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161.
Christian D. Johnson Katherine A. Muller Michael J. Truex Guzel Tartakovsky David J. Becker Carl M. Harms Jovan Popovic 《Ground Water Monitoring & Remediation》2022,42(1):81-87
Diminishing rates of subsurface volatile contaminant removal by soil vapor extraction (SVE) oftentimes warrants an in-depth performance assessment to guide remedy decision-making processes. Such a performance assessment must include quantitative approaches to better understand the impact of remaining vadose zone contamination on soil gas and groundwater concentrations. The spreadsheet-based Soil Vapor Extraction Endstate Tool (SVEET) software functionality has recently been expanded to facilitate quantitative performance assessments. The updated version, referred to as SVEET2, includes expansion of the input parameter ranges for describing a site (site geometry, source characteristics, etc.), an expanded list of contaminants, and incorporation of elements of the Vapor Intrusion Estimation Tool for Unsaturated-zone Sources software to provide soil gas concentration estimates for use in vapor intrusion evaluation. As part of the update, SVEET2 was used to estimate the impact of a tetrachloroethene (PCE) vadose zone source on groundwater concentrations, comparing SVEET2 results to field-observed values at an undisclosed site where SVE was recently terminated. PCE concentrations from three separate monitoring wells were estimated by SVEET2 to be within the range of 6.0–6.7 μg/L, as compared to actual field concentrations that ranged from 3 to 11 μg/L PCE. These data demonstrate that SVEET2 can rapidly provide representative quantitative estimates of impacts from a vadose zone contaminant source at field sites. In the context of the SVE performance assessment, such quantitative estimates provide a basis to support remedial and/or regulatory decisions regarding the continued need for vadose zone volatile organic compound remediation or technical justification for SVE termination, which can significantly reduce the cost to complete for a site. 相似文献
162.
Copper has two naturally occurring stable isotopes of masses 63 and 65 which can undergo mass dependent fractionation during various biotic and abiotic chemical reactions. These interactions and their resulting Cu isotope fractionations can be used to determine the mechanisms involved in the cycling of Cu in natural systems. In this study, Cu isotope changes were investigated at the organismal level in the metal-accumulating desert plant, Prosopis pubescens. Initial results suggest that the lighter Cu isotope was preferentially incorporated into the leaves of the plant, which may suggest that Cu was actively transported via intracellular proteins. The roots and stems show a smaller degree of Cu isotope fractionation and the direction and magnitude of the fractionations was dependent upon the levels of Cu exposure. Based on this and previous work with bacteria and yeast, a trend is emerging that suggests the lighter Cu isotope is preferentially incorporated into biological components, while the heavier Cu isotope tends to become enriched in aqueous solutions. In bacteria, plants and animals, intracellular Cu concentrations are strictly regulated via dozens of enzymes that can bind, transport, and store Cu. Many of these enzymes reduce Cu(II) to Cu(I). These initial results seem to fit into a broader picture of Cu isotope cycling in natural systems where oxidation/reduction reactions are fundamental in controlling the distributions of Cu isotopes. 相似文献
163.
Vera Ponomareva Maxim Portnyagin Alexander Derkachev I. Florin Pendea Joanne Bourgeois Paula J. Reimer Dieter Garbe-Schönberg Stepan Krasheninnikov Dirk Nürnberg 《International Journal of Earth Sciences》2013,102(6):1673-1699
We report tephrochronological and geochemical data on early Holocene activity from Plosky volcanic massif in the Kliuchevskoi volcanic group, Kamchatka Peninsula. Explosive activity of this volcano lasted for ~1.5 kyr, produced a series of widely dispersed tephra layers, and was followed by profuse low-viscosity lava flows. This eruptive episode started a major reorganization of the volcanic structures in the western part of the Kliuchevskoi volcanic group. An explosive eruption from Plosky (M~6), previously unstudied, produced tephra (coded PL2) of a volume of 10–12 km3 (11–13 Gt), being one of the largest Holocene explosive eruptions in Kamchatka. Characteristic diagnostic features of the PL2 tephra are predominantly vitric sponge-shaped fragments with rare phenocrysts and microlites of plagioclase, olivine and pyroxenes, medium- to high-K basaltic andesitic bulk composition, high-K, high-Al and high-P trachyandesitic glass composition with SiO2 = 57.5–59.5 wt%, K2O = 2.3–2.7 wt%, Al2O3 = 15.8–16.5 wt%, and P2O5 = 0.5–0.7 wt%. Other diagnostic features include a typical