Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.     

Subduction,mega-shear systems and Late Palaeozoic basin development in the African segment of Gondwana

 Basins within the African sector of Gondwana contain a Late Palaeozoic to Early Mesozoic Gondwana sequence unconformably overlying Precambrian basement in the interior and mid-Palaeozoic strata along the palaeo-Pacific margin. Small sea-board Pacific basins form an exception in having a Carboniferous to Early Permian fill overlying Devonian metasediments and intrusives. The Late Palaeozoic geographic and tectonic changes in the region followed four well-defined consecutive events which can also be traced outside the study area. During the Late Devonian to Early Carboniferous period (up to 330 Ma) accretion of microplates along the Patagonian margin of Gondwana resulted in the evolution of the Pacific basins. Thermal uplift of the Gondwana crust and extensive erosion causing a break in the stratigraphic record characterised the period between 300 and 330 Ma. At the end of this period the Gondwana Ice Sheet was well established over the uplands. The period 260–300 Ma evidenced the release of the Gondwana heat and thermal subsidence caused widespread basin formation. Late Carboniferous transpressive strike-slip basins (e.g. Sierra Australes/Colorado, Karoo-Falklands, Ellsworth-Central Transantarctic Mountains) in which thick glacial deposits accumulated, formed inboard of the palaeo-Pacific margin. In the continental interior the formation of Zambesi-type rift and extensional strike-slip basins were controlled by large mega-shear systems, whereas rare intracratonic thermal subsidence basins formed locally. In the Late Permian the tectonic regime changed to compressional largely due to northwest-directed subduction along the palaeo-Pacific margin. The orogenic cycle between 240 and 260 Ma resulted in the formation of the Gondwana fold belt and overall north–south crustal shortening with strike-slip motions and regional uplift within the interior. The Gondwana fold belt developed along a probable weak crustal zone wedged in between the cratons and an overthickened marginal crustal belt subject to dextral transpressive motions. Associated with the orogenic cycle was the formation of mega-shear systems one of which (Falklands-East Africa-Tethys shear) split the supercontinent in the Permo-Triassic into a West and an East Gondwana. By a slight clockwise rotation of East Gondwana a supradetachment basin formed along the Tethyan margin and northward displacement of Madagascar, West Falkland and the Gondwana fold belt occurred relative to a southward motion of Africa. Received: 2 October 1995 / Accepted: 28 May 1996     

Whole-rock and sulfide lead-isotope data from the hydrothermal JADE field in the Okinawa back-arc trough

The mineralization of the active hydrothermal JADE field resembles in many aspects the Kuroko-type mineralization. The JADE field is located in a back-arc graben and is associated with a bimodal volcanism. Lead isotope data from igneous rocks, sediments, and ores further emphasize the similarities with the Kuroko ores and suggest that both sediments and volcanic rocks contributed comparable amounts of lead to the deposit. When compared to the sediments, a much larger volume of volcanic rocks must have contributed lead to the deposit, because of the considerably lower lead concentration of volcanic rocks. In contrast to the crustal type lead of the JADE field and the Kuroko-type sulfide deposits the lead isotope signatures of VMS-type deposits at mid-ocean ridges is distinctly different. In the absence of a sedimentary cover it reflects the composition of the mantle source, whereas in the presence of a sedimentary cover it is either a mixture of mantle and sedimentary lead or it may even be completely dominated by the latter. Received: 5 October 1995 / Accepted: 10 May 1996     

Ophiolite remnants at the eastern margin of the Bohemian Massif and their bearing on the tectonic evolution

Summary Amphibolites are widespread in the eastern part of the Bohemian Massif, east of the South Bohemian Pluton. Based on their geological situation, their metamorphic evolution and their geochemistry, they were separated into three genetically different units: the Rehberg ophiolite, the Buschandlwand amphibolite and the Raabs group. The metamorphic Rehberg ophiolite consists of a ultramafic to mafic plutonic sequence overlain by a gabbro/dike complex and a volcanic section with basaltic, andesitic and rhyolitic volcanics associated with pelitic to psammitic sediments. The entire ophiolite underwent amphibolite facies metamorphism. Rock/MORB normalisation plots and other element ratio plots, such as Ti vs. V or Ta/Yb vs. Th/Yb argue for a supra-subduction zone environment as site of the origin of the Rehberg ophiolite. The Letovice ophiolite in Moravia is structured in a similar way. Geochemically it shows a more MORB like composition but also a distinct tholeiitic island arc group. Although there is no age data for the protolith of both ophiolites, it is believed that they have formed in an oceanic basin separating the Brunovistulian-Moravian block to the east and the Moldanubian block to the west. Possible traces of the continuation of the ophiolites towards the north can be found in the Stare Mesto ophiolites and the ophiolites surrounding the Sowie Gory block in the Sudetes.

