Carbon isotope fractionation between calcite,graphite and CO2: an experimental study

The partitioning of stable carbon isotopes between calcite, graphite and CO₂ was experimentally determined at temperatures from 500 to 1200 °C and 1 to 15 kbar pressure. Attainment of carbon isotope equilibrium in CO₂-calcite runs was proven by achieving the same fractionation from isotopically opposite directions. The resultant CO₂-calcite fractionation curve for carbon differs from Bottinga's calculation by 1.2 and confirms recent experiments of Chacko et al. and Mattey et al. In CO₂-graphite experiments equilibrium fractions were extrapolated by applying the partial-exchange technique of Northrop and Clayton and by optimizing the contribution of surface reaction in graphite. CO₂-graphite fractionations at temperatures up to 800 °C are in fair agreement with Bottinga's calculation, but yield a surprisingly high fractionation of 5 at upper mantle temperatures. The combination of CO₂-calcite (carbon) and CO₂-graphite fractionation results in a new experimentally determined calcite-grapite fractionation curve, expressed by the equation:

The first rotation periods in Praesepe

The cluster Praesepe (age ∼650 Myr) is an ideal laboratory to study stellar evolution. Specifically, it allows us to trace the long-term decline of rotation and activity on the main sequence. Here, we present rotation periods measured for five stars in Praesepe with masses of 0.1–0.5 M_⊙– the first rotation periods for members of this cluster. Photometric periodicities were found from two extensive monitoring campaigns, and are confirmed by multiple independent test procedures. We attribute these variations to magnetic spots co-rotating with the objects, thus indicating the rotation period. The five periods, ranging from 5 to 84 h, show a clear positive correlation with object mass, a trend which has been reported previously in younger clusters. When comparing with data for F–K stars in the coeval Hyades, we find a dramatic drop in the periods at spectral type K8–M2 (corresponding to 0.4–0.6 M_⊙). A comparison with periods of very low mass (VLM) stars in younger clusters provides a constraint on the spin-down time-scale: we find that the exponential rotational braking time-scale is clearly longer than 200 Myr, most likely 400–800 Myr. These results are not affected by the small sample size in the rotation periods in Praesepe. Both findings, the steep drop in the period–mass relation and the long spin-down time-scale, indicate a substantial change in the angular momentum loss mechanism for VLM objects, possibly the breakdown of the solar-type (Skumanich) rotational braking. While the physical origin for this behaviour is unclear, we argue that parts of it might be explained by the disappearance of the radiative core and the resulting breakdown of an interface-type dynamo in the VLM regime. Rotational studies in this mass range hold great potential to probe magnetic properties and interior structure of main-sequence stars.     

Facies architecture and sedimentology of a meandering fluvial system: a Palaeogene example from the Weisselster Basin, Germany

The Schleenhain open pit coal mine, located 30 km south of Leipzig, Germany, exposes Upper Eocene and Oligocene non-marine strata representing fluvial deposition in the centre of the Weisselster Basin. Active mining and successive cuts provided the rare opportunity to obtain a three-dimensional perspective of laterally extensive surface outcrops. These were used to construct a detailed fence diagram, which provided the basis for recognition of key architectural elements in the weakly consolidated meandering stream deposits. In addition to the eight basic architectural elements of Miall (1985 ), the element SL (shallow lake deposits) was newly defined and the element CH (channel) was subdivided into CHg (palaeo-river system) and CHk (small channel). The profiles contain parts of two fining-upward cycles, which are separated by an unconformity spanning the Early Oligocene. Deposits of the first cycle begin with transverse sand bars (downstream accretion deposits-DA) and point bars (lateral accretion deposits-LA). The upper part of the cycle is represented by overbank fines (OF) and the element SL, which consists of laterally discontinuous lenses of dark, plant-bearing, kaolinite-rich clays, that were deposited in shallow lakes adjacent to the active channel. Coal seams interlayered with palaeosols are the main constituents of element OF. Sheetlike bodies of medium to fine gravels (gravel bars and bedforms-GB) on an erosive coal surface mark the beginning of the second cycle. Dissolution of underlying Permian salts and sulphates prior to, during, and after the deposition of the Palaeogene strata caused the development of two synclines within the outcrop. Coal seams and clay horizons which thicken and dip towards the centre of the synclines, provide evidence for their chronological development.     

Sea-level rise impact models and environmental conservation: A review of models and their applications

Conservation managers and policy makers need tools to identify coastal habitats and human communities that are vulnerable to sea-level rise. Coastal impact models can help determine the vulnerability of areas and populations to changes in sea level. Model outputs may be used to guide decisions about the location and design of future protected areas and development, and to prioritize adaptation of existing protected area investments. This paper reviews state-of-the-art coastal impact models that determine sea-level rise vulnerability and provides guidance to help managers and policy makers determine the appropriateness of various models at local, regional, and global scales. There are a variety of models, each with strengths and weaknesses, that are suited for different management objectives. We find important trade-offs exist regarding the cost and capacity needed to run and interpret the models, the range of impacts they cover, and regarding the spatial scale that each operates which may overstate impacts at one end and underestimate impacts at the other. Understanding these differences is critical for managers and policy makers to make informed decisions about which model to use and how to interpret and apply the results.     