subduction-related pattern of incompatible elements, high concentrations of all REE (>10× mantle values), moderate enrichment in LREE (La/Yb ~ 5.3), and non-fractionated mantle-like pattern of LILE. Geochemical fingerprinting of the PL2 tephra with the help of EMP and LA-ICP-MS analyses allowed us to map its occurrence in terrestrial sections across Kamchatka and to identify this layer in Bering Sea sediment cores at a distance of >600 km from the source. New high-precision 14C dates suggest that the PL2 eruption occurred ~10,200 cal BP, which makes it a valuable isochrone for early Holocene climate fluctuations and permits direct links between terrestrial and marine paleoenvironmental records. The terrestrial and marine 14C dates related to the PL2 tephra have allowed us to estimate an early Holocene reservoir age for the western Bering Sea at 1,410 ± 64 14C years. Another important tephra from the early Holocene eruptive episode of Plosky volcano, coded PL1, was dated at 11,650 cal BP. This marker is the oldest geochemically characterized and dated tephra marker layer in Kamchatka to date and is an important local marker for the Younger Dryas—early Holocene transition. One more tephra from Plosky, coded PL3, can be used as a marker northeast of the source at a distance of ~110 km. 相似文献
164.
Bronfenbrenner’s bioecological theory for modelling community resilience to natural disasters 总被引:1,自引:1,他引:0
Helen J. Boon Alison Cottrell David King Robert B. Stevenson Joanne Millar 《Natural Hazards》2012,60(2):381-408
This paper advocates the use of Bronfenbrenner’s bioecological theory as a framework to analyse resilience at diverse scales. Bronfenbrenner’s bioecological theory can be employed to (a) benchmark
social resilience, (b) target the priority interventions required and (c) measure progress arising from these interventions
to enhance resilience to natural disasters. First, the paper explores resilience to natural disasters in the context of climatic
change as building resilience is seen as a way to mitigate impacts of natural disasters. Second, concepts of resilience are
systematically examined and documented, outlining resilience as a trait and resilience as a process. Third, issues arising
in relation to the measurement of resilience are discussed. Fourth, Bronfenbrenner’s bioecological systems theory is described
and proffered to model and assess resilience at different scales. Fifth, studies are described which have supported the use
of the bioecological systems theory for the study of resilience. Sixth, an example of the use of Bronfenbrenner’s theory is
offered and the paper concludes with suggestions for future research using Bronfenbrenner’s theory. 相似文献
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167.
Joanne M. R. Fernlund 《第四纪科学杂志》1993,8(1):67-78
Radiocarbon dates of shells from the long singular ridges belonging to the Halland Coastal Moraines indicate that the ridges are younger than 12 400 yr BP, whereas according to the existing chronostratigraphy of western Sweden, the area was ice free before 12 700 yr BP. The ridges are interpreted as push moraines and not deposits of a stationary ice margin. The chronostratigraphy of western Sweden seems to need revision; however, further study is necessary before it is possible to present a new model. 相似文献
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170.
Txomin Hermosilla Michael A. Wulder Joanne C. White Nicholas C. Coops Geordie W. Hobart Lorraine B. Campbell 《International Journal of Digital Earth》2016,9(11):1035-1054
Free and open access to the Landsat archive has enabled the implementation of national and global terrestrial monitoring projects. Herein, we summarize a project characterizing the change history of Canada’s forested ecosystems with a time series of data representing 1984–2012. Using the Composite2Change approach, we applied spectral trend analysis to annual best-available-pixel (BAP) surface reflectance image composites produced from Landsat TM and ETM+ imagery. A total of 73,544 images were used to produce 29 annual image composites, generating ~400 TB of interim data products and resulting in ~25 TB of annual gap-free reflectance composites and change products. On average, 10% of pixels in the annual BAP composites were missing data, with 86% of pixels having data gaps in two consecutive years or fewer. Change detection overall accuracy was 89%. Change attribution overall accuracy was 92%, with higher accuracy for stand-replacing wildfire and harvest. Changes were assigned to the correct year with an accuracy of 89%. Outcomes of this project provide baseline information and nationally consistent data source to quantify and characterize changes in forested ecosystems. The methods applied and lessons learned build confidence in the products generated and empower others to develop or refine similar satellite-based monitoring projects. 相似文献