Use of Cu isotopes to distinguish primary and secondary Cu mineralization in the Ca?ariaco Norte porphyry copper deposit, Northern Peru

A significant proportion of the copper in the Ca?ariaco Norte porphyry copper deposit in northern Peru occurs in chalcocite and covellite-rich veins and disseminations that exist from the surface to depths greater than 1?km. The overall range of Cu isotopic ratios of 42 mineral separates from Ca?ariaco varies from ?8.42 to 0.61?‰, with near-surface chalcocite and Fe oxides having isotopically depleted values compared to chalcocite, covellite, and chalcopyrite from deeper levels. The majority (34 of 36) of measured Cu sulfides have a typical hypogene copper isotope composition of δ⁶⁵Cu?=?0.18?±?0.38?‰, with no enriched isotopic signature existing in the Ca?ariaco Norte sulfide data. Thus, the copper isotope data indicate that most of the chalcocite and covellite formed from high-temperature hypogene mineralization processes and that only a minor portion of the deposit is enriched by supergene processes. The nonexistence of an enriched δ⁶⁵Cu reservoir suggest the presence of an undiscovered lateral/exotic Cu occurrence that enriched ⁶⁵Cu that remained in solution during weathering. Regardless of the cause, the comparative analysis of the Cu isotope dataset reveals that little exploration potential for an extensive supergene enrichment blanket exists because the weathering history at Ca?ariaco Norte was not conducive to preservation of enriched Cu at depth beneath the leach cap.     

A 2400-year record of trace metal loading in lake sediments of Lagoa Vermelha, southeastern Brazil

Sediments of the Lagoa Vermelha (Red Lake), situated in the Ribeira Valley, southeastern Brazil, are made of a homogeneous, organic-rich, black clay with no visible sedimentary structures. The inorganic geochemical record (Al, As, Ba, Br, Co,Cs, Cr, Fe, Mn, Ni, Rb, Sc, Sb, V, Zn, Hg and Pb) of the lake sediments was analyzed in a core spanning 2430 years. The largest temporal changes in trace metal contents occurred approximately within the last 180 years. Recent sediments were found to be enriched in Pb, Zn, Hg, Ni, Mn, Br and Sb (more than 2-fold increase with respect to the “natural background level”). The enhanced accumulation of Br, Sb, and Mn was attributed to biogeochemical processes and diagenesis. On the other hand, the anomalous concentrations of Pb, Zn, Hg and Ni were attributed to pollution. As Lagoa Vermelha is located in a relatively pristine area, far removed from direct contamination sources, the increased metal contents of surface sediments most likely resulted from atmospheric fallout. Stable Pb isotopes provided additional evidence for anthropogenic contamination. The shift of ²⁰⁶Pb/²⁰⁷Pb ratios toward decreasing values in the increasingly younger sediments is consistent with an increasing contribution of airborne anthropogenic lead. In the uppermost sediments (0-10 cm), the lowest values of the ²⁰⁶Pb/²⁰⁷Pb ratios may reflect the influence of the less radiogenic Pb from the Ribeira Valley District ores (²⁰⁶Pb/²⁰⁷Pb between 1.04 and 1.10), emitted during the last 50 years.     

Verification of mid-ocean ballast water exchange using naturally occurring coastal tracers

We examined methods for verifying whether or not ships have performed mid-ocean ballast water exchange (BWE) on four commercial vessels operating in the Pacific and Atlantic Oceans. During BWE, a ship replaces the coastal water in its ballast tanks with water drawn from the open ocean, which is considered to harbor fewer organisms capable of establishing in coastal environments. We measured concentrations of several naturally occurring chemical tracers (salinity, six trace elements, colored dissolved organic matter fluorescence and radium isotopes) along ocean transects and in ballast tanks subjected to varying degrees of BWE (0-99%). Many coastal tracers showed significant concentration changes due to BWE, and our ability to detect differences between exchanged and unexchanged ballast tanks was greatest under multivariate analysis. An expanded dataset, which includes additional geographic regions, is now needed to test the generality of our results.     