Integrating knowledge to assess coastal vulnerability to sea-level rise: The development of the DIVA tool

This paper describes the development of the DIVA tool, a user-friendly tool for assessing coastal vulnerability from subnational to global levels. The development involved the two major challenges of integrating knowledge in the form of data, scenarios and models from various natural, social and engineering science disciplines and making this integrated knowledge accessible to a broad community of end-users. These challenges were addressed by (i) creating and applying the DIVA method, an iterative, modular method for developing integrating models amongst distributed partners and (ii) making the data, scenarios and integrated model, equipped with a powerful graphical user interface, directly and freely available to end-users.     

Arsenic-enriched aquifers: Occurrences and mobilization of arsenic in groundwater of Ganges Delta Plain, Barasat, West Bengal, India

Hydrogeochemical characteristics and elemental features of groundwater and core sediments have been studied to better understand the sources and mobilization process responsible for As-enrichment in part of the Gangetic plain (Barasat, West Bengal, India). Analysis of water samples from shallow tubewells (depth 24.3–48.5 m) and piezometer wells (depth 12.2–79.2 m) demonstrate that the groundwater is mostly the Ca-HCO₃ type and anoxic in nature (mean Eh_SHE = 34 mV). Arsenic concentrations ranged from <10–538 μg/L, with high concentrations only present in the shallow to medium depth (30–50 m) of the aquifer along with high Fe (0.07–9.8 mg/L) and relatively low Mn (0.15–3.38 mg/L) as also evidenced in core sediments. Most groundwater samples contained both As(III) and As(V) species in which the concentration of As(III) was generally higher than that of As(V), exhibiting the reducing condition. Results show lower concentrations of NO₃, SO₄ and NO₂ along with higher values of DOC and HCO₃, indicating the reducing nature of the aquifer with abundant organic matter that can promote the release of As from sediments into groundwater. Positive correlations of As with Fe and DOC were also observed. The presence of DOC may actively drive the redox processes. This study revealed that reduction processes of FeOOH was the dominant mechanism for the release of As into the groundwater in this part of the Ganges Delta plain.     

The nature of O18/O16 and C13/C12 secular trends in sedimentary carbonate rocks

Measurements on 170 carbonate rocks show decreasing δO¹⁸ of similar magnitude for both limestones and dolomites over a time span of ~ 2800 m.y. The Proterozoic dolomites are on average heavier by ~5%. in δO¹⁸ than their coeval limestones. The data may indicate displacement in δC¹³ of about 3%. at approximately 570 m.y. ago, with Precambrian carbonates being heavier in δC¹³ at a given δO¹⁸ level than their Phanerozoic counterparts. The compilation of the previously published data is consistent with the above described features.     

The duisburg method of metro-construction, a successful application of the gap freezing method

Between March 1977 and August 1979 contract No.4 of the Stadtbahnbau (Metro-construction) in Duisburg was executed, making successful use of gap freezing.

The gap freezing was necessary because the Metro-tunnel is crossed by a groundwater stream (flow velocity up to 15 m/d) and it had to be assured that open cut construction of the tunnel was possible and that the original situation could be reinstated as far as possible after completion.

The Duisburg building ground also made a special construction method necessary. Ground strata: from surface to 2–4 m, civilisation deposits; from ˜ 4 m to ≈ 25–28 m below surface, glacial sand and gravel deposits, containing stones with a diameter > 20 cm and even boulders of 1 m³ and more; from approximately 28 m below surface, layers of Tertiary clay and silt; the groundwater table is ˜ 8 m below the surface, the stream flowing within the sand and gravel deposits from SE to NW (towards the Rhine).

Installing a groundwater barrier, for instance by erecting a continuous diaphragm wall enclosure, was already ruled out in early design stages as was the use of driven steelpiles.

At the inception of the design in 1974, it was decided first to carry out a measuring scheme to establish the groundwater flow velocity. This was followed by a large scale (1:1) trial freezing to ascertain the feasibility of the gap-freezing method.

When these experiments were scientifically valued it was established, that the risk involved was acceptable. The contract documents were prepared prescribing a combination of “cover and cut” with gap-freezing, which is tentatively called the “Duisburg method of Metro-construction”.

During the construction a large scale measuring and scientific research programme was carried out.     

Relationship between13C and18O fractionation and changes in major element composition in a recent calcite-depositing spring — A model of chemical variations with inorganic CaCO3 precipitation

A theoretical model is derived in which isotopic fractionations can be calculated as a function of variations in dissolved carbonate species on CO₂ degassing and calcite precipitation. This model is tested by application to a calcite-depositing spring system near Westerhof, Germany. In agreement with the model,¹³C of the dissolved carbonate species changes systematically along the flow path. The difference in δ values between the upper and lower part of the stream is about 1‰. The¹³C content of the precipitated calcite is different from that expected from the theoretical partitioning. The isotopic composition of the solid CaCO₃ is similar to that of the dissolved carbonate, though in theory it should be isotopically heavier by about 2.4‰. The¹⁸O composition of dissolved carbonate and H₂O is constant along the stream. Calculated calcite-water temperatures differ by about +5°C from the observed temperatures demonstrating isotopic disequilibrium between the water and precipitated solid. This is attributed to kinetic effects during CaCO₃ deposition from a highly supersaturated solution, in which precipitation is faster than equilibration with respect to isotopes.Plant populations in the water have virtually no influence on CO₂ degassing, calcite saturation and isotopic fractionation. Measurements of P_CO2, S_C and¹³C within a diurnal cycle demonstrate that metabolic effects are below the detection limit in a system with a high supply-rate of dissolved carbonate species. The observed variations are due to differences in CO₂ degassing and calcite precipitation, caused by continuously changing hydrodynamic conditions and carbonate nucleation rates.