential galactic emission mapping experiment (GEM) sites in Portugal using custom made omnidirectional disconic antennas and directional pyramidal horn antennas. For the installation of a 10-m dish dedicated to the mapping of polarized galactic emission foreground planned for 2005–2007 in the 5–10 GHz band, the three sites chosen as suitable to host the antenna were surveyed for local radio pollution in the frequency range 0.01–10 GHz. Tests were done to look for radio broadcasting and mobile phone emission lines in the radio spectrum. The results show one of the sites to be almost entirely RFI clean and showing good conditions to host the experiment.     

Analysis of the 1 November 2015 heavy rainfall episode in Algarve by using weather radar and rain gauge data

The trigger for the study presented in this paper was the extreme rain event of 1 November 2015 in Algarve region. The main objective was the analysis and improvement of the precipitation field using a radar–rain gauge merging method. Ordinary kriging with radar-based error correction has been applied to hourly values of precipitation from both sensors. The merging technique allowed keeping the better radar spatial pattern, being the respective estimates corrected by the rain gauges observations. The procedure led to a reduction in the errors of the precipitation estimates, evaluated by cross-validation, when compared to univariate interpolation of rain gauge observation or radar rain product. Finally, some discussion is also added on the problematic of flooding in urban areas, especially those with absent or deficient urban planning.     

Standardization of a NaI(Tl) scintillation detector and its use on environments for Geology teaching in a Brazilian university

This paper describes analytical protocols adopted for calibrating a portable gamma rays spectrometer using a 2? × 2? NaI(Tl) scintillation detector for performing exploration and environmental surveys. The steps involved the determination of counting times with good accuracy, calibration in energy and concentration, and data conversion to effective dose (Ed) for monitoring the radioactivity levels in the air, for indoor and outdoor environments. The χ² test was applied to the counting rate data acquired for ten different readings, allowing determine the greater accuracy among them. Some standards yielded values above of the detection limit for calibrating the K, eU, and eTh windows, whereas empirical equations provided satisfactory results. The count rates in these windows were obtained in selected environments related to Geology teaching activities in a Brazilian university. Then, they were converted to Ed, showing the applicability of the adopted procedures for environmental surveys. The radiological monitoring showed two sites exhibiting Ed values above the WHO guideline reference value of 1 mSv/year. The first was in a minerals and rocks museum and the second in a deposit (litoteca) dedicated to the rocks storage. Thus, the members of the public are only occasionally exposed to the natural gamma radiation there. Additionally, the Ed values are much lower than the recommended limit of 20 mSv/year for occupationally exposed individuals.