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Ophiolitrelikte am ostrand der Böhmischen Masse und ihre bedeutung für die tektonische entwicklung

Zusammenfassung Amphibolite sind in der Böhmischen Masse, östlich des Südböhmischen Plutons weit verbreitet. Ausgehend von ihrer geologischen Position, ihrer metamorphen Entwick lung und ihrer Geochemie lassen sie sich in drei genetisch unterschiedliche Einheiten teilen: den Rehberg Ophiolith, den Buschandlwand Amphibolit und die Raabser Gruppe. Der metamorphe Rehberg Ophiolith besteht aus einer ultramatischen bis mafischen plutonischen Abfolge, die von einem Gabbro/Gangkomplex überlagert wird und einer vulkanischen Folge mit Basalten, Andesiten and Rhyoliten, die mit tonigen und sandigen Sedimenten verknüpft sind. Der gesamte Ophiolithkörper wurde unter amphibolitfaziellen Bedingungen metamorph überprägt. Rock/MORB Diagramme und andere Elementdarstellungen, wie z.B. das Ti vs. V, oder das Ta/Yb vs. Th/Yb Diagramm sprechen für eine Entstehung des Rehberg Ophioliths in einer Suprasubduction Zone. Der Letovice Ophiolith in Mähren weist eine ähnliche Struktur auf. Geochemisch zeigt er stärkere Ähnlichkeiten mit MORB, enthält aber auch Elemente von tholeiitischen Inselbogenbasalten. Auch wenn es für beide Ophiolithe noch keine Protolith-Altersdaten gibt, scheint es dennoch wahrscheinlich, daß sie in einem Ozeanbecken, das den Brunovistulisch-Moravischen Kontinentalblock im Osten vom Moldanubischen Kontinent im Westen trennt, gebildet wurden. Die mögliche Fortsetzung beider Ophiolithe könnten im Norden der Stare Mesto Ophiolith und die Ophiolithe rund um den Sowie Gory Block in den Sudeten darstellen.

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With 7 Figures     

Evolution of the northeastern Kaapvaal craton and the central Limpopo belt,South Africa,based on single-zircon ages (extended abstract)

Geologie en Mijnbouw -     

Accretion and exhumation at a Variscan active margin, recorded in the Saxothuringian flysch

The Saxothuringian flysch basin, on the north flank of the Central European Variscides, was fed and eventually overthrust by the northwestern, active margin of the Tepla-Barrandian terrane. Clast spectra, mineral composition and isotopic ages of detrital mica and zircon have been analyzed in order to constrain accretion and exhumation of rocks in the orogenic wedge. The earliest clastic sediments preserved are of early Famennian age (ca. 370?Ma). They are exposed immediately to the NW of the suture, and belong to the par-autochthon of the foreland. Besides ultramafic (?ophiolite) material, these rocks contain clasts derived from Early Paleozoic continental slope sediments, originally deposited at the NW margin of the Saxothuringian basin. These findings, together with the paleogeographic position of the Famennian clastics debris on the northwestern passive margin, indicate that the Saxothuringian narrow ocean had been closed by that time. Microprobe analyses of detrital hornblendes suggest derivation from the “Randamphibolit” unit, now present in the middle part of the Saxothuringian allochthon (Münchberg nappes). Detrital zircons of metamorphic rocks formed a little earlier (ca. 380?Ma) indicate rapid recycling at the tectonic front. The middle part of the flysch sequence (ca. early to middle Viséan), both in the par-autochthon and in the allochthon, contains abundant clasts of Paleozoic rocks derived from the northwestern slope and rise, together with debris of Cadomian basement, 500-Ma granitoids and 380?Ma (early Variscan) crystalline rocks. All of these source rocks were still available in the youngest part of the flysch (c. middle to late Viséan), but some clasts record, in addition, accretion of the northwestern shelf. Our findings permit deduction of minimum rates of tectonic shortening well in excess of 10–30?mm per year, and rates of exhumation of ca. 3?mm/a, and possibly more.     

Global modelling study (GSM TIP) of the ionospheric effects of excited N2, convection and heat fluxes by comparison with EISCAT and satellite data for 31 July 1990

Near-earth plasma parameters were calculated using a global numerical self-consistent and time-dependent model of the thermosphere, ionosphere and protonosphere (GSM TIP). The model results are compared with experimental data of different origin, mainly EISCAT measurements and simultaneous satellite data (N_e and ion composition). Model runs with varying inputs of auroral FAC distributions, temperature of vibrationally excited nitrogen and photoelectron energy escape fluxes are used to make adjustments to the observations. The satellite data are obtained onboard Active and its subsatellite Magion –2 when they passed nearby the EISCAT station around 0325 and 1540 UT on 31 July 1990 at a height of about 2000 and 2200 km, respectively. A strong geomagnetic disturbance was observed two days before the period under study. Numerical calculations were performed with consideration of vibrationally excited nitrogen molecules for high solar-activity conditions. The results show good agreement between the incoherent-scatter radar measurements (N_e, T_e, T_i) and model calculations, taking into account the excited molecular nitrogen reaction rates. The comparison of model results of the thermospheric neutral wind shows finally a good agreement with the HWM93 empirical wind model.     

Assessment of Lichen Vitality During a Transplantation Experiment to a Polluted Site

The present work evaluates the stress effects in two epiphytic lichen species with different thallus morphology, the foliose Parmelia caperata and the fruticose Evernia prunastri, as resulting from transplanting from an unpolluted to an air-polluted area. Lichen samples were collected in Portugal in a clean area, during the spring 2003, and transplanted (1) to the same zone nearby and (2) to a polluted area as affected by an industrial complex. Transplant samples were taken periodically during four months in both places. At the same time lichen samples from the clean-air site native (in-situ) populations were also collected. For each sample were measured the chlorophyll content, the chlorophyll degradation and the cell membrane damage, the latter represented by leacheate conductivity. During the experiment the meteorological conditions were registered. The results indicate the absence of stress effects of transplanting as such, and suggest that leachate conductivity may be the more sensitive indicator of general lichen vitality.