First lead isotopic data for cinnabar in the Almadén district (Spain): implications for the genesis of the mercury deposits

The Almadén district constitutes the largest and probably the most intriguing mercury concentration in the world. Two types of mineralization are recognized: 1) stratabound, of Lower Silurian age, well represented by the large Almadén deposit; and 2) fully discordant mercury deposits of minor importance in terms of size, and exemplified by the deposit of Las Cuevas. The latter ones can be found at different positions along the Almadén stratigraphic column. Both types of deposits are always associated with the so-called frailesca rocks (diatremes of alkali basaltic composition). This paper reports the first lead isotope compositions of cinnabar in the district. Whole samples and stepwise leaching cinnabar aliquots display relatively homogeneous isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.112–18.460; ²⁰⁷Pb/²⁰⁴Pb = 15.635–15.705; ²⁰⁸Pb/²⁰⁴Pb = 38.531–38.826). Taken together with Jébrak et al.s (2002) pyrite lead isotope results, the new cinnabar isotopic data define a steep array trend on the ²⁰⁷Pb/²⁰⁴Pb– ²⁰⁶Pb/²⁰⁴Pb diagram, indicating a mixed contribution of lead and probably mercury from different sedimentary sources in the Almadén basin. The Almadén Hg deposits are related to a contemporaneous mafic magmatism that might have provided part of the mercury. Hydrothermal leaching of organic matter from sedimentary rocks and formation of Hg organic complexes enhanced metal solubility, promoting transport from and within the volcanic units.Editorial handling: M. Chiaradia     

Residual displacement ratios for assessment of existing structures

Results of an analytical study aimed at evaluating residual displacement ratios, C_r, which allow the estimation of residual displacement demands from maximum elastic displacement demands is presented. Residual displacement ratios were computed using response time‐history analyses of single‐degree‐of‐freedom systems having 6 levels of relative lateral strength when subjected to an ensemble of 240 earthquake ground motions recorded in stations placed on firm sites. The results were statistically organized to evaluate the influence of the following parameters: period of vibration, level of relative lateral strength, site conditions, earthquake magnitude, and distance to the source. In addition, the influence of post‐yield stiffness ratio in bilinear systems and of the unloading stiffness in stiffness‐degrading systems was also investigated. A special emphasis is given to the uncertainty of these ratios. From this study, it is concluded that mean residual displacement ratios are more sensitive to changes in local site conditions, earthquake magnitude, distance to the source range and hysteretic behaviour than mean inelastic displacement ratios. In particular, residual displacement ratios exhibit large levels of record‐to‐record variability and, therefore, this dispersion should be taken into account when estimating residual displacements. A simplified expression is presented to estimate mean residual displacements ratios for elastoplastic systems during the evaluation of existing structures built on firm soil sites. Copyright © 2005 John Wiley & Sons, Ltd.     

New approach in the kinematic k−2 source model for generating physical slip velocity functions

In an attempt to improve the ground motion modelling, the characteristics of the slip velocity functions (SVF) generated using the kinematic k ⁻² source are investigated and compared to the dynamic solutions proposed in the literature. Several numerical simulations were performed to test the influence of the model parameters on the SVF modelling. Overall, the shapes of SVF are very complex and exhibit a large variability in time and space. However, we found out that the mean SVF is a simple boxcar with duration equal to the largest rise time value. In the areas of weak slip, the SVFs are characterized by the existence of negative values, whereas in large slip areas, the SVF is more impulsive. Overall, on the examples investigated, the SVFs modelled with this k ⁻² source model are different from a typical Kostrov's solution. The critical analysis of the kinematic k ⁻² source led us to identify the Fourier decomposition of the slip to be responsible for these difficulties, and to propose a new recombination scheme. It consists of adding a positive correction to the Fourier slip components. The slip is described as the sum of positive contributions at various scales. The SVFs modelled using this new scheme are greatly improved. Moreover, through several parametrical analyses performed to qualify this new approach, we show that the SVF are corrected while preserving the essential quality of the k ⁻² modelling, that is, the ω² spectral shape and C _d apparent directivity of the synthetic accelerograms. Strong ground motion modelling in the near-fault region was made and numerical ground motion parameters were compared to the empirical relationships. We show that predicted peak ground motion is consistent with near-source attenuation laws.     

An automated object-based approach for the multiscale image segmentation of forest scenes

Over the last decade the analysis of Earth observation data has evolved from what were predominantly per-pixel multispectral-based approaches, to the development and application of multiscale object-based methods. To empower users with these emerging object-based approaches, methods need to be intuitive, easy to use, require little user intervention, and provide results closely matching those generated by human interpreters. In an attempt to facilitate this, we present multiscale object-specific segmentation (MOSS) as an integrative object-based approach for automatically delineating image-objects (i.e., segments) at multiple scales from a high-spatial resolution remotely sensed forest scene. We further illustrate that these segments cognitively correspond to individual tree crowns, ranging up to forest stands, and describe how such a tool may be used in computer-assisted forest inventory mapping. MOSS is composed of three primary components: object-specific analysis (OSA), object-specific upscaling (OSU), and a new segmentation algorithm referred to as size constrained region merging (SCRM). The rationale for integrating these methods is that the first two provide the third with object-size parameters that otherwise would need to be specified by a user. Analysis is performed on an IKONOS-2 panchromatic image that represents a highly fragmented forested landscape in the Sooke Watershed on southern Vancouver Island, BC, Canada.     

U–Pb zircon and Re–Os molybdenite geochronology from La Caridad porphyry copper deposit: insights for the duration of magmatism and mineralization in the Nacozari District, Sonora, Mexico

Uranium–lead zircon (laser ablation multi-collector ICP-MS spot analysis) ages from La Caridad porphyry copper deposit in the Nacozari District, Northeastern Sonora, Mexico, suggest a short period of magmatism, between 55.5 and 52.6 Ma. Two U–Pb ages from the mineralized quartz monzonite unit, showing different textural characteristics, yielded indistinguishable crystallization ages (~54 Ma), and indicate that the intrusion responsible for the mineralization occurred as a single large complex unit, instead of multiple pulses of magmatism. Some zircons analyzed also show inherited ages in cores recording dates of 112–124 Ma, 141–166 Ma and 1.4 Ga. The Re–Os molybdenite ages from the potassic and phyllic hydrothermal alteration veins yielded identical ages within error, 53.6±0.3 Ma and 53.8±0.3 Ma, respectively (weighted average of 53.7±0.21 Ma), supporting a restricted period for the mineralization. The geochronological data thus indicate a short-lived magmatic and hydrothermal system. The inherited zircons of Precambrian and Late Jurassic-Mid Cretaceous age found in the intrusive rocks of La Caridad deposit, can be explained considering two possible scenarios within the tectonic/magmatic evolution of the area. The first scenario considers the presence of a Precambrian anorogenic granitic basement that is intruded by Mesozoic (Jurassic–Cretaceous) units present beneath the La Caridad deposit. The second scenario suggests that the Mesozoic Glance Conglomerate Formation of Arizona underlies the Paleocene volcanic-igneous pile in the La Caridad area.     

Late Archean Cu-Au-Mo mineralization at Gameleira and Serra Verde, Carajàs Mineral Province, Brazil: constraints from Re-Os molybdenite ages

New Re-Os molybdenite ages provide constraints on the timing of Late Archean Cu-Au-Mo mineralization in the northern Carajás Mineral Province. Molybdenite from the Gameleira iron oxide Cu-Au-Mo deposit yielded an age of 2,614±14 Ma. This age overlaps within its analytical error with Re-Os ages of molybdenite from the Serra Verde Cu-Au-Mo vein deposit (2,609±13 Ma) and from the nearby small Garimpo Fernando gold mining operation (2,592±13 and 2,602±13 Ma), which is probably related to the latter. The geochronological data imply that the hydrothermal Cu-Au-Mo mineralization in these three deposits was epigenetic and coincides with a regional tectonic regime changing from dextral transtension and clastic sedimentation at 2.7–2.6 Ga to sinistral transpression and inversion at 2.6 Ga. Previously reported stable isotope and microthermometric data are compatible with a magmatic affiliation of the Cu-Au-Mo ores at Gameleira and Serra Verde. A genetic relationship of mineralization may therefore exist with 2.56–2.76 Ga Archean alkaline granitoids or with 2.6–2.7 calc-alkaline to tholeiitic volcanic-arc type magmatism.Editorial handling: F. Tornos     

Luminous efficacy of global solar radiation on a horizontal surface for overcast and intermediate skies

Summary  In the first part of this research two models for the luminous efficacy of global solar radiation on horizontal surfaces and overcast skies have been developed. The first of these models is developed using a method similar to that proposed by Littlefair (1988). The second model has been obtained from the corresponding illuminance and irradiance models in an, apparently, new approach to the subject. In the second part of this research, a model for the luminous efficacy of global solar radiation for intermediate skies and horizontal surfaces is developed from the corresponding illuminance and irradiance models. The model for intermediate skies is given by the same mathematical function as that of the analogous model for overcast skies, and only the empirical constants change. In all the cases the only independent variables used are the solar altitude and the brightness index. The models proposed in the present paper have been statistically tested, and their prediction accuracy compared with other models available in the scientific literature. Received June 26, 2000 Revised December 9, 